Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA

Journal of Hydrology (Elsevier) | October 1st, 2019

Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where comp

Concentrations of uranium (U) >30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize U. High concentrations (>30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected in 24 percent of 257 domestic, irrigation, and public-supply wells sampled across an approximately 110,000 km2 area. In this study we evaluated mechanisms for mobilization of U in the San Joaquin Valley proposed in previous studies, confirming mobilization by HCO3 and refuting mobilization by NO3 and we refined our understanding of the geologic sources of U to the scale of individual alluvial fans. The location of high concentrations depends on the interactions of geological U sources from fluvial fans that originate in the Sierra Nevada to the east and seepage of irrigation water that contains high concentrations of HCO3 that leaches U from the sediments. In addition, interactions with PO4 from fertilized irrigated fields may sequester U in the aquifer. Principal component analysis of the data demonstrates that HCO3 and ions associated with high total dissolved solids in the aquifer and the percentage of agriculture near the well sampled are associated with high U concentrations. Nitrate concentrations do not appear to control release of U to the aquifer. Age dating of the groundwater and generally increasing U concentrations of the past 25  years in resampled wells where irrigation is prevalent suggests that high U concentrations are associated with younger water, indicating that irrigation of fields over the past 100  years has significantly contributed to increasing concentrations and mobilizing U. In some places, the groundwater is supersaturated with uranyl-containing minerals, as would be expected in roll front deposits. In general, the interaction of natural geological sources high in U, the anthropogenically driven addition of HCO3 and possibly phosphate fertilizer, control the location and concentration of U in each individual fluvial fan, but the addition of nitrate in fertilizer does not appear control the location of high U. These geochemical interactions are complex but can be used to determine controls on anomalously high U in alluvial aquifers.

Applying the Connectivity Approach: Groundwater management in California's Kings Basin

California Roundtable on Water and Food Supply (CRWFS) | March 27th, 2015

The California Roundtable on Water and Food Supply (CRWFS) studied the processes used in the Kings Groundwater Subbasin (Kings Basin) of California’s San Joaquin Valley

The California Roundtable on Water and Food Supply (CRWFS) studied the processes used in the Kings Groundwater Subbasin (Kings Basin) of California’s San Joaquin Valley to reveal strategies for advancing groundwater sustainability within the context of watershed-scale, integrated water management. This inquiry was guided by the principles of the “connectivity approach”: a framework developed by CRWFS for resource managers, land use planners and policymakers to discover the linkages, strengths, successes, potentials, and disconnects related to their particular resource stewardship issues. A key concept is connected benefits, which refers to achieving multiple benefits across resource and development sectors to respond to California’s increasing water management challenges.

Appraisal of the water resources of Death Valley, California–Nevada

U.S. Geological Survey (USGS) | December 1st, 1977

Approaches for groundwater management in times of depletion and regulatory change

University of California, Davis (UC Davis) | June 1st, 2018

New legislation and related regulations in California mandate groundwater management to avoid undesirable results from excessive groundwater pumping and other hum

New legislation and related regulations in California mandate groundwater management to avoid undesirable results from excessive groundwater pumping and other human activities. Required aspects of management planning that will occur in well over 100 alluvial groundwater sub-basins across the state include scientific foundation and public transparency. While the details of individual groundwater management approaches will be particular to conditions in each management area, there will be common elements based on similar aspects of many groundwater systems in the state. The process of beginning to implement groundwater management for a large part of the state poses challenges. Use of scientific knowledge and methods of analysis developed in academia and industry will be helpful to the overall effort. This dissertation considers aspects of groundwater management that are expected to be common among many planning efforts. Inactive water supply wells acting as conduits for contaminant migration is considered through field examples and use of recently available databases regarding existing well constructions and water quality. Nonpoint source pollution effects on groundwater quality from conduit wells are investigated and selective regulatory action is explored as an option for addressing an issue that is too large for complete solution with available resources. Options for managed aquifer recharge are explored for a combined urban-agricultural area through use of a recently released land use database. A hydro-economic analysis is performed using linear programming to evaluate the efficacy of an on-farm recharge approach. Future work may include development of additional insights within the context of the study areas presented as well as extensions that consider new geographic areas and additional related considerations.

Approved Determination of the Revised Groundwater Sustainability Plan Submitted for the San Joaquin Valley – Merced Subbasin

California Department of Water Resources (DWR) | August 4th, 2023

Aquifer depletion exacerbates agricultural drought losses in the US High Plains

Nature Portfolio (Springer Nature) | January 15th, 2024

Aquifer depletion poses a major threat to the ability of farmers, food supply chains and rural economies globally to use groundwater as a means of adapting to climate var

Aquifer depletion poses a major threat to the ability of farmers, food supply chains and rural economies globally to use groundwater as a means of adapting to climate variability and change. Empirical research has demonstrated the large differences in drought risk exposure that exist between rainfed and irrigated croplands, but previous work commonly assumes water supply for the latter is unconstrained. Here we evaluate how aquifer depletion affects the resilience of irrigated crop production to drought risk using over 30 years of data on historical corn and soybean yields, production areas and aquifer conditions for the High Plains region in the United States. We show that aquifer depletion reduces the ability of farmers to sustain irrigated crop yields and production areas in years and locations with large growing-season water deficits. Our findings demonstrate that drought-related production losses on irrigated croplands increase non-linearly with aquifer depletion, highlighting the need for proactive aquifer conservation interventions to support adaptation and resilience to future increases in rainfall variability under climate change.

Aquifer Recharge from the 1969 and 1978 Floods in the Mojave River Basin, California

U.S. Geological Survey (USGS) | April 15th, 1980

Aquifer-system compaction and land subsidence: Measurements, analyses, and simulations-the Holly Site, Edwards Air Force Base, Antelope Valley, California

U.S. Geological Survey (USGS) | July 1st, 2000

Arsenic, chromium, uranium, and vanadium in rock, alluvium, and groundwater, Mojave River and Morongo Areas, western Mojave Desert, southern California

U.S. Geological Survey (USGS) | October 16th, 2023

Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geoge

Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geogenic contaminants arsenic, chromium, and vanadium can form negatively charged ions with oxygen known as oxyanions. Uranium complexes with bicarbonate and carbonate to form negatively charged ions having aqueous chemistry similar to oxyanions. The concentrations of arsenic, chromium, uranium, and vanadium in groundwater result from the combined effects of (1) geologic abundance within aquifer materials; (2) the fraction of these elements that have weathered from and sorbed to the surfaces of mineral grains and are potentially available to groundwater; and (3) the aqueous chemistry of dissolved oxyanions in groundwater during different redox conditions and pH, both of which are affected by hydrogeology, including the length of time groundwater has been in contact with aquifer materials. Concentrations of arsenic, chromium, uranium, and vanadium were measured in samples of (1) rock, surficial alluvium, and drill cuttings using portable (handheld) X-ray fluorescence (pXRF); (2) operationally defined fractions extractable from these materials; and (3) water from wells sampled between 2000 and 2018 within the 3,500 square mile Mojave River area and Morongo area of the western Mojave Desert, southern California.

Arsenic, Chromium, Uranium, and Vanadium in Rock, Arsenic, Chromium, Uranium, and Vanadium in Rock, Alluvium, and Groundwater, Mojave River and Morongo Alluvium, and Groundwater, Mojave River and Morongo Areas, Western Mojave Desert, Southern California

U.S. Geological Survey (USGS) | October 16th, 2023

Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geoge

Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geogenic contaminants arsenic, chromium, and vanadium can form negatively charged ions with oxygen known as oxyanions. Uranium complexes with bicarbonate and carbonate to form negatively charged ions having aqueous chemistry similar to oxyanions. The concentrations of arsenic, chromium, uranium, and vanadium in groundwater result from the combined effects of (1) geologic abundance within aquifer materials; (2) the fraction of these elements that have weathered from and sorbed to the surfaces of mineral grains and are potentially available to groundwater; and (3) the aqueous chemistry of dissolved oxyanions in groundwater during different redox conditions and pH, both of which are affected by hydrogeology, including the length of time groundwater has been in contact with aquifer materials. Concentrations of arsenic, chromium, uranium, and vanadium were measured in samples of (1) rock, surficial alluvium, and drill cuttings using portable (handheld) X-ray fluorescence (pXRF); (2) operationally defined fractions extractable from these materials; and (3) water from wells sampled between 2000 and 2018 within the 3,500 square mile Mojave River area and Morongo area of the western Mojave Desert, southern California. ... The quality of water imported from northern California and infiltrated from ponds for groundwater recharge may be altered by naturally present trace elements, especially uranium in areas of agricultural land use or chromium within mafic alluvium. Introduction