Estimation of groundwater residence time with deeply-derived carbon mixture considered in California

Science of the Total Environment (Elsevier) | December 16th, 2022

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic co

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic contamination. As a useful indicator of groundwater renewal rate and its residence time, groundwater age has been conventionally investigated based on 14C content and 3H concentration. However, the influence of deeply-derived (endogenic) CO2 mixture is not fully and quantitatively considered, although endogenic carbon contributes a large part of the dissolved inorganic carbon in groundwater. Combined with 3H concentration, both conventional and modified 14C-dating methods with endogenic CO2 mixture considered are employed for groundwater age determination in California. On average, the conventional groundwater 14C apparent age is overestimated by ~4.9 kyr or ~26.2 %, causing groundwater recharge rate underestimation and aquifer recovery time overestimation by ~46.0 % and ~26.2 %, respectively. High 3H concentration indicates modern water mixture in more than one fifth of groundwater samples, including those with high modified 14C apparent age (> 12 kyr, i.e., fossil groundwater) in the Central Valley and southern California, which are generally considered not to be recharged by modern water. Modern water mixture in old groundwater can potentially bring anthropogenic contamination to these groundwater resources, which should be paid attentions by the government and the managers. The results have important implications in evaluation of groundwater replenishment and its susceptibility to modern contamination in California, and in groundwater resources estimation globally.

Evaluation of Processes Affecting 1,2-Dibromo-3-Chloropropane (DBCP) Concentrations in Ground Water in the Eastern San Joaquin Valley, California: Analysis of Chemical Data and Ground-Water Flow and Transport Simulations

U.S. Geological Survey (USGS) | December 17th, 1999

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DB

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DBCP), an agricultural fumigant banned from use since the late 1970’s, persists at concentrations greater than the maximum contaminant level of 0.2 micrograms per liter (?g/L). Field data indicate that DBCP concentrations in ground water have decreased since the late 1970’s. Laboratory experiments by earlier investigators show that DBCP transformed to 2-bromoallyl alcohol (BAA) under conditions similar to in situ conditions, with an estimated half-life ranging from 6.1 (pH 7.8, 21.1 degrees Celsius) to 141 years (pH 7.0, 15 degrees Celsius). For this current study, a detailed hydrogeologic investigation was done to assess the relative importance of chemical transformation, dispersion, and ground-water pumping and reapplication of irrigation water in affecting DBCP concentrations. Groundwater samples were collected from 20 monitoring wells installed along a 4.6- kilometer transect. DBCP concentrations in these samples ranged from less than the detection limit of 0.03  g/L to a maximum of 6.4 g/L. Results of chlorofluorocarbon (CFC) age dating indicate that DBCP occurs in water that ranges in age from about 2 to 41 years. The primary transformation product BAA, which was identified during previous laboratory studies, was not detected at or greater than 0.03  g/L in any of the 20 ground- water samples. The lack of detection of BAA indicates that transformation to BAA is insignificant relative to other processes controlling DBCP concentrations. Results from this current study indicate that the in situ hydrolysis half-life for DBCP to BAA is much greater than the laboratory-determined values.

Evaluation of the characteristics, discharge, and water quality of selected springs at Fort Irwin National Training Center, San Bernardino County, California

U.S. Geological Survey (USGS) | March 29th, 2024

Eight springs and seeps at Fort Irwin National Training Center were described and categorized by their general characteristics, discharge, geophysical properties, and wat

Eight springs and seeps at Fort Irwin National Training Center were described and categorized by their general characteristics, discharge, geophysical properties, and water quality between 2015 and 2017. The data collected establish a modern (2017) baseline of hydrologic conditions at the springs. Two types of springs were identified: (1) precipitation-fed upland springs (Cave, Desert King, Devouge, No Name, and Panther Springs) and (2) groundwater discharge-fed basin springs (Garlic, Bitter, and Jack Springs). Comparison of electrical resistivity tomography data collected at groundwater basin springs from 2015 to 2017 indicated that spring discharge and connection to the underlying groundwater system is highly focused, although the springs themselves appear diffuse and are spread out over a large area.

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

U.S. Geological Survey (USGS) | December 13th, 2003

From early 1995 through 2001, nitrate (NO3) concentrations in ground water in the Warren subbasin, California, increased from a background concentration of 10 milligrams

From early 1995 through 2001, nitrate (NO3) concentrations in ground water in the Warren subbasin, California, increased from a background concentration of 10 milligrams per liter (mg/L) to more than the U.S. Environmental Protection Agency (USEPA) water-quality maximum contaminant level of 44 mg/L (10 mg/L as nitrogen). This increase coincided with an artificial ground-water recharge program implemented by the local water district, Hi-Desert Water District (HDWD), to reverse ground-water level declines of as much as 300 ft. Major findings on ground-water quality from this study are the following: •Septage from septic tanks was the primary source of NO3 to the ground-water system. •Rising ground-water levels, resulting from the artificial-recharge program, entrained high-NO3 septage stored in the unsaturated zone. •The potential for ground-water contamination should be evaluated before beginning an artificial- recharge program in an area that uses septic tanks.

Factors Affecting Public-Supply-Well Vulnerability to Contamination: Understanding Observed Water Quality and Anticipating Future Water Quality

U.S. Geological Survey (USGS) | May 14th, 2013

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the vulnerability of water from public-supply wells to contamination (referred to hereafter as “public-supply-well vulnerability”). The study was designed as a follow-up to earlier NAWQA studies that found mixtures of contaminants at low concentrations in groundwater near the water table in urban areas across the Nation and, less frequently, in deeper groundwater typically used for public supply. Beside the factors affecting public-supply-well vulnerability to contamination, this circular describes measures that can be used to determine which factor (or factors) plays a dominant role at an individual public-supply well. Case-study examples are used throughout to show how such information can be used to improve water quality. In general, the vulnerability of the water from public-supply wells to contamination is a function of contaminant input within the area that contributes water to a well, the mobility and persistence of a contaminant once released to the groundwater, and the ease of groundwater and contaminant movement from the point of recharge to the open interval of a well. The following measures described in this circular are particularly useful for indicating which contaminants in an aquifer might reach an individual public-supply well and when, how, and at what concentration they might arrive: Sources of recharge—Information on the sources of recharge for a well provides insight into contaminants that might enter the aquifer with the recharge water and potentially reach the well. Geochemical conditions—Information on the geochemical conditions encountered by groundwater traveling to a well provides insight into contaminants that might persist in the water all the way to the well. Groundwater-age mixtures—Information on the ages of the different waters that mix in a well provides insight into the time lag between contaminant input at the water table and contaminant arrival at the well. It also provides insight into the potential for in-well dilution of contaminated water by unaffected groundwater of a different age that simultaneously enters the well. Preferential flow pathways—pathways that provide little resistance to flow—can influence how all other factors affect public-supply-well vulnerability to contamination. For example, preferential flow pathways can influence whether a contaminant source is physically linked to a well, whether contaminant concentrations are substantially altered before contaminated groundwater reaches a well, and whether contaminated groundwater can arrive at a well within a timeframe of concern to the well owner. Methods for recognizing the influence of preferential flow pathways on the quality of water from a public-supply well are presented in this circular and can provide opportunities to prevent or mitigate the deterioration of a water supply. Knowing what water-quality variables to measure, what spatial and temporal scales on which to measure them, and how to interpret the resulting data makes it possible for samples from public-supply wells to provide a broad window into a well’s past and present water quality—and possibly future water quality. Such insight can enable resource managers to prioritize actions for sustaining a high-quality groundwater source of drinking water.

Final Environmental Impact Report Volume II: Revised Draft EIR Comprehensive Groundwater Cleanup Strategy for Historical Chromium Discharges from PG&E’s Hinkley Compressor Station, San Bernardino County

California State Water Resources Control Board (SWRCB) | April 20th, 2013

Click here for Volume I.

Click here for Volume I.

Fluid migration pathways to groundwater in mature oil fields: Exploring the roles of water injection/production and oil-well integrity in California, USA

Science of The Total Environment (Elsevier) | August 23rd, 2023

Fourth Five Year Review Report for the San Gabriel Valley Area 2 Superfund Site, Los Angeles, California

U.S. Environmental Protection Agency (EPA) | September 15th, 2022

This is the fourth Five-Year Review of the San Gabriel Valley Area 2 (Site) located in the San Gabriel Valley in Los Angeles County, California. The purpose of this Five-

This is the fourth Five-Year Review of the San Gabriel Valley Area 2 (Site) located in the San Gabriel Valley in Los Angeles County, California. The purpose of this Five-Year Review is to review information to determine if the remedy is and will continue to be protective of human health and the environment. The Site addresses approximately 10 square miles of groundwater contamination in eastern Los Angeles County within the San Gabriel Valley. Groundwater contamination is believed to result from the cumulative impact of decades of improper chemical handling and disposal practices at numerous industrial operations in the Valley. The Site contamination originates at current and former industrial facilities in and near Azusa, California and extends to the southwest through portions of the cities of Irwindale, Baldwin Park, West Covina, and Industry. The most prevalent contaminants in groundwater are trichloroethylene, tetrachloroethylene, carbon tetrachloride, perchlorate, n-nitrosodimethylamine (NDMA), and 1,4-dioxane.

Geologic Map and Borehole Stratigraphy of Hinkley Valley and Vicinity, San Bernardino County, California

U.S. Geological Survey (USGS) | December 17th, 2020

Hinkley Valley, in the central to western Mojave Desert of southeastern California, has a long historical record owing to its position as a crossroads for rail and road t

Hinkley Valley, in the central to western Mojave Desert of southeastern California, has a long historical record owing to its position as a crossroads for rail and road traffic and its position adjacent to the Mojave River. Subflow in the Mojave River provided groundwater recharge that maintained water consumption and demand by way of shallow wells for local agriculture (Thompson, 1929) in the valley. Its crossroads position led to construction of several power-transmission lines, pipeline, and communications cable routes that transect Hinkley Valley. One of these, a natural gas pipeline and its associated compressor station, was the locus of hexavalent chromium, Cr(VI), releases into, and consequent contamination of, groundwater (Izbicki and Groover, 2018). Understanding the movement and fate of the contaminants is a complex hydrologic and geo-chemical problem. Geologic mapping of the Hinkley Valley area provides framework elements for use in resolving this problem.

Geologic, Hydrologic, and Water-Quality Data From Multiple-Well Monitoring Sites in the Bunker Hill and Yucaipa Groundwater Subbasins, San Bernardino County, California, 1974–2016

U.S. Geological Survey (USGS) | October 31st, 2018

In 1974, the U.S. Geological Survey (USGS), in cooperation with the San Bernardino Valley Municipal Water District, initiated a study to assess the regional groun

In 1974, the U.S. Geological Survey (USGS), in cooperation with the San Bernardino Valley Municipal Water District, initiated a study to assess the regional groundwater resources in the Bunker Hill Subbasin of the Upper Santa Ana Valley Groundwater Basin in San Bernardino County, California. The study area expanded east into the Yucaipa Subbasin in 1996. This report compiles the geologic (borehole lithology and geophysical logs) and hydrologic (water- quality and water-level) data collected from 1974–2016 for 11 multiple-well monitoring sites (48 individual wells) constructed by the USGS in the Bunker Hill (7 sites) and Yucaipa (4 sites) Groundwater Subbasins. Approximately 240 water-quality samples from the 11 sites were analyzed for constituents including major and minor ions, nutrients, selected trace elements, organic wastewater compounds (OWCs), volatile organic compounds (VOCs), pesticides and pesticide degradates, the stable isotopes of hydrogen, oxygen, and nitrogen, and the radiogenic isotopes of tritium and carbon-14. All environmental data associated with these sites are available on the project web page for the San Bernardino Optimal Basin Management study and the Yucaipa Valley Hydrogeology study. Quality-assurance blank samples were processed periodically throughout the study and show that approximately 2.4 percent of the analytical results for major and minor ions, trace elements, and nutrients, and 1.5 percent of the results for VOCs fall below the acceptable study reporting limits and therefore are censored.