Small Tributaries Pollutants of Concern Reconnaissance Monitoring: Pilot Evaluation of Source Areas Using PCB Congener Data

San Francisco Estuary Institute (SFEI) | October 1st, 2019

PCB congener profiles can be used to help identify source areas that contribute most to the PCB mass exported from the watershed via stormwater and to illustrate variabi

PCB congener profiles can be used to help identify source areas that contribute most to the PCB mass exported from the watershed via stormwater and to illustrate variability in PCB mobilization from source areas over time. A method is presented for estimating the contributions of different Aroclor mixtures to the congener profiles of samples of stormwater and sediment. The method is based on the use of indicator congeners that are representative of each of the four most commonly used Aroclors. In this report, the method was applied in three watersheds. In the Pulgas Pump Station watershed, stormwater and sediment had high concentrations with a unique congener profile, dominated by congeners indicative of a combination of Aroclors 1242 and 1260. The concentrations and congener profiles in sediment suggest that there are two distinct source areas in the watershed that combine to create the mix of 1242 and 1260 that is dominant in stormwater at the Pump Station. The data indicate that if PCB flux from one of these areas could be eliminated, loads from the watershed would be reduced by 50% or more. For the Coyote Creek watershed, the similarity in congener profiles for the highest concentration sediment samples and the stormwater samples suggest that the important source areas in the watershed have been identified, and that reduction of loading from an area at the south end of the Charcot Avenue Storm Drain watershed would yield the greatest reduction in export at the Coyote Creek station. The concentrations and congener profiles in stormwater and sediment from the Guadalupe River watershed indicate the presence of one source area that is likely a substantial contributor to PCB export from the watershed, but that all of the significant sources areas may not yet have been identified.

Smartphone-based turbidity reader

Nature Portfolio (Springer Nature) | December 27th, 2019

Water quality is undergoing significant deterioration due to bacteria, pollutants and other harmful particles, damaging aquatic life and lowering the quality of d

Water quality is undergoing significant deterioration due to bacteria, pollutants and other harmful particles, damaging aquatic life and lowering the quality of drinking water. It is, therefore, important to be able to rapidly and accurately measure water quality in a cost-effective manner using e.g., a turbidimeter. Turbidimeters typically use different illumination angles to measure the scattering and transmittance of light through a sample and translate these readings into a measurement based on the standard nephelometric turbidity unit (NTU). Traditional turbidimeters have high sensitivity and specificity, but they are not field-portable and require electricity to operate in field settings. Here we present a field-portable and cost effective turbidimeter that is based on a smartphone. This mobile turbidimeter contains an opto-mechanical attachment coupled to the rear camera of the smartphone, which contains two white light-emitting-diodes to illuminate the water sample, optical fibers to transmit the light collected from the sample to the camera, an external lens for image formation, and diffusers for uniform illumination of the sample. Including the smartphone, this cost-effective device weighs only ~350 g. In our mobile turbidimeter design, we combined two illumination approaches: transmittance, in which the optical fibers were placed directly below the sample cuvette at 180° with respect to the light source, and nephelometry in which the optical fibers were placed on the sides of the sample cuvette at a 90° angle with respect to the to the light source. Images of the end facets of these fiber optic cables were captured using the smart phone and processed using a custom written image processing algorithm to automatically quantify the turbidity of each sample. Using transmittance and nephelometric readings, our mobile turbidimeter achieved accurate measurements over a large dynamic range, from 0.3 NTU to 2000 NTU. The accurate performance of our smartphone-based turbidimeter was also confirmed with various water samples collected in Los Angeles (USA), bacteria spiked water samples, as well as diesel fuel contaminated water samples. Having a detection limit of ~0.3 NTU, this cost-effective smartphone-based turbidimeter can be a useful analytical tool for screening of water quality in resource limited settings.

Social Disparities in Nitrate-Contaminated Drinking Water in California’s San Joaquin Valley

National Institutes of Health (NIH) | September 1st, 2011

Sonoma Creek Baylands Strategy

Sonoma Land Trust | May 1st, 2020

The purpose of the Strategy is to provide Sonoma Land Trust and partners with a clear and comprehensive plan that coordinates the protection, acquisition, restoration, an

The purpose of the Strategy is to provide Sonoma Land Trust and partners with a clear and comprehensive plan that coordinates the protection, acquisition, restoration, and enhancement of diverse baylands habitats (e.g., subtidal, mudflat, tidal marsh, brackish marsh, freshwater marsh, upland-wetland transition), integrates natural processes to increase climate resilience of the Sonoma Creek Baylands, identifies appropriate public access, and provides recommendations for the redesign of SR 37 and increased connectivity under and across the SMART rail line where they pass through the Sonoma Creek Baylands. 

Source area management practices as remediation tool to address groundwater nitrate pollution in drinking supply wells

Journal of Contaminant Hydrology (Elsevier) | July 19th, 2019

Nitrate in drinking water may cause serious health problems for consumers. Agricultural activities are known to be the main source of groundwater nitrate contaminating ru

Nitrate in drinking water may cause serious health problems for consumers. Agricultural activities are known to be the main source of groundwater nitrate contaminating rural domestic and urban public water supply wells in farming regions. Management practices have been proposed to reduce the amount of nitrate in groundwater, including improved nutrient management practices and “pump and fertilize” with nitrate-affected irrigation wells. Here, we evaluate the feasibility and long-term impacts of agricultural managed aquifer recharge (Ag-MAR) in the source area of public water supply wells. A numerical model of nitrate fate and transport was developed for the Modesto basin, part of California's Central Valley aquifer system. The basin is representative of semi-arid agricultural regions around the world with a diversity of crop types, overlying an unconsolidated sedimentary aquifer system. A local public supply well in an economically disadvantaged community surrounded by farmland was the focus of this study. Model scenarios implemented include business as usual, alternative low-impact crops, and Ag-MAR in the source area of the public supply well. Alternative nutrient management and recharge practices act as remediation tools in the area between farmland and the public supply well. Improved agricultural source area management practices are shown to be an effective tool to maintain or even enhance groundwater quality in the targeted supply well while remediating ambient groundwater.

Sources of high-chloride water and managed aquifer recharge in an alluvial aquifer in California, USA

Hydrogeology Journal (Springer) | July 3rd, 2015

Sources, Pathways and Loadings: Multi-Year Synthesis with a Focus on PCBs and Hg

San Francisco Estuary Institute (SFEI) | December 15th, 2015

This report provides a synthesis of information gathered since 2000 on sources, pathways, and loadings of pollutants of concern in the San Francisco Bay Area with a focus

This report provides a synthesis of information gathered since 2000 on sources, pathways, and loadings of pollutants of concern in the San Francisco Bay Area with a focus on polychlorinated biphenyls (PCBs) and total mercury (Hg). Concentration and load estimates for other pollutants of concern (POC) are provided in the Appendix tables but not supported by any synthesis or discussion in the main body of the report. The PCB and Hg TMDLs for San Francisco Bay call for implementation of control measures to reduce stormwater PCB loads from 20 kg to 2 kg by 2030 and to reduce stormwater Hg loads from 160 kg to 80 kg by 2028 with an interim milestone of 120 kg by 2018. These are very challenging objectives given that the 2 kg PCB load allocation translates to a mean annual yield of 0.31 g/km2 for the free flowing areas downstream from reservoirs (6,650 km2), a mean annual concentration of 1.33 ng/L (assuming an annual average flow from small tributaries of 1.5 km3), and mean annual particle ratio of 1.4 ng/g of suspended sediment load (assuming an average annual suspended sediment load of 1.4 million metric t). Similarly for Hg, the 80 kg load allocation translates to a mean annual yield of 12 g/km2, a mean annual concentration of 53 ng/L, and mean annual particle ratio of 58 ng/g of suspended sediment load. Concentrations of these low magnitudes have been observed commonly in the Bay Area for Hg and yields of this low magnitude have been observed for PCBs and Hg. However, concentrations of PCBs at these magnitudes have only been observed in Marsh Creek (a more rural watershed) and particle ratios of PCBs and Hg as low as these have never been observed in the region.

South Kings Groundwater Sustainability Agency Groundwater Sustainability Plan

South Kings Groundwater Sustainability Agency | December 19th, 2019

South San Francisco Bay Salt Pond Restoration Project— A Synthesis of Phase-1 Mercury Studies

U.S. Geological Survey (USGS) | March 7th, 2023

The South Bay Salt Pond Restoration Project (SBSPRP) encompasses over 6,000 hectares of former salt production ponds along the south edge of the San Francisco Bay and rep

The South Bay Salt Pond Restoration Project (SBSPRP) encompasses over 6,000 hectares of former salt production ponds along the south edge of the San Francisco Bay and represents the largest wetland restoration effort on the west coast of North America. A series of studies associated with Phase 1 (2010–2018) restoration activities that are focused on a historically mercury contaminated slough and series of ponds within the restoration area have recently been completed. This report brings together the key findings of these loosely coordinated studies and integrates the results into a more comprehensive and holistic product that informs future restoration activities associated with the SBSPRP and elsewhere.

Spectral characterization of dissolved organic matter in groundwater to assess mixing with oil-field water near selected oil fields, southern California

Science of The Total Environment (Elsevier) | September 16th, 2023