Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

American Association for the Advancement of Science (AAAS) | October 24th, 2024

Prioritization of Oil and Gas Fields for Regional Groundwater Monitoring Based on a Preliminary Assessment of Petroleum Resource Development and Proximity to California’s Groundwater Resources

U.S. Geological Survey (USGS) | July 20th, 2018

The California State Water Resources Control Board initiated a regional monitoring program in July 2015 to determine where and to what degree groundwater quality may be a

The California State Water Resources Control Board initiated a regional monitoring program in July 2015 to determine where and to what degree groundwater quality may be adversely impacted by oil and gas development activities. A key issue in the implementation of the regional groundwater monitoring program is that each year, detailed characterization work can be done in only a few of California’s 487 onshore oil and gas fields. The first step in monitoring groundwater near petroleum development is to prioritize oil and gas fields using consistent statewide analysis of available data that indicate potential risk of groundwater to oil and gas development. The U.S. Geological Survey compiled data for four factors that characterize the intensity of petroleum resource development and proximity to groundwater resources: petroleum-well density, volume of water injected in oil fields, vertical proximity of groundwater resources to oil and gas resource development, and water-well density. An overall priority ranking for each field was determined by computing summary metrics, analyzing statewide distributions of summary metrics for all oil and gas fields, using those distributions to define relative categories of potential risk for each factor, and combining relative risk rankings for different factors into an overall priority ranking. This preliminary assessment does not represent an evaluation of groundwater risk to oil and gas development, which needs to be based on detailed analysis and data related to development activities including well stimulation, well integrity issues, produced water ponds, and underground injection. Based on the prioritization analysis, 22 percent (107 fields) of the total number of oil and gas fields in California were ranked as high priority, 23 percent (114 fields) as moderate priority, and 55 percent (266 fields) as low priority. These results indicate that between 100 and 200 oil fields are principal candidates for the next steps in the regional monitoring program. The land area of fields that ranked high priority accounted for 41 percent of the total field area (3,392 square miles). More than half of the high priority fields were in the southern San Joaquin Valley and the Los Angeles Basin. Some of the larger fields tended to have higher rankings because of greater intensity of petroleum development, sometimes coupled with proximity to groundwater resources. The U.S. Geological Survey, in collaboration with the California State Water Resources Control Board and other agencies, has begun regional groundwater monitoring near oil and gas fields selected for study through the California Oil, Gas, and Groundwater cooperative program. Groundwater monitoring includes compiling, analyzing, and developing three-dimensional visualizations of existing data, including geological frameworks, salinity mapping, identification of surface features that could potentially affect groundwater quality, locations and depths of oil/gas and water wells, cataloging well-construction integrity issues, and evaluating the directions of groundwater flow. These analyses are required to determine where existing wells should be monitored and where new monitoring wells may need to be drilled.

Proposed Drinking Water Cost Assessment Model Assumptions on Physical Consolidation

California State Water Resources Control Board (SWRCB) | July 14th, 2023

The State Water Resources Control Board (State Water Board) is proposing an updated methodology for estimating potential modeled physical consolidation costs for Failing

The State Water Resources Control Board (State Water Board) is proposing an updated methodology for estimating potential modeled physical consolidation costs for Failing public water systems, At-Risk public water systems, state small water systems, and domestic wells. Non-consolidation options will be covered in detail in subsequent white papers.

Proposed Health-Protective Concentration for the Noncancer Effects of Hexavalent Chromium in Drinking Water

California Environmental Protection Agency (CalEPA) | November 21st, 2023

Public and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA

Environment International (Elsevier) | March 19th, 2021

Humans are primary drivers of environmental contamination worldwide, including in drinking-water resources. In the United States (US), federal and state agencies regulate

Humans are primary drivers of environmental contamination worldwide, including in drinking-water resources. In the United States (US), federal and state agencies regulate and monitor public-supply drinking water while private-supply monitoring is rare; the current lack of directly comparable information on contaminant-mixture exposures and risks between private- and public-supplies undermines tapwater (TW) consumer decision-making. Methods: We compared private- and public-supply residential point-of-use TW at Cape Cod, Massachusetts, where both supplies share the same groundwater source. TW from 10 private- and 10 public-supply homes was analyzed for 487 organic, 38 inorganic, 8 microbial indicators, and 3 in vitro bioactivities. Concentrations were compared to existing protective health-based benchmarks, and aggregated Hazard Indices (HI) of regulated and unregulated TW contaminants were calculated along with ratios of in vitro exposure-activity cutoffs. Results: Seventy organic and 28 inorganic constituents were detected in TW. Median detections were comparable, but median cumulative concentrations were substantially higher in public supply due to 6 chlorine–disinfected samples characterized by disinfection byproducts and corresponding lower heterotrophic plate counts. Public-supply applicable maximum contaminant (nitrate) and treatment action (lead and copper) levels were exceeded in private-supply TW samples only. Exceedances of health-based HI screening levels of concern were common to both TW supplies. Discussion: These Cape Cod results indicate comparable cumulative human-health concerns from contaminant exposures in private- and public-supply TW in a shared source-water setting. Importantly, although this study’s analytical coverage exceeds that currently feasible for water purveyors or homeowners, it nevertheless is a substantial underestimation of the full breadth of contaminant mixtures documented in the environment and potentially present in drinking water. Conclusion: Regardless of the supply, increased public engagement in source-water protection and drinking-water treatment, including consumer point-of-use treatment, is warranted to reduce risks associated with long-term TW contaminant exposures, especially in vulnerable populations. 

Public drinking water contaminant estimates for birth cohorts in the Environmental Influences on Child Health Outcomes (ECHO) Cohort

Nature Portfolio (Springer Nature) | August 4th, 2024

We observed significant regional variability in contaminant concentrations across the US. ZCTAs were most likely to exceed the maximum contaminant level for arsenic (n 

We observed significant regional variability in contaminant concentrations across the US. ZCTAs were most likely to exceed the maximum contaminant level for arsenic (n = 100, 1.4%) and the health-protective threshold for total trihalomethanes (n = 3584, 64.0%). A 10% higher proportion of residents who were American Indian/Alaskan Native and Hispanic/Latino was associated with higher arsenic (11%, 95% CI: 7%, 15%; and 2%, 95% CI: 0%, 3%, respectively) and uranium (15%, 95% CI: 10%, 21%; and 9%, 95% CI: 6%, 12%, respectively) concentrations.

Quality of Groundwater Used for Domestic Drinking-Water Supply in the Coachella Valley, 2020

U.S. Geological Survey (USGS) | January 13th, 2023

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

U.S. Geological Survey (USGS) | November 1st, 2024

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domes

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply. The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents— the disinfection by-product chloroform, the gasoline oxygenate methyl tert-butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources, with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

Quality of Groundwater Used for Domestic Supply in the Modesto, Turlock, and Merced Subbasins of the San Joaquin Valley, California

U.S. Geological Survey (USGS) | January 6th, 2023

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domes

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the Modesto, Turlock, and Merced subbasins of the San Joaquin Valley where more than 78,000 residents are estimated to use privately owned domestic wells. Results indicate that inorganic and organic constituents in groundwater were respectively present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 37 percent and 9 percent of the aquifer area used for domestic drinking-water supplies (herein, “domestic groundwater resources”). The most prevalent inorganic constituents exceeding regulatory benchmarks were nitrate, uranium, and arsenic. The only organic constituents exceeding regulatory benchmarks were the fumigant constituents 1,2,3-trichloropropane (1,2,3-TCP) and 1,2-dibromo-3-chloropropane (DBCP), but the herbicides atrazine and simazine were detected at low concentrations below one-tenth of regulatory benchmarks in 30 percent of domestic groundwater resources. Total dissolved solids (TDS) and manganese exceeded aesthetic-based (secondary maximum contaminant level [SMCL]) benchmarks for drinking water in 3 percent and 13 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFAS) were detected in 23 percent of domestic groundwater resources, with 4 percent exceeding California state notification or response levels for specific compounds. Total coliform bacteria were detected in 20 percent of domestic groundwater resources. Elevated concentrations of nitrate, uranium, TDS, and pesticides (fumigant constituents and herbicides) are related to agricultural land use and were typically present at shallow depths up to 75 meters below land surface. Agriculturally derived constituents were detected in wells screened below the Corcoran Clay Member of the Tulare Formation (herein, “Corcoran Clay”) in the southeastern part of the study area, where the Corcoran Clay tends to be shallower and thinner than in areas to the northwest. Nitrate, uranium, and TDS were most prevalent in the northwest part of the study area proximal to the valley trough where soils are poorly drained and agricultural land uses are predominantly grain, alfalfa, and dairy farms. Pesticides tended to occur in groundwater below coarse-grained surficial deposits and within a northwest to southeast trending band along the eastern extent of the Corcoran Clay that typically demarcates the western extent of well-drained soils associated with perennial orchard crops. Elevated concentrations of arsenic tended to occur west of this band in reducing groundwater but also sometimes co-occurred with elevated nitrate in oxic groundwater, most likely because of geochemical conditions in agriculturally affected groundwater that can enhance the mobility of arsenic from aquifer sediments.

Quality of Groundwater Used for Domestic Supply in the Northern San Joaquin Valley, California

U.S. Geological Survey (USGS) | July 28th, 2021

 Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Moni

 Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project (PBP) of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and provides increased public access to groundwater-quality information. Private domestic and small-system drinking-water wells in the Northern San Joaquin Valley (NSJV) were the target for this assessment. These wells tend to pump water from shallower parts of alluvial aquifers compared to deeper, long-screened public-supply wells in the region.