Numerical Simulation of Ground-Water Flow and Assessment of the Effects of Artificial Recharge in the Rialto–Colton Basin, San Bernardino County, California

U.S. Geological Survey (USGS) | July 1st, 2001

Nutrient Chemistry in the Elizabeth Lake Subwatershed: Effects of Onsite Wastewater Treatment Systems on Groundwater and Lake Water Quality, Los Angeles County, California

U.S. Geological Survey (USGS) | April 16th, 2024

Nutrient (nitrogen [N] and phosphorus [P] chemistry) down-gradient from onsite wastewater treatment system (OWTS) was evaluated with a groundwater study in the area surr

Nutrient (nitrogen [N] and phosphorus [P] chemistry) down-gradient from onsite wastewater treatment system (OWTS) was evaluated with a groundwater study in the area surrounding Elizabeth Lake, the largest of three sag lakes within the Santa Clara River watershed of Los Angeles County, California. Elizabeth Lake is listed on the “303 (d) Impaired Waters List” for excess nutrients and is down-gradient from more than 600 OWTS. The primary objective of this study was to develop a conceptual hydrogeological model to determine if discharge from OWTS is transported into shallow groundwater within the Elizabeth Lake subwatershed and contributes nutrients to Elizabeth Lake in excess of the total maximum daily load limit.

Nutrients in the Nation’s Streams and Groundwater, 1992–2004

U.S. Geological Survey (USGS) | June 6th, 2011

This report is one of a series of publications, The Quality of Our Nation’s Waters, which describes major findings of the NAWQA Program on water-quality issues of regio

This report is one of a series of publications, The Quality of Our Nation’s Waters, which describes major findings of the NAWQA Program on water-quality issues of regional and national concern. This report presents an assessment of the occurrence and distribution of nutrients in the Nation’s streams and groundwater based on water-quality data from about 500 streams and over 5,000 wells collected from 1992 through 2001. Other topics addressed include the relation of nutrient conditions to aquatic life in streams, changes in nutrient conditions from 1988 through 2004, and implications for future changes. The information in this series is intended primarily for those interested or involved in resource management and protection, conservation, regulation, and policy-making at regional and national levels. In addition, the information is relevant to those at a local level who wish to know more about the general quality of streams and groundwater in areas near where they live and how that quality compares with other areas across the Nation.

Nutrients in the Nation’s Streams and Groundwater: National Findings and Implications

U.S. Geological Survey (USGS) | September 1st, 2010

A comprehensive national analysis of the distribution and trends of nutrient concentrations in streams and groundwater from 1992 through 2004 is provided by

A comprehensive national analysis of the distribution and trends of nutrient concentrations in streams and groundwater from 1992 through 2004 is provided by the National Water-Quality Assessment (NAWQA) Program of the United States Geological Survey (USGS). Findings describe the distribution and causes of varying nutrient concentrations in streams and groundwater throughout the Nation and examine the primary sources that contribute to elevated concentrations. Results show that excessive nutrient enrichment is a widespread cause of ecological degradation in streams and that nitrate contamination of groundwater used for drinking water, particularly shallow domestic wells in agricultural areas, is a continuing human-health concern. Finally, despite major Federal, State and local non-point-source nutrient control efforts for streams and watersheds across the Nation, USGS trend analyses for 1993–2003 suggest limited national progress to reduce the impacts of non-point sources of nutrients during this period. Instead, concentrations have remained the same or increased in many streams and aquifers across the nation, and continue to pose risks to aquatic life and human health. This Fact Sheet highlights selected national fndings and their implications, and serves as a companion product to the complete analysis reported in the USGS Circular titled “The Quality of Our Nation’s Waters—Nutrients in the Nation’s Streams and Groundwater, 1992–2004.”

Oases of the future? Springs as potential hydrologic refugia in drying climates

Ecological Society of America (Wiley) | June 1st, 2020

Natural springs in water‐limited landscapes are biodiversity hotspots and keystone ecosystems that have a disproportionate influence on surrounding landscapes despite t

Natural springs in water‐limited landscapes are biodiversity hotspots and keystone ecosystems that have a disproportionate influence on surrounding landscapes despite their usually small size. Some springs served as evolutionary refugia during previous climate drying, supporting relict species in isolated habitats. Understanding whether springs will provide hydrologic refugia from future climate change is important to biodiversity conservation but is complicated by hydrologic variability among springs, data limitations, and multiple non‐climate threats to groundwater‐dependent ecosystems. We present a conceptual framework for categorizing springs as potentially stable, relative, or transient hydrologic refugia in a drying climate. Clues about the refugial capacity of springs can be assembled from various approaches, including citizen‐science‐powered ecohydrologic monitoring, remote sensing, landowner interviews, and environmental tracer analysis. Managers can integrate multiple lines of evidence to predict which springs may become future refugia for species of concern, strengthening the long‐term effectiveness of their conservation and restoration, and informing climate adaptation for terrestrial and freshwater species.

Occurrence and sources of radium in groundwater associated with oil fields in the southern San Joaquin Valley, California

American Chemical Society (ACS) | August 7th, 2019

Geochemical data from 40 water wells were used to examine the occurrence and sources of radium (Ra) in groundwater associated with three oil fields in California (Fruitva

Geochemical data from 40 water wells were used to examine the occurrence and sources of radium (Ra) in groundwater associated with three oil fields in California (Fruitvale, Lost Hills, South Belridge). 226Ra+228Ra activities (range = 0.010–0.51 Bq/L) exceeded the 0.185 Bq/L drinking-water standard in 18% of the wells (not drinking-water wells). Radium activities were correlated with TDS concentrations (p < 0.001, ρ = 0.90, range = 145–15,900 mg/L), Mn + Fe concentrations (p < 0.001, ρ = 0.82, range = <0.005–18.5 mg/L), and pH (p < 0.001, ρ = −0.67, range = 6.2–9.2), indicating Ra in groundwater was influenced by salinity, redox, and pH. Ra-rich groundwater was mixed with up to 45% oil-field water at some locations, primarily infiltrating through unlined disposal ponds, based on Cl, Li, noble-gas, and other data. Yet 228Ra/226Ra ratios in pond-impacted groundwater (median = 3.1) differed from those in oil-field water (median = 0.51). PHREEQC mixing calculations and spatial geochemical variations suggest that the Ra in the oil-field water was removed by coprecipitation with secondary barite and adsorption on Mn–Fe precipitates in the near-pond environment. The saline, organic-rich oil-field water subsequently mobilized Ra from downgradient aquifer sediments via Ra-desorption and Mn/Fe-reduction processes. This study demonstrates that infiltration of oil-field water may leach Ra into groundwater by changing salinity and redox conditions in the subsurface rather than by mixing with a high-Ra source.

Occurrence of hexavalent chromium in ground water in the western Mojave Desert, California

Applied Geochemistry (Elsevier) | July 1st, 2004

About 200 samples from selected public supply, domestic, and observation wells completed in alluvial aquifers underlying the western Mojave Desert were analyzed for total

About 200 samples from selected public supply, domestic, and observation wells completed in alluvial aquifers underlying the western Mojave Desert were analyzed for total dissolved Cr and Cr(VI). Because Cr(VI) is difficult to preserve, samples were analyzed by 3 methods. Chromium(VI) was determined in the field using both a direct colorimetric method and EPA method 218.6, and samples were speciated in the field for later analysis in the laboratory using a cation-exchange method developed for the study described in this paper. Comparison of the direct colorimetric method and EPA method 218.6 with the new cation-exchange method yielded r2 values of 0.9991 and 0.9992, respectively. Total dissolved Cr concentrations ranged from less than the 0.1 μg/l detection limit to 60 μg/l, and almost all the Cr present was Cr(VI). Near recharge areas along the mountain front pH values were near neutral, dissolved O2 concentrations were near saturation, and Cr(VI) concentrations were less than the 0.1 μg/l detection limit. Chromium(VI) concentrations and pH values increased downgradient as long as dissolved O2 was present. However, low Cr(VI) concentrations were associated with low dissolved O2concentrations near ground-water discharge areas along dry lakes. Chromium(VI) concentrations as high as 60 μg/l occurred in ground water from the Sheep Creek fan alluvial deposits weathered from mafic rock derived from the San Gabriel Mountains, and Cr(VI) concentrations as high as about 36 μg/l were present in ground water from alluvial deposits weathered from less mafic granitic, metamorphic, and volcanic rocks. Chromium(III) was the predominant form of Cr only in areas where dissolved O2 concentrations were less than 1 mg/l and was detected at a median concentration of 0.1 μg/l, owing to its low solubility in water of near-neutral pH. Depending on local hydrogeologic conditions and the distribution of dissolved O2, Cr(VI) concentrations may vary considerably with depth. Samples collected under pumping conditions from different depths within wells show that Cr(VI) concentrations can range from less than the 0.1 μg/l detection limit to 36 μg/l in a single well and that dissolved O2 concentrations likely control the concentration and redox speciation of Cr in ground water.

Occurrence of natural and anthropogenic hexavalent chromium (Cr VI) in groundwater near a mapped plume, Hinkley, CA

U.S. Geological Survey (USGS) | March 22nd, 2018

This report describes (1) work done between January 2015 and May 2017 as part of the U.S. Geological Survey (USGS) hexavalent chromium, Cr(VI), background study and (2) t

This report describes (1) work done between January 2015 and May 2017 as part of the U.S. Geological Survey (USGS) hexavalent chromium, Cr(VI), background study and (2) the summative-scale approach to be used to estimate the extent of anthropogenic (man-made) Cr(VI) and background Cr(VI) concentrations near the Pacific Gas and Electric Company (PG&E) natural gas compressor station in Hinkley, California. Most of the field work for the study was completed by May 2017. The summative-scale approach and calculation of Cr(VI) background were not well-defined at the time the USGS proposal for the background Cr(VI) study was prepared but have since been refined as a result of data collected as part of this study. The proposed summative scale consists of multiple items, formulated as questions to be answered at each sampled well. Questions that compose the summative scale were developed to address geologic, hydrologic, and geochemical constraints on Cr(VI) within the study area. Each question requires a binary (yes or no) answer. A score of 1 will be assigned for an answer that represents data consistent with anthropogenic Cr(VI); a score of –1 will be assigned for an answer that represents data inconsistent with anthropogenic Cr(VI). The areal extent of anthropogenic Cr(VI) estimated from the summative-scale analyses will be compared with the areal extent of anthropogenic Cr(VI) estimated on the basis of numerical groundwater flow model results, along with particle-tracking analyses. On the basis of these combined results, background Cr(VI) values will be estimated for “Mojave-type” deposits, and other deposits, in different parts of the study area outside the summative-scale mapped extent of anthropogenic Cr(VI). 

Occurrence of water and thermogenic gas from oil-bearing formations in groundwater near the Orcutt Oil Field, California, USA

Journal of Hydrology: Regional Studies (Elsevier) | April 11th, 2022

Study region: Santa Barbara County, California, USA. Study focus: To analyze a wide array of newly collected chemical, isotopic, dissolved gas, and age dating tracers

Study region: Santa Barbara County, California, USA. Study focus: To analyze a wide array of newly collected chemical, isotopic, dissolved gas, and age dating tracers in conjunction with historical data from groundwater and oil wells to determine if water and/or thermogenic gas from oil-bearing formations have mixed with groundwater in the Orcutt Oil Field and surrounding area. New hydrological insights for the region: Three of 15 groundwater samples had compositions indicating potential mixing with water and/or thermogenic gas from oil-bearing formations. Relevant indicators included salinity tracers (TDS, Cl, Br), NH3, DOC, enriched δ13C-DIC, δ2H- CH4, δ13C-CH4, and δ13C-C2H6 values, and trace amounts of C3-C5 gas. The potential sources/ pathways for oil-bearing formation water and/or thermogenic gas in groundwater overlying and adjacent to the Orcutt Oil Field include: (1) upward movement from formations developed for oil production due to: (a) natural migration; or (b) anthropogenic activity such as injection and/or movement along wellbores; and (2) oil and gas shows in overlying non-producing oil-bearing formations. Groundwater age tracers, elevated 4He concentrations, and isotopic compositions of noble gases indicated legacy produced water ponds were not a source. This phase of the study relied on samples and data from existing infrastructure. Additional data on potential end-member compositions from new and existing wells and assessments of potential vertical head gradients and pathways between oil and groundwater zones may yield additional insight.

Oil, Food, and Water: Challenges and Opportunities for California Agriculture

Pacific Institute | December 1st, 2015

A new comprehensive study by the Pacific Institute  sheds light on the risks posed when oil and gas exploration and production operate alongside agriculture. “There

A new comprehensive study by the Pacific Institute  sheds light on the risks posed when oil and gas exploration and production operate alongside agriculture. “There is growing concern about competition for land and water, and the impacts of soil and water contamination on the food supply and health and safety of farmworkers and consumers,” said Matthew Heberger, the study’s lead author. The disposal of oil and gas wastewater, which contains harmful chemicals, is a particular concern for agriculture. Disposal in unlined percolation pits poses a significant risk of contaminating groundwater resources that may, in turn, be used by agriculture. While this practice has been banned in several states, it is still widely used in California’s Central Valley, one of the nation’s most important agricultural regions. There are also serious deficiencies in the way California regulates the underground injection of wastes – current practices are not sufficiently protective of freshwater aquifers that may be used as drinking water or to irrigate crops and water livestock.