South Lahontan

California’s Water: Protecting Headwaters

Public Policy Institute of California (PPIC) | October 1st, 2016

Mountainous regions provide most of the state’s water supply. But major problems loom— from a growing risk of wildfires to a shrinking snowpack. This brief outlin

Mountainous regions provide most of the state’s water supply. But major problems loom— from a growing risk of wildfires to a shrinking snowpack. This brief outlines ways California and the federal government—the largest landowner in headwater areas—could address critical problems in these areas. This publication is part of a briefing kit that summarizes a dozen of the state’s most pressing water management issues.

Californians Without Safe Water and Sanitation: California Water Plan Update 2013

California Department of Water Resources (DWR) | February 20th, 2015

This report was prepared as part of the California Water Plan Update 2013 process and is an update to the 2005 Californians without Safe Water report. It continues the d

This report was prepared as part of the California Water Plan Update 2013 process and is an update to the 2005 Californians without Safe Water report. It continues the dialogue regarding Californians without safe drinking water and/or adequate sanitation facilities and includes 14 recommendations towards ensuring that all Californians have safe drinking water and adequate sanitation facilities. The report also highlights Governor Brown’s goal of ensuring that all Californians have access to safe drinking water, as specified by his signing of Assembly Bill (AB) 685 and the release of the California Water Action Plan that includes Action 7, “Provide Safe Water for All Communities.”

CaliPopGen: A genetic and life history database for the fauna and flora of California

Nature Portfolio (Springer Nature) | July 5th, 2022

CaliPopGen is a database of population genetic data for native and naturalized eukaryotic species in California, USA. It summarizes the published literature (1985–2020)

CaliPopGen is a database of population genetic data for native and naturalized eukaryotic species in California, USA. It summarizes the published literature (1985–2020) for 5,453 unique populations with genetic data from more than 187,394 individuals and 448 species (513 species plus subspecies) across molecular markers including allozymes, RFLPs, mtDNA, microsatellites, nDNA, and SNPs. Terrestrial habitats accounted for the majority (46.4%) of the genetic data. Taxonomic groups with the greatest representation were Magnoliophyta (20.31%), Insecta (13.4%), and Actinopterygii (12.85%). CaliPopGen also reports life-history data for most included species to enable analyses of the drivers of genetic diversity across the state. The large number of populations and wide taxonomic breadth will facilitate explorations of ecological patterns and processes across the varied geography of California. CaliPopGen covers all terrestrial and marine ecoregions of California and has a greater density of species and georeferenced populations than any previously published population genetic database. It is thus uniquely suited to inform conservation management at the regional and state levels across taxonomic groups.

CASGEM Alternative Monitoring Plan Fact Sheet

California Department of Water Resources (DWR) | August 15th, 2023

Causes of the Extreme Dry Conditions over California During Early 2013

American Meteorological Society (AMS) | September 30th, 2014

The state of California experienced extreme dry conditions during early 2013. In particular, January and February received 28% and 15%, respectively, of their nor

The state of California experienced extreme dry conditions during early 2013. In particular, January and February received 28% and 15%, respectively, of their normal monthly rainfall. When January and February are combined, January/ February 2013 is ranked as the driest of the period 1895–2014. Such large precipitation deficits exerted enormous stress on water resources in an already high water-demand region. Thus, it is of practical importance to investigate the causes of this extreme climate event so as to assess its predictability. *Chapter 3, Explaining Extreme Events of 2013 from a Climate Perspective, Bull. Amer. Meteor. Soc., 95 (9)

Changes in Riparian Vegetation in the Southwestern United States: Historical Changes along the Mojave River, California

U.S. Geological Survey (USGS) | January 31st, 2001

Chapter A of Natural and Anthropogenic (Human-Made) Hexavalent Chromium, Cr(VI), in Groundwater near a Mapped Plume, Hinkley, California: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study

U.S. Geological Survey (USGS) | April 25th, 2023

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and Selected Element Concentrations in Rock, Alluvium, and Core Material Chapter C: Chromium in Minerals and Selected Aquifer Materials Chapter D: Analyses of Regulatory Water-Quality Data Chapter E: Groundwater Chemistry and Hexavalent Chromium Chapter F: Environmental Tracers of Groundwater Source, Age, and Geochemical Evolution Chapter G: Evaluation of Natural and Anthropogenic (Human-Made) Hexavalent Chromium Chapter H: Predevelopment Water Levels, Groundwater Recharge, and Selected Hydrologic Properties of Aquifer Materials, Hinkley and Water Valleys, California Chapter I: Sequestration and Reoxidation of Chromium in Experimental Microcosms Chapter J: Summary and Conclusions Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert 80 miles (mi) northeast of Los Angeles, California. Remediation began in 1992, and in 2010, site cleanup was projected to require between 10 and 95 years and was expected to cost between $36 and $176 million. A 2007 PG&E study estimated the natural Cr(VI) background in groundwater in Hinkley Valley to be 3.1 micrograms per liter (μg/L). This concentration was used for interim regulatory purposes by the Lahontan Regional Water Quality Control Board (RWQCB). In the fourth quarter (October–December) 2015, the regulatory Cr(VI) plume extended about 3.0 mi downgradient from the release location within the Hinkley compressor station, while groundwater having Cr(VI) concentrations greater than 3.1 μg/L was present more than 8 mi downgradient. Although rocks and minerals in the area are naturally low in chromium, alluvium eroded from the San Gabriel Mountains and transported to Hinkley Valley by the Mojave River, and locally small exposures of mafic rock, including hornblende diorite and basalt, may contribute Cr(VI) to groundwater. In response to limitations of the PG&E 2007 Cr(VI) background study’s methodology, uncertainty in the natural Cr(VI) background concentration, and an increase in the mapped extent of groundwater having Cr(VI) concentrations greater than the interim regulatory background of 3.1 μg/L, the Lahontan RWQCB concluded that the 2007 PG&E background Cr(VI) study should be updated. The purpose of the updated study is to estimate background Cr(VI) concentrations in groundwater within the upper aquifer upgradient, downgradient, near the margins, and within the footprint of the PG&E Cr(VI) plume in Hinkley, California. The scope of the study included eight tasks; results from those tasks are presented in the chapters within this professional paper.

Chapter B of Natural and Anthropogenic (Human-Made) Hexavalent Chromium, Cr(VI), in Groundwater near a Mapped Plume, Hinkley, California: Survey of Chromium and Selected Element Concentrations in Rock, Alluvium, and Core Material

U.S. Geological Survey (USGS) | April 25th, 2023

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and Selected Element Concentrations in Rock, Alluvium, and Core Material Chapter C: Chromium in Minerals and Selected Aquifer Materials Chapter D: Analyses of Regulatory Water-Quality Data Chapter E: Groundwater Chemistry and Hexavalent Chromium Chapter F: Environmental Tracers of Groundwater Source, Age, and Geochemical Evolution Chapter G: Evaluation of Natural and Anthropogenic (Human-Made) Hexavalent Chromium Chapter H: Predevelopment Water Levels, Groundwater Recharge, and Selected Hydrologic Properties of Aquifer Materials, Hinkley and Water Valleys, California Chapter I: Sequestration and Reoxidation of Chromium in Experimental Microcosms Chapter J: Summary and Conclusions Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from the Pacific Gas and Electric Company (PG&E) compressor station in Hinkley, California, in the western Mojave Desert 80 miles northeast of Los Angeles, California. In 2015, the extent of anthropogenic Cr(VI) in groundwater in Hinkley and Water Valleys was uncertain, and some Cr(VI) in groundwater may be naturally occurring from rock and aquifer material. On the basis of more than 1,500 portable (handheld) X-ray fluorescence (pXRF) measurements on more than 250 samples of rock, surficial alluvium, and core material from selected wells in Hinkley and Water Valleys, chromium concentrations are commonly low compared to the average bulk continental abundance of 185 milligrams per kilogram (mg/kg). However, chromium concentrations are as high as 530 mg/kg in mafic hornblende diorite that crops out along the western margin of Hinkley Valley in Iron Mountain. Other chromium-containing rocks in the area are either (1) not consistently high in chromium, (2) have limited areal extent, or (3) in the case of basalt, are present only in Water Valley. Chromium concentrations in core material adjacent to the screened intervals of wells sampled for water chemistry and isotopic composition as part of the U.S. Geological Survey Cr(VI) background study ranged from less than the study reporting level (SRL) of 5 mg/kg to 410 mg/kg, with a median concentration of 23 mg/kg. Chromium concentrations in core material were lower in the eastern subarea and higher in the western and the northern subareas of Hinkley Valley and in Water Valley. The highest chromium concentration in core material was in weathered hornblende diorite bedrock. Chromium concentrations in core material adjacent to the screened interval of sampled wells were log-normally distributed below a threshold of 85 mg/kg, and 3 percent of chromium concentrations were greater than 85 mg/kg. Manganese can oxidize trivalent chromium, Cr(III), to Cr(VI). Similar to chromium, manganese concentrations in core material also were log-normally distributed below a threshold of 970 mg/kg, and 5 percent of manganese concentrations were greater than 970 mg/kg. Both chromium and manganese concentrations were higher in fine-textured core material and in visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains. High concentrations of chromium and manganese in core material commonly co-occurred. Fine-textured core material, chromium concentrations greater than 85 mg/kg, and manganese concentrations greater than 970 mg/kg in core material adjacent to the screened interval of sampled wells were selected for use as metrics (threshold values) within a summative-scale analysis (SSA) developed to identify natural and anthropogenic Cr(VI) in water from wells later within this professional paper (chapter G). Principal component analysis (PCA) of 18 elements within surficial alluvium, rock, and core material measured using pXRF shows distinct elemental assemblages associated with (1) older and more recent “Mojave-type” deposits, including alluvium and lake-margin (beach) deposits sourced from the Mojave River, (2) alluvium eroded from mafic rock, including hornblende diorite that crops out on Iron Mountain, (3) alluvium eroded from felsic volcanic and hydrothermal rock that crops out on Mount General along the eastern margin of Hinkley Valley, (4) playa/mudflat and other fine-textured deposits, and (5) material with visually abundant iron- and manganese-oxide coatings. Most wells sampled as part of this study were completed in Mojave-type deposits. Portable (handheld) X-ray fluorescence data measured on core material from those wells do not appear to be different or unusual compared to the magnitude and range of data from the larger Mojave River groundwater basin, and the core material has a low-chromium, felsic composition consistent with a Mojave River origin. In general, the elemental composition of core material from wells was not measurably altered by admixtures with local mafic, felsic volcanic, or hydrothermal source materials; although, where present, admixtures with basalt may contribute chromium to core material.

Chapter C of Natural and Anthropogenic (Human-Made) Hexavalent Chromium, Cr(VI), in Groundwater near a Mapped Plume, Hinkley, California: Chromium in Minerals and Selected Aquifer Materials

U.S. Geological Survey (USGS) | April 25th, 2023

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and Selected Element Concentrations in Rock, Alluvium, and Core Material Chapter C: Chromium in Minerals and Selected Aquifer Materials Chapter D: Analyses of Regulatory Water-Quality Data Chapter E: Groundwater Chemistry and Hexavalent Chromium Chapter F: Environmental Tracers of Groundwater Source, Age, and Geochemical Evolution Chapter G: Evaluation of Natural and Anthropogenic (Human-Made) Hexavalent Chromium Chapter H: Predevelopment Water Levels, Groundwater Recharge, and Selected Hydrologic Properties of Aquifer Materials, Hinkley and Water Valleys, California Chapter I: Sequestration and Reoxidation of Chromium in Experimental Microcosms Chapter J: Summary and Conclusions Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from a Pacific Gas and Electric Company (PG&E) compressor station in Hinkley, California, in the western Mojave Desert 80 miles northeast of Los Angeles, California. In 2015, the extent of anthropogenic Cr(VI) in groundwater in Hinkley and Water Valleys was uncertain, but some Cr(VI) in groundwater may be naturally occurring from rock and aquifer material. To evaluate potential sources of natural Cr(VI), chromium and other selected trace-element concentrations were measured by inductively coupled plasma-mass spectrometry (ICP-MS), with multi-acid digestion, on 34 samples of surficial alluvium and core material from Hinkley and Water Valleys, California, and on 2 samples of alluvium from the mafic Sheep Creek fan to the southwest. Chromium concentrations in Hinkley and Water Valleys ranged from 2 to 110 milligrams per kilogram (mg/kg), with a median concentration of 14 mg/kg; concentrations were highest in weathered mafic hornblende diorite associated with Iron Mountain. High chromium concentrations also were present within fine-textured materials and visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains. For comparison, chromium concentrations as high as 170 mg/kg were measured in mafic alluvium from the Sheep Creek fan. In contrast, chromium concentrations were lowest in Mojave-type deposits (Mojave River stream and lake margin deposits), with a median of 6 mg/kg. Chromium concentrations measured by ICP-MS compared favorably with concentrations measured by portable (handheld) X-ray fluorescence (pXRF; chapter B), on the basis of least-squares regression results and a coefficient of determination (R2) of 0.97. Minerals in bulk samples and the heavy (dense) mineral fractions isolated from those samples were identified using optical techniques, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Quartz and feldspar were the most abundant minerals, especially within recent and older Mojave River deposits. Chromium concentrations were as high as 1,250 mg/kg in the heavy-mineral fraction, with specific gravity greater than 3.32. Chromium was not commonly detected in the light-mineral fraction, with specific gravity less than 2.85. Most chromium within the heavy-mineral fraction was substituted within magnetite mineral grains less than 100 micrometers (μm) in diameter, and almost no chromite was present within the heavy-mineral fraction. Although magnetite is resistive to weathering, weathering of magnetite to hematite was identified (1) in Miocene materials underlying unconsolidated deposits in the western subarea of Hinkley Valley and (2) in alluvium within Water Valley that contains weathered minerals eroded from Miocene rock. Less-dense, more easily weathered chromium-containing amphiboles, such as actinolite in older Mojave River alluvium and hornblende in locally derived alluvium from Iron Mountain, were identified optically. Magnetite was not identified in weathered hornblende diorite and was less abundant in locally derived materials and in Miocene materials than in Mojave-type deposits. A comparison of ICP-MS data and sequential extraction data shows that approximately 90 percent of chromium in aquifer material within Hinkley and Water Valleys was not extractable and was interpreted to reside within unweathered mineral grains. Most extractable chromium was within the strong acid extractable fraction. Chromium within the weakly sorbed, and specifically sorbed extractable fractions in oxide accumulations within the regulatory Cr(VI) plume is potentially mobile into groundwater with changes in ionic strength or pH. Although Hinkley and Water Valleys are regionally low in chromium, natural geologic sources of chromium may be present in aquifer materials penetrated by wells completed in (1) weathered hornblende diorite bedrock underlying the western subarea; (2) Miocene deposits underlying the western subarea and unconsolidated material in the northern subarea and Water Valley containing basalt or weathered minerals eroded from Miocene deposits; (3) unconsolidated material containing visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains that are present near the water table and near lithologic or geologic contacts; and (4) brown clay and mudflat/playa deposits in the northern subarea. Brown clay and mudflat/playa deposits in the eastern subarea near Mount General have a low-chromium, felsic mineralogy similar to Mojave River deposits and do not contain high concentrations of chromium; however, manganese(IV) oxides within these materials may facilitate oxidation of trivalent chromium, Cr(III), to Cr(VI). In general, admixtures of geologic material eroded from various source terrains that were identified within Mojave-type deposits do not appear to greatly alter the elemental composition of the unconsolidated material composing aquifers in Hinkley and Water Valleys. Chemical and mineralogic data did not indicate high natural abundance, unusual mineralogy, or unusual sorptive properties for chromium on the surfaces of mineral grains within older Mojave River alluvium downgradient from the “western excavation site” in the western subarea.

Chapter D of Natural and Anthropogenic (Human-Made) Hexavalent Chromium, Cr(VI), in Groundwater near a Mapped Plume, Hinkley, California Hinkley Valley: Analyses of Regulatory Water-Quality Data

U.S. Geological Survey (USGS) | April 25th, 2023

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and

Documents in this series: Chapter A: Introduction to Study Area Hydrogeology, Chromium Sources, Site History, and Purpose of Study Chapter B: Survey of Chromium and Selected Element Concentrations in Rock, Alluvium, and Core Material Chapter C: Chromium in Minerals and Selected Aquifer Materials Chapter D: Analyses of Regulatory Water-Quality Data Chapter E: Groundwater Chemistry and Hexavalent Chromium Chapter F: Environmental Tracers of Groundwater Source, Age, and Geochemical Evolution Chapter G: Evaluation of Natural and Anthropogenic (Human-Made) Hexavalent Chromium Chapter H: Predevelopment Water Levels, Groundwater Recharge, and Selected Hydrologic Properties of Aquifer Materials, Hinkley and Water Valleys, California Chapter I: Sequestration and Reoxidation of Chromium in Experimental Microcosms Chapter J: Summary and Conclusions Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert 80 miles northeast of Los Angeles, California. The Pacific Gas and Electric Company has monitored groundwater near Hinkley, California, for Cr(VI) and other constituents since the late 1980s. By June 2017, more than 20,000 samples had been collected and analyzed for Cr(VI) for regulatory purposes. Most Cr(VI) samples were analyzed using the U.S. Environmental Protection Agency (EPA) Method 218.6 with a laboratory reporting level (LRL) of 0.2 micrograms per liter (μg/L). Between July 2012 and June 2017, selected samples were analyzed for low-level Cr(VI) concentrations using a modified version of EPA Method 218.6 with an LRL of 0.06 μg/L. Field-blank data and duplicate samples collected during this period indicate a study reporting level (SRL) of 0.2 μg/L for most analyses and a SRL of 0.12 μg/L for low-level Cr(VI) analyses. The overall precision for Cr(VI) data analyzed by both methods at the interim regulatory Cr(VI) background concentration of 3.1 μg/L was 0.09 μg/L, or about 3 percent. Hexavalent chromium concentration trends were calculated for 564 monitoring wells for the period from July 2012 through June 2017. Upward Cr(VI) concentration trends were present in water from 102 monitoring wells throughout Hinkley and Water Valleys. Upward Cr(VI) concentration trends in water from wells near the margins of the October–December 2015 (Q4 2015) regulatory Cr(VI) plume (1) within strands of the Lockhart fault east and southeast of the Hinkley compressor station and (2) in water from shallow wells within the northern subarea were consistent with expansion of the Cr(VI) plume in these areas between 2012 and 2017. Upward Cr(VI) concentration trends were widely distributed elsewhere in Hinkley and Water Valleys outside the Q4 2015 regulatory Cr(VI) plume and were commonly associated with declining water levels. These upward trends may result from natural Cr(VI) sources, including movement of Cr(VI) containing groundwater from (1) weathered bedrock, (2) fine-textured deposits, or (3) secondarily oxidized material distributed throughout aquifer deposits. Downward Cr(VI) concentration trends were observed in 146 monitoring wells. Downward trends and can be attributed to remediation activities downgradient from the Hinkley compressor station. Hexavalent chromium concentration trends also were calculated for 219 domestic wells from July 2012 through June 2017. Upward Cr(VI) concentration trends in 8 domestic wells and downward trends in 23 domestic wells were clustered largely within former residential areas west of the Q4 2015 regulatory Cr(VI) plume. Results of Cr(VI) trend analyses (including upward, downward, and no trend) were used with other data as part of a summative-scale analysis (chapter G) to define the extent of anthropogenic Cr(VI) and natural Cr(VI) within Hinkley and Water Valleys.