Regional patterns in hydrologic response, a new three-component metric for hydrograph analysis and implications for ecohydrology, Northwest Volcanic Aquifer Study Area, USA

Journal of Hydrology (Elsevier) | June 12th, 2020

Spatial patterns of hydrologic response were examined for the Northwest Volcanic Aquifer Study Area (NVASA). The utility of established hydrograph-separation methods for

Spatial patterns of hydrologic response were examined for the Northwest Volcanic Aquifer Study Area (NVASA). The utility of established hydrograph-separation methods for assessing hydrologic response in permeable volcanic terranes was assessed and a new three-component metric for hydrograph analysis was developed. The new metric, which partitions streamflow into subcomponents defined by the timescales of hydrologic response (e.g., fast-runoff, intermediate-interflow and slow-baseflow), was used to gain a fundamental understanding of the regional hydrology, investigate sub-regional differences, influencing factors, and ecohydrological implications. The combined effects of NVASA’s physiography, climate and geology create a strongly coupled surface-groundwater system that produces copious baseflow and limited quantities of runoff and interflow. Patterns of hydrologic response are influenced by the type and rate of precipitation and permeability of the underlying geology. Under variable precipitation conditions the hydrologic response of volcanic terranes with similar permeability and subsurface-storage capacity can be significantly different. From a water management and ecohydrology perspective, understanding regional patterns of hydrologic response and sub-regional differences is fundamental. Results indicate that minimum-flow methods provide the most conservative estimate of baseflow and may be the most robust for filtering out snowmelt bias in baseflow estimates. Baseflow contributes ∼75% of the perennial streamflow across the NVASA and represents a critical component of the regional water supply that provides critical cold-water habitat.

Regional patterns in the geochemistry of oil-field water, southern San Joaquin Valley, California, USA

Applied Geochemistry (Elsevier) | September 21st, 2018

Chemical and isotopic data for water co-extracted with hydrocarbons in oil and gasfields are commonly used toexamine the source of the formation water and possible impact

Chemical and isotopic data for water co-extracted with hydrocarbons in oil and gasfields are commonly used toexamine the source of the formation water and possible impacts on groundwater in areas of oil and gas de-velopment. Understanding the geochemical variability of oil-field water could help to evaluate its origin anddelineate possible contamination of shallow aquifers in cases where oil-field water is released to the environ-ment. Here we report geochemical and multiple isotope (H, C, O, Sr, Ra) data from 22 oil wells, three sources ofproduced water that are disposed of in injection wells, and two surface disposal ponds in four oilfields in thesouthern San Joaquin Valley, California (Fruitvale, Lost Hills, North and South Belridge). Correlations betweenCl andδ18O, as well as other ions, and gradual increases in salinity with depth, indicate dilution of one or moresaline end-members by meteoric water. The saline end-members, represented by deep samples (610 m–2621 m)in three oil-bearing zones, are characterized by NaeCl composition, near-seawater Cl concentrations (median20,000 mg/L), enrichedδ18OeH2O (median 3.4‰), high ammonium (up to 460 mg-N/L), and relatively highradium activity (226Ra+228Ra = 12.3 Bq/L). The deepest sample has low Na/Cl (0.74), high Ca/Mg (5.0), andlow87Sr/86Sr (0.7063), whereas the shallower samples have higher Na/Cl (0.86–1.2), Ca/Mg near 1, and higher87Sr/86Sr (∼0.7083). The data are consistent with an original seawater source being modified by various depthand lithology dependent diagenetic processes. Dilution by meteoric water occurs naturally on the east side of thevalley, and in association with water-injection activities on the west side. Meteoric-waterflushing, particularlyon the east side, results in lower solute concentrations (minimum total dissolved solids 2730 mg/L) and totalradium (minimum 0.27 Bq/L) in oil-field water, and promotes biodegradation of dissolved organic carbon andhydrocarbon gases like propane. Acetate concentrations andδ13C of dissolved inorganic carbon indicate biogenicmethane production occurs in some shallow oil zones. Natural and human processes produce substantialvariability in the geochemistry of oil-field water that should be considered when evaluating mixing between oil-field waters and groundwater. The variability could result in uncertainty as to detecting the potential source andimpact of oil-field water on groundwater.

Regional Supplement to the Corps of Engineers Wetland Delineation Manual: Arid West Region (Version 2.0)

U.S. Army Corps of Engineers (USACE) | September 9th, 2008

This document is one of a series of Regional Supplements to the Corps of Engineers Wetland Delineation Manual, which provides technical guidance and procedures for identi

This document is one of a series of Regional Supplements to the Corps of Engineers Wetland Delineation Manual, which provides technical guidance and procedures for identifying and delineating wetlands that may be subject to regulatory jurisdiction under Section 404 of the Clean Water Act or Section 10 of the Rivers and Harbors Act. The development of Regional Supplements is part of a nationwide effort to address regional wetland characteristics and improve the accuracy and efficiency of wetland-delineation procedures. This supplement is applicable to the Arid West Region, which consists of all or portions of 12 states: Arizona, California, Colorado, Idaho, Montana, Nevada, New Mexico, Oregon, Texas, Utah, Washington, and Wyoming.

Regional Watershed Modeling and Trends Implementation Plan

San Francisco Estuary Institute (SFEI) | July 1st, 2019

Regional Watershed Spreadsheet Model (RWSM) Year 5 Progress Report

San Francisco Estuary Institute (SFEI) | March 1st, 2016

The Regional Watershed Spreadsheet Model (RWSM) is a regional-scale planning tool developed primarily to estimate long-term average annual loads from the small tributari

The Regional Watershed Spreadsheet Model (RWSM) is a regional-scale planning tool developed primarily to estimate long-term average annual loads from the small tributaries surrounding San Francisco Bay, and secondarily to provide supporting information for prioritizing watersheds or areas within watersheds for management actions. The RWSM has been in development since 2010. In previous years, obstacles to calibrating the PCB and Hg models included issues associated with GIS data underlying the Model, a simplistic model structure and parameterization, lack of available empirical data for calibrating concentrations associated with specific land uses and source areas, and the high uncertainty with the empirical calibration dataset. The modeling effort in Years 2014 and 2015 (Year 4 and 5 of the model development) focused on improving the model calibration to attempt to resolve these issues. The major changes included switching from a sediment-based model to a water-based model, elimination of double counting of source areas on top of general land uses, changes in the model calibration approach, and changes to the land use grouping.

Regulatory steps needed to protect and conserve wetlands not subject to the Clean Water Act

California State Water Resources Control Board (SWRCB) | November 17th, 2003

This report responds to legislative direction to describe the steps and resources needed to protect California wetlands and other waters that are not covered by the feder

This report responds to legislative direction to describe the steps and resources needed to protect California wetlands and other waters that are not covered by the federal Clean Water Act (CWA). It gives special attention to "isolated" waters removed from CWA jurisdiction by the U.S. Supreme Court's 2001 decision in Solid Waste Agency of Northern Cook County v. U.S. Army Corps of Engineers (SWANCC). Wetlands and riparian areas support extraordinary biodiversity and are uniquely important in sustaining the hydrologic, chemical, and ecological integrity of broader aquatic systems. However, for physical and legal reasons, they present special management challenges. Neither CWA nor the state Porter-Cologne Water Quality Control Act (Porter-Cologne) were designed to conserve wetlands, and their regulatory protection is therefore often problematic and incomplete.

Relationship between wetland condition, stress, and buffer

San Francisco Estuary Institute (SFEI) | April 25th, 2016

Relationship between wetland size and CRAM condition scores for depressional wetlands

San Francisco Estuary Institute (SFEI) | March 28th, 2016

Relative risk of groundwater-quality degradation near California (USA) oil fields estimated from 3H, 14C, and 4He

Applied Geochemistry (Elsevier) | June 5th, 2021

 Relative risks of groundwater-quality degradation near selected California oil fields are estimated by examining spatial and temporal patterns in chemical and isotopic

 Relative risks of groundwater-quality degradation near selected California oil fields are estimated by examining spatial and temporal patterns in chemical and isotopic data in the context of groundwater-age categories defined by tritium and carbon-14. In the Coastal basins, western San Joaquin Valley (SJV), and eastern SJV; 82, 76, and 0% of samples are premodern (pre-1953 recharge), respectively; and 3, 0, and 31% are modern (recharged during or after 1953), respectively. Carbon-14 and helium-4 data indicate most premodern samples are 1000 to 10,000 (33%) or >10,000 (50%) years old. Organic chemicals that could be associated with deeper hydrocarbon reservoirs (e.g. thermogenic gases and benzene) occur most frequently in premodern groundwater, suggesting premodern groundwater has a higher risk of degradation from upward migration of hydrocarbons than modern and mixed-age groundwater. Low sulfate concentrations in some premodern groundwater containing high thermogenic-methane concentrations (>28 mg/L) indicate methane attenuation associated with sulfate reduction can be limited in premodern groundwater. The more common occurrence of manufactured compounds, like tetrachloroethene, in modern and mixed-age groundwater than in premodern groundwater indicates modern and mixed-age groundwater has a higher risk of degradation from land-surface sources than premodern groundwater. Time-series data for chloride in groundwater affected by disposal of oil-field water in unlined ponds indicate some modern and mixed-age groundwater are susceptible to chemical migration within 2–3 km of surface sources. Timescales for diluting chloride concentrations in groundwater with fresh recharge once disposal ponds are decommissioned are shorter in mixed-age groundwater with large fractions of modern water (9–14 years in one example) than in mixed-age groundwater with large fractions of premodern water (no evidence of dilution after 12 years of monitoring in one example). The presence of predominantly premodern groundwater in the Coastal basins and western SJV indicates these areas have relatively high risk from upward migration of hydrocarbons, reduced methane attenuation capacity, and long dilution times, whereas predominantly modern-and mixed-age groundwater in the eastern SJV indicates this area has relatively high risk from chemical migration from land-surface sources and subsequent extensive spreading. Age-based characterizations of relative risk could inform the design of groundwater-monitoring programs near oil fields in terms of the spatial distribution of monitoring points relative to source areas and monitoring frequency and duration. 

Remedial Investigation Report for Former Titan 1-A Missile Facility, Lincoln, California

U.S. Army Corps of Engineers (USACE) | February 12th, 2025

Previous investigations have identified groundwater and soil vapor as the primary environmental matrices that have been impacted by the release and volatile organic compo

Previous investigations have identified groundwater and soil vapor as the primary environmental matrices that have been impacted by the release and volatile organic compounds (VOCs) as the contaminants of potential concern (COPCs). Previous investigations have determined that the DOD-related releases at the Site consist of benzene, toluene, ethylbenzene, xylenes (BTEX), trichloroethene (TCE), and TCE’s degradation products. The release has primarily impacted shallow groundwater and there does not appear to be a significant vadose zone (soil) source (Brown and Caldwell 2007a). This RI presents and evaluates previously collected data. No new data are provided in this report. Due to size, this document has been divided. Part one, Part two, Part three, Part four, Part five, Part six, Part seven Click here for proposed  USACE site remediation schedule