Quality of Groundwater Used for Domestic Drinking-Water Supply in the Coachella Valley, 2020

U.S. Geological Survey (USGS) | January 13th, 2023

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

U.S. Geological Survey (USGS) | November 1st, 2024

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domes

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply. The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents— the disinfection by-product chloroform, the gasoline oxygenate methyl tert-butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources, with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

Quality of Groundwater Used for Domestic Supply in the Modesto, Turlock, and Merced Subbasins of the San Joaquin Valley, California

U.S. Geological Survey (USGS) | January 6th, 2023

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domes

More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the Modesto, Turlock, and Merced subbasins of the San Joaquin Valley where more than 78,000 residents are estimated to use privately owned domestic wells. Results indicate that inorganic and organic constituents in groundwater were respectively present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 37 percent and 9 percent of the aquifer area used for domestic drinking-water supplies (herein, “domestic groundwater resources”). The most prevalent inorganic constituents exceeding regulatory benchmarks were nitrate, uranium, and arsenic. The only organic constituents exceeding regulatory benchmarks were the fumigant constituents 1,2,3-trichloropropane (1,2,3-TCP) and 1,2-dibromo-3-chloropropane (DBCP), but the herbicides atrazine and simazine were detected at low concentrations below one-tenth of regulatory benchmarks in 30 percent of domestic groundwater resources. Total dissolved solids (TDS) and manganese exceeded aesthetic-based (secondary maximum contaminant level [SMCL]) benchmarks for drinking water in 3 percent and 13 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFAS) were detected in 23 percent of domestic groundwater resources, with 4 percent exceeding California state notification or response levels for specific compounds. Total coliform bacteria were detected in 20 percent of domestic groundwater resources. Elevated concentrations of nitrate, uranium, TDS, and pesticides (fumigant constituents and herbicides) are related to agricultural land use and were typically present at shallow depths up to 75 meters below land surface. Agriculturally derived constituents were detected in wells screened below the Corcoran Clay Member of the Tulare Formation (herein, “Corcoran Clay”) in the southeastern part of the study area, where the Corcoran Clay tends to be shallower and thinner than in areas to the northwest. Nitrate, uranium, and TDS were most prevalent in the northwest part of the study area proximal to the valley trough where soils are poorly drained and agricultural land uses are predominantly grain, alfalfa, and dairy farms. Pesticides tended to occur in groundwater below coarse-grained surficial deposits and within a northwest to southeast trending band along the eastern extent of the Corcoran Clay that typically demarcates the western extent of well-drained soils associated with perennial orchard crops. Elevated concentrations of arsenic tended to occur west of this band in reducing groundwater but also sometimes co-occurred with elevated nitrate in oxic groundwater, most likely because of geochemical conditions in agriculturally affected groundwater that can enhance the mobility of arsenic from aquifer sediments.

Quality of Groundwater Used for Domestic Supply in the Northern San Joaquin Valley, California

U.S. Geological Survey (USGS) | July 28th, 2021

 Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Moni

 Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project (PBP) of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and provides increased public access to groundwater-quality information. Private domestic and small-system drinking-water wells in the Northern San Joaquin Valley (NSJV) were the target for this assessment. These wells tend to pump water from shallower parts of alluvial aquifers compared to deeper, long-screened public-supply wells in the region. 

Quality of Groundwater Used for Public Supply in the Continental United States: A Comprehensive Assessment

American Chemical Society (ACS) | October 21st, 2022

Quality of Water Colorado River Basin Progress Report No. 25

U.S. Bureau of Reclamation (USBR) | January 14th, 2017

The Colorado River and its tributaries provide water to about 35 - 40 million people and irrigation water to nearly 4.5 million acres of land in the United States (Mov

The Colorado River and its tributaries provide water to about 35 - 40 million people and irrigation water to nearly 4.5 million acres of land in the United States (Moving Forward, 2015;). The river also serves about 3.3 million people and 500,000 acres in Mexico (Cohen, 2011). The effect of salinity is a major concern in both the United States and Mexico. Salinity damages in the United States are presently estimated to be about $382 million per year at 2014 salinity concentrations, which includes 1.3 million tons of implemented salinity controls. This biennial report on the quality of water in the Colorado River Basin is required by Public Laws 84-485, 87-483, and the Colorado River Basin Salinity Control Act (Salinity Control Act) (Public Law 93-320, as amended by Public Laws 98-569, 104-20, 104-127, and 106-459).

Quality of Water from Domestic Wells in Principal Aquifers of the United States, 1991–2004: Overview of Major Findings

U.S. Geological Survey (USGS) | November 5th, 2009

This report is one of a series of publications, The Quality of Our Nation’s Waters, which describes major findings of the NAWQA Program on water-quality issues of regio

This report is one of a series of publications, The Quality of Our Nation’s Waters, which describes major findings of the NAWQA Program on water-quality issues of regional and national concern. This report presents a national assessment of the quality of water in private domestic wells based on samples from about 2,100 wells located in 48 states and tapping 30 regional aquifers used for water supply. Compared to previous investigations of domestic well water quality, “Quality of Water from Domestic Wells in Principal Aquifers of the United States, 1991–2004 —Overview of Major Findings” greatly expands the number of contaminants assessed in domestic wells and improves geographic coverage of wells sampled. More than 43 million people—about 15 percent of the U.S. population—rely on domestic wells as their source of drinking water (Hutson and others, 2004). The quality and safety of water from domestic wells, also known as private wells, are not regulated by the Federal Safe Drinking Water Act or, in most cases, by state laws. Rather, individual homeowners are responsible for maintaining their domestic well systems and for monitoring water quality. The lack of regular monitoring of domestic wells makes periodic assessments at national, regional, and local scales important sources of information about this key source of drinking water. This study from the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) assesses water-quality conditions for about 2,100 domestic wells. The sampled wells are located in 48 states and in parts of 30 regionally extensive aquifers used for water supply in the United States. As many as 219 properties and contaminants, including pH, major ions, nutrients, trace elements, radon, pesticides, and volatile organic compounds (VOCs), were measured. Fecal indicator bacteria and additional radionuclides were analyzed for a smaller number of wells. The large number of contaminants assessed and the broad geographic coverage of the present study provides a foundation for an improved understanding of the quality of water from the major aquifers tapped by domestic supply wells in the United States.

Quality of Water from Public-Supply Wells in the United States, 1993–2007: Overview of Major Findings

U.S. Geological Survey (USGS) | July 12th, 2010

In this study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS), chemical water-quality conditions were assessed in source (un

In this study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS), chemical water-quality conditions were assessed in source (untreated) groundwater from 932 public-supply wells, hereafter referred to as public wells, and in source and finished water from a subset of 94 wells. The public wells are located in selected parts of 41 states and withdraw water from parts of 30 regionally extensive water-supply aquifers, which constitute about one-half of the principal aquifers in the United States. Although the wells sampled in this study represent less than 1 percent of all groundwater-supplied public water systems in the United States, they are widely distributed nationally and were randomly selected within the sampled hydrogeologic settings to represent typical aquifer conditions. All source-water samples were collected prior to any treatment or blending that potentially could alter contaminant concentrations. As a result, the sampled groundwater represents the quality of the source water and not necessarily the quality of finished water ingested by the people served by these public wells.

Quantification Settlement Agreement and Related Agreements and Documents to which Southern California Agencies are Signatories

California Natural Resources Agency (CNRA) | October 10th, 2003

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA

Science of the Total Environment (Elsevier) | June 15th, 2018

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by abo

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 y ears in the San Joaquin Valley, California (SJV). D uring this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993 –2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (b50 m) wells surrounded predominantly by agricultural land uses, while premodern (pre-1950) groundwater from deeper wells, and recently recharged groundwater from wells surrounded by mainly urban, natural, and mixed land uses had lower TDS concentrations, approaching the TDS concentrations in the Historic groundwater. For the NESJV and SESJV, inverse geochemical modeling with PHREEQC indicated that weathering of primary silicate minerals accounted for the majority o f the increase in TDS concentrations, contributing more than nitrate from fertilizers and sulfate from soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas like the SJV, can cause large changes in groundwater quality on a regional scale.