Lithium in groundwater used for drinking-water supply in the United States

Science of the Total Environment (Elsevier) | May 1st, 2021

Lithium concentrations in untreated groundwater from 1464 public-supply wells and 1676 domestic-supply wells distributed across 33 principal aquifers in the United States

Lithium concentrations in untreated groundwater from 1464 public-supply wells and 1676 domestic-supply wells distributed across 33 principal aquifers in the United States were evaluated for spatial variations and possible explanatory factors. Concentrations nationwide ranged from <1 to 396 μg/L (median of 8.1) for public supply wells and <1 to 1700 μg/L (median of 6 μg/L) for domestic supply wells. For context, lithium concentrations were compared to a Health Based Screening Level (HBSL, 10 μg/L) and a drinking-water only threshold (60 μg/L). These thresholds were exceeded in 45% and 9% of samples from public-supply wells and in 37% and 6% from domestic-supply wells, respectively. However, exceedances and median concentrations ranged broadly across geographic regions and principal aquifers. Concentrations were highest in arid regions and older groundwater, particularly in unconsolidated clastic aquifers and sandstones, and lowest in carbonate-rock aquifers, consistent with differences in lithium abundance among major lithologies and rock weathering extent. The median concentration for public-supply wells in the unconsolidated clastic High Plains aquifer (central United States) was 24.6 μg/L; 24% of the wells exceeded the drinking-water only threshold and 86% exceeded the HBSL. Other unconsolidated clastic aquifers in the arid West had exceedance rates comparable to the High Plains aquifer, whereas no public supply wells in the Biscayne aquifer (southern Florida) exceeded either threshold, and the highest concentration in that aquifer was 2.6 μg/L. Multiple lines of evidence indicate natural sources for the lithium concentrations; however, anthropogenic sources may be important in the future because of the rapid increase of lithium battery use and subsequent disposal. Geochemical models demonstrate that extensive evaporation, mineral dissolution, cation exchange, and mixing with geothermal waters or brines may account for the observed lithium and associated constituent concentrations, with the latter two processes as major contributing factors.

Long-term Monitoring of Pollutants in Fish and Mussels Documents Major Improvements and Persistent Problems

California State Water Resources Control Board (SWRCB) | December 1st, 2007

Of the 390 sites sampled between 1998 and 2003, 32 percent fell into the “low” contamination category. These sites were scattered throughout the state, with

Of the 390 sites sampled between 1998 and 2003, 32 percent fell into the “low” contamination category. These sites were scattered throughout the state, with a particular prevalence in the Sierra Nevada and the area north of San Diego. Unfortunately, the Delta region had relatively few sites with low concentration of pollutants. In general, PCB and DDT levels in fish and mussels across California have declined greatly since the 1970s, and many species have bounced back in response to the decline in DDT levels. However, the report also found that present concentrations of pollutants in fish collected from many California water bodies are high enough to cause concern for possible effects on human health and to have a significant impact on the fishing beneficial use. The report found that fish in 68 percent of the water bodies sampled have “moderate to very high levels of mercury or persistent organics (such as PCBs and organochlorinated pesticides like DDT).” Consumption advisories exist for only a fraction of the water bodies likely to need them. Many water bodies with elevated contaminant levels in fish are near population centers and are popular for fishing. Furthermore, subsistence fishing is increasing, and consumption of contaminated fish is an environmental justice issue.

Long-term variation in concentrations and mass loads in a semi-arid watershed influenced by historic mercury mining and urban pollutant sources

Science of the Total Environment (Elsevier) | December 15th, 2017

Urban watersheds are significantly anthropogenically-altered landscapes. Most previous studies cover relatively short periods, without addressing concentrations, loads, a

Urban watersheds are significantly anthropogenically-altered landscapes. Most previous studies cover relatively short periods, without addressing concentrations, loads, and yields in relation to annual climate fluctuations, and datasets on Ag, Se, PBDEs, and PCDD/Fs are rare. Intensive storm-focused sampling and continuous turbidity monitoring were employed to quantify pollution at two locations in the Guadalupe River (California, USA). At a downstream location, we determined loads of suspended sediment (SS) for 14 yrs., mercury (HgT), PCBs, and total organic carbon (TOC) (8 yrs), total methylmercury (MeHgT) (6 yrs), nutrients, and trace elements including Ag and Se (3 yrs), DDTs, chlordanes, dieldrin, and PBDEs (2 yrs), and PCDD/Fs (1 yr). At an upstream location, we determined loads of SS for 4 yrs. and HgT, MeHgT, PCBs and PCDD/Fs for 1 yr. These data were compared to previous studies, climatically adjusted, and used to critically assess the use of small datasets for estimating annual average conditions. Concentrations and yields in the Guadalupe River appear to be atypical for total phosphorus, DDTs, dieldrin, HgT, MeHgT, Cr, Ni, and possibly Se due to local conditions. Other pollutants appear to be similar to other urban systems. On average, wet season flow varied by 6.5-fold and flow-weighted mean (FWM) concentrations varied 4.4-fold, with an average 7.1-fold difference between minimum and maximum annual loads. Loads for an average runoff year for each pollutant were usually less than the best estimate of long-term average. The arithmetic average of multiple years of load data or a FWM concentration combined with mean annual flow was also usually below the best estimate of long-term average load. Mean annual loads using sampled years were also less than the best estimate of long-term average by a mean of 2.2-fold. Climatic adjustment techniques are needed for computing estimates of long-term average annual loads.

Longitudinal metatranscriptomic sequencing of Southern California wastewater representing 16 million people from August 2020–21 reveals widespread transcription of antibiotic resistance genes

Water Research (Elsevier) | November 22nd, 2022

Municipal wastewater provides a representative sample of human fecal waste across a catchment area and contains a wide diversity of microbes. Sequencing wastewater sample

Municipal wastewater provides a representative sample of human fecal waste across a catchment area and contains a wide diversity of microbes. Sequencing wastewater samples provides information about human-associated and medically important microbial populations, and may be useful to assay disease prevalence and antimicrobial resistance (AMR). Here, we present a study in which we used untargeted metatranscriptomic sequencing on RNA extracted from 275 sewage influent samples obtained from eight wastewater treatment plants (WTPs) representing approximately 16 million people in Southern California between August 2020 – August 2021. We characterized bacterial and viral transcripts, assessed metabolic pathway activity, and identified over 2,000 AMR genes/variants across all samples. Because we did not deplete ribosomal RNA, we have a unique window into AMR carried as ribosomal mutants. We show that AMR diversity varied between WTPs (as measured through PERMANOVA, P < 0.001) and that the relative abundance of many individual AMR genes/variants increased over time (as measured with MaAsLin2, Padj < 0.05). Similarly, we detected transcripts mapping to human pathogenic bacteria and viruses suggesting RNA sequencing is a powerful tool for wastewater-based epidemiology and that there are geographical signatures to microbial transcription. We captured the transcription of gene pathways common to bacterial cell processes, including central carbon metabolism, nucleotide synthesis/salvage, and amino acid biosynthesis. We also posit that due to the ubiquity of many viruses and bacteria in wastewater, new biological targets for microbial water quality assessment can be developed. To the best of our knowledge, our study provides the most complete longitudinal metatranscriptomic analysis of a large population's wastewater to date and demonstrates our ability to monitor the presence and activity of microbes in complex samples. By sequencing RNA, we can track the relative abundance of expressed AMR genes/variants and metabolic pathways, increasing our understanding of AMR activity across large human populations and sewer sheds.

Los Angeles Sustainable Water Project: Ballona Creek Watershed

University of California, Los Angeles (UCLA) | November 1st, 2015

Implementing integrated water management systems (IWM) that incorporate all components of the urban water cycle, including imported water, local groundwater, captured st

Implementing integrated water management systems (IWM) that incorporate all components of the urban water cycle, including imported water, local groundwater, captured stormwater, greywater, and treated wastewater is crucial to creating a sustainable water supply for the city of Los Angeles (City). The City has researched, written, and initiated implementation of recommendations from many reports critical to creating an IWM plan for the City as well as to defining the current capacity of the system. While work on this issue has been ongoing for many years, the extreme drought currently impacting water supplies throughout California has created a new urgency to increase the City’s ability to provide a secure water supply through local sources. In April 2015, Governor Brown directed the first-ever statewide mandatory cut of 25% in urban water use due to the continuing drought conditions. In addition to statewide efforts, many policies and plans have been created on a local level within the City that address urban water management, integrated resources planning, stormwater capture, and groundwater management. The Los Angeles Mayor’s Office recently set strong goals to increase the sustainability of the City’s water supply over the next several years. The goals included completing a comprehensive sustainability plan containing objectives for water supply and demand in the City, which was released in April 2015 (Sustainable City pLAn). In an emergency drought directive released in October 2014, the Mayor identified additional accelerated water goals including reducing per capita potable water use by 20% by 2017 (from 2014 base-line of 130 gallons per capita per day (GPCD) to 104 GPCD), reducing the City’s reliance on MWD water by 50% by 2025, and converting 85% of public golf course acreage to recycled water by 2017. Through building upon regional research and reports that have been generated on potential components of the local water supply portfolio (e.g., groundwater, recycled water, and stormwater), as well as gathering and analyzing current data on flows of water and wastewater throughout the City systems and environment, this project further identifies and refines opportunities to implement integrated water management throughout the City. As water quality regulation in the Los Angeles area currently drives much of the current water management practices, we examined greater water self-reliance through this lens. Therefore, the City has been divided by watershed to assess Total Maximum Daily Load (TMDL) compliance alongside integrated water management opportunities and challenges that exist and must be addressed in order to meet water quality compliance requirements and maximize local water supply. This first report focuses on the Ballona Creek Watershed and the Hyperion Service Area; following reports will focus on the Dominguez Channel and Los Angeles River watersheds.

Lower Peninsula Watershed Condition Assessment 2016. Technical memorandum prepared for the Santa Clara Valley Water District - Priority D5 Project

San Francisco Estuary Institute (SFEI) | October 2nd, 2017

This report describes baseline information about the amount and distribution of aquatic resources, and evaluates that overall ecological conditions of streams using the C

This report describes baseline information about the amount and distribution of aquatic resources, and evaluates that overall ecological conditions of streams using the California Rapid Assessment Method (CRAM), for the Lower Peninsula watershed in Santa Clara County; consisting of Stevens-Permanente Creek, Adobe Creek, southern extent of San Francisquito Creek, and their tributaries. The Lower Peninsula watershed covers approximately 98 square-miles with creeks flowing from the Santa Cruz Mountains into southwest San Francisco Bay and its tidal wetlands.

Lower Tule River Irrigation District Groundwater Sustainability Agency Groundwater Sustainability Plan

Lower Tule River Irrigation District Groundwater Sustainability Agency | January 21st, 2020

Making the Most of Water for the Environment: A Functional Flows Approach for California’s Rivers

Public Policy Institute of California (PPIC) | August 25th, 2020

In California, water and land management activities have substantially altered river flows and degraded river channels and their floodplains. The result has been a precip

In California, water and land management activities have substantially altered river flows and degraded river channels and their floodplains. The result has been a precipitous decline in native fish populations, including the collapse of valued salmon fisheries, and widespread imperilment of freshwater biodiversity. Environmental flows—flows in rivers and streams necessary to sustain ecosystem health—are essential to reversing these trends. Yet many rivers in California lack environmental flows. And for those rivers with such protections, environmental flows are typically established at static minimum levels, which fail to preserve the natural seasonal and interannual variability of flow that sustains healthy ecosystems. A new approach to managing environmental water is needed. 

Making Waves: One Water Quality Standardization Concept – A Leap for Sustainable Water Management

Elsevier | February 20th, 2026

Current water management frameworks are often disjointed, failing to consider the full range of potential water uses. This fragmentation leads to inconsistent regulations

Current water management frameworks are often disjointed, failing to consider the full range of potential water uses. This fragmentation leads to inconsistent regulations; for example, potable water production from wastewater often faces stricter quality standards than water sourced from even wastewater-impacted surface waters. This article proposes a use-based approach to water management, developing water quality standards that account for the economic, public health, and ecological needs of downstream users. We advocate for expanding the concept of water quality from simple pollutant removal to “building water” to match the needs of users so desired constituents are either left in the source water or added to treated water to meet specific user needs. This strategy requires a multidimensional, risk-based regulatory framework, supported by advances in data science and affordable measurement tools for effective enforcement. Such advancement enables a move beyond binary standards to foster sustainable global water resource management and mitigate scarcity.

Managed Aquifer Recharge in California: Four Examples of Managed Groundwater Replenishment Across the State

American Geosciences Institute (AGI) | September 29th, 2017

In California, surface water from rainfall, snowmelt, and distant rivers rarely meets the state’s urban and agricultural water needs. Groundwater is an essentia

In California, surface water from rainfall, snowmelt, and distant rivers rarely meets the state’s urban and agricultural water needs. Groundwater is an essential water source, providing 35% of the fresh water used in California. However, when groundwater is used more rapidly than it is naturally replenished, groundwater management becomes necessary. One of the tools used by groundwater managers is managed aquifer recharge (MAR). Aquifers, the porous rocks and sediments that hold and transmit groundwater, are naturally replenished by surface water that seeps into the ground. MAR enhances the recharge rate by creating artificial streams and ponds where water trickles into the ground, or by using wells to directly inject water underground. MAR can also be used to improve groundwater quality and prevent some of the negative consequences of groundwater depletion, like ground sinking (subsidence) or the intrusion of salty groundwater from the oceans into coastal freshwater aquifers. Because of its arid climate and large population, California is home to some of the oldest and largest MAR projects in the United States. This case study highlights four of these projects, covering almost a century of MAR and water security in California.