History and Sources of Co-Occurring Pesticides in an Abstraction Well Unraveled by Age Distributions of Depth-Specific Groundwater Samples

American Chemical Society (ACS) | November 24th, 2019

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse sources and different contaminants may have different sources even in a single groundwater well, making these questions complicated to answer. Age dating of groundwater has been used to reconstruct contaminant travel times to wells; however, critics have highlighted that groundwater flow is often complex with mixing of groundwater of different ages. In drinking water wells, where water is typically abstracted from a large depth interval, such mixing is even more problematic. We present a way to overcome some of the obstacles in identifying the source and age of contaminants in drinking water wells by combining depth-specific sampling with age tracer modeling, particle tracking simulations, geological characterization, and contaminant properties. This multitool approach was applied to a drinking water well, where bentazon and dichlorprop contamination was found to have different pollutant sources and release histories, even though both pesticides can be associated with the same land use. Bentazon was derived from recent application to a golf course, while dichlorprop was derived from agricultural use more than 30 years ago. The advantages, limitations, and pitfalls of the proposed course of action are then further discussed.

Hoopa Valley Tribe Water Quality Plan

Hoopa Valley Tribal Environmental Protection Agency | February 14th, 2008

The Hoopa Valley Tribal Council pursuant to Title 37 of the Hoopa Tribal Code has assigned the primary responsibility for the protection and enhancement of water quality

The Hoopa Valley Tribal Council pursuant to Title 37 of the Hoopa Tribal Code has assigned the primary responsibility for the protection and enhancement of water quality on the Hoopa Valley Indian Reservation to the Riparian Review Committee (RRC). The RRC along with the Hoopa Valley Tribal Environmental Protection Agency provides Reservation-wide coordination of the water quality control program by developing, reviewing and recommending for Tribal approval Reservation wide policies and plans for the implementation of Tribal and Federal law. This Water Quality Control Plan recognizes the unique characteristics of each watershed with regard to natural water quality, existing, potential, and historical beneficial uses, and water quality problems. The goal of this plan is to provide a definitive program of actions designed to preserve and enhance water quality on the Reservation, and to protect the beneficial uses of water for the next 10 years to 20 years. The plan is concerned with all factors and activities that might affect water quality. However, the plan emphasizes actions to be taken by the Riparian Review Committee, the Hoopa Valley Tribal Fisheries, Forestry, Public Utility Departments, and Tribal Environmental Protection Agency, as they have responsibility for maintaining water quality on the Reservation. The Water Quality Control Plan (WQCP) is comprehensive in scope. The WQCP describes the Hoopa Valley Reservation waters, the quality and quantity issues, and the existing, potential and historical beneficial uses of the Reservation’s waters. The plan also prescribes criteria for the protection of the Reservation waters and includes plans and policies that describe the basis for the management of water quality and protection of human health. The Hoopa Valley Tribe has recognized authority for setting water quality standards for its Reservation waters, including both the Trinity and Klamath Rivers (U.S. EPA, 2002). Included in the plan are specific criteria that apply to the Lower Klamath River on the Hoopa Valley Reservation (Figure 1.1).

How freeing rivers can help California ease flood risks and revive ecosystems

Los Angeles Times | February 20th, 2024

Natural floodplains — the lush green lands along rivers that historically flooded, retained water, and nourished life in the heart of the valley — were mostly drained

Natural floodplains — the lush green lands along rivers that historically flooded, retained water, and nourished life in the heart of the valley — were mostly drained and converted to farmland generations ago as the state’s waters were dammed and diverted. Today, an effort to bring back some of those floodplains is flourishing at the 2,100-acre Dos Rios Ranch Preserve near Modesto, where workers years ago planted native trees on retired farm fields and removed berms to create space for water to spread out again.

How much potable water is saved by wastewater recycling? Quasi-experimental evidence from California

Resources, Conservation & Recycling (Elsevier) | October 6th, 2021

Recently, California has made large investments in wastewater recycling to replace applications that use potable water. It may be expected that the use of recycled water

Recently, California has made large investments in wastewater recycling to replace applications that use potable water. It may be expected that the use of recycled water reduces potable water use, but such an equivalency is not assured. The addition of recycled water infrastructure in a large Californian water district creates a natural experiment where this work tests how recycled water usage affects primary potable water. This is done using econometric methods for causal inference in an observational setting that mirror a randomized control trial (RCT). From 2001 to 2014, a number of public parks were given recycled water infrastructure, while others in those regions remained exclusively on potable supply. A two-way fixed effects regression is used to produce a difference-in-differences estimate of the average treatment effect of recycled water on total and potable water usage. The results indicate that potable water usage is reduced significantly when a park is connected to the recycled water supply. The estimated rate of displacement in the study period is 81.7%, meaning each unit of recycled water use avoided 0.817 units of potable water usage, which implies the connection of parks to recycled water supply increases total water use. The analysis provides, to the best of our knowledge, the first empirical estimate of the water savings claimed by urban water recycling programs, and the first empirical estimate of displacement using quasi-experimental methods. The methodology can be utilized to evaluate the effectiveness of recycling programs around the world.

Human Impacts Dominate Global Loss of Lake Ecosystem Resilience

American Geophysical Union (AGU) | June 5th, 2024

Human viral nucleic acids concentrations in wastewater solids from Central and Coastal California USA

Nature Portfolio (Springer Nature) | June 22nd, 2023

Hydraulic fracturing in faulted sedimentary basins: Numerical simulation of potential contamination of shallow aquifers over long time scales

American Geophysical Union (AGU) | December 12th, 2013

Hydraulic fracturing, used to economically produce natural gas from shale formations, has raised environmental concerns. The objective of this study is to assess one of

Hydraulic fracturing, used to economically produce natural gas from shale formations, has raised environmental concerns. The objective of this study is to assess one of the largely unexamined issues, which is the potential for slow contamination of shallow groundwater due to hydraulic fracturing at depth via fluid migration along conductive faults. We compiled publicly available data of shale gas basins and hydraulic fracturing operations to develop a two-dimensional, single-phase, multi-species, density-dependent, finite-element numerical groundwater flow and mass transport model. The model simulates hydraulic fracturing in the vicinity of a permeable fault zone in a generic, low-recharge, regional sedimentary basin in which shallow, active groundwater flow occurs above nearly stagnant brine. A sensitivity analysis of contaminant migration along the fault considered basin, fault and hydraulic fracturing parameters. Results show that specific conditions are needed for the slow contamination of a shallow aquifer: a high permeability fault, high over-pressure in the shale unit, and hydro-fracturing in the upper portion of the shale near the fault. Undersuch conditions, contaminants from the shale unit reach the shallow aquifer in less than 1000 years following hydraulic fracturing, at concentrations of solutes up to 90% of their initial concentration in the shale, indicating that the impact on groundwater quality could be significant. Important implications of this result are that hydraulic fracturing should not be carried out near potentially conductive faults, and that impacts should be monitored for long timespans. Further work is needed to assess the impact of multiphase flow on contaminant transport along natural preferential pathways.

Hydraulic fracturing near domestic groundwater wells

National Academy of Sciences (NAS) | December 12th, 2017

Hydraulic fracturing operations are generating considerable discussion about their potential to contaminate aquifers tapped by domestic groundwater wells. Groundw

Hydraulic fracturing operations are generating considerable discussion about their potential to contaminate aquifers tapped by domestic groundwater wells. Groundwater wells located closer to hydraulically fractured wells are more likely to be exposed to contaminants derived from on-site spills and well-bore failures, should they occur. Nevertheless, the proximity of hydraulic fracturing operations to domestic groundwater wells is unknown. Here, we analyze the distance between domestic groundwater wells (public and self-supply) constructed between 2000 and 2014 and hydraulically fractured wells stimulated in 2014 in 14 states. We show that 37% of all recorded hydraulically fractured wells stimulated during 2014 exist within 2 km of at least one recently constructed (2000–2014) domestic groundwater well. Furthermore, we identify 11 counties where most (>50%) recorded domestic groundwater wells exist within 2 km of one or more hydraulically fractured wells stimulated during 2014. Our findings suggest that understanding how frequently hydraulic fracturing operations impact groundwater quality is of widespread importance to drinking water safety in many areas where hydraulic fracturing is common. We also identify 236 counties where most recorded domestic groundwater wells exist within 2 km of one or more recorded oil and gas wells producing during 2014. Our analysis identifies hotspots where both conventional and unconventional oil and gas wells frequently exist near recorded domestic groundwater wells that may be targeted for further water-quality monitoring.

Hydrodynamic and Water Quality Model Calibration and Application in San Francisco Bay

San Francisco Estuary Institute (SFEI) | September 3rd, 2018

To answer management questions about nutrient related water quality in San Francisco Bay, hydrodynamic and biogeochemical models have been developed. This report outline

To answer management questions about nutrient related water quality in San Francisco Bay, hydrodynamic and biogeochemical models have been developed. This report outlines the development of both of these models. Section 2 is the description and validation of the hydrodynamic model, previously completed in December 2017 for the San Francisco Bay Interim Model Validation Report, but included here for completeness. Section 3 of this report covers the description and validation the biogeochemical model.

Hydrodynamic Model Development Report: Sacramento-San Joaquin River Delta and Suisun Bay (Water Year 2016)

San Francisco Estuary Institute (SFEI) | December 13th, 2019

This report describes work related to hydrodynamic model development for the San Francisco Bay-Delta Estuary, undertaken as part of a broader eort to develop and apply co

This report describes work related to hydrodynamic model development for the San Francisco Bay-Delta Estuary, undertaken as part of a broader eort to develop and apply coupled biogeochemical-hydrodynamic models to inform nutrient management decisions. The primary intended application of the hydrodynamic model output is for use as input to an offline coupled biogeochemical model to simulate a wide range of state variables and processes, including: advective and dispersive transport, nutrient transformations, phytoplankton production, benthic and pelagic grazing, sediment diagenesis, and oxygen cycling.