Pesticide Concentrations of Surface Water and Suspended Sediment in Yolo By-Pass and Cache Slough Complex, California, 2019–2021

U.S. Geological Survey (USGS) | July 9th, 2024

Managed flow pulses in the north Sacramento-San Joaquin Delta are an adaptive management tool used in efforts to enhance food availability in delta smelt (Hypomesus trans

Managed flow pulses in the north Sacramento-San Joaquin Delta are an adaptive management tool used in efforts to enhance food availability in delta smelt (Hypomesus transpacificus) habitat as part of the North Delta Food Subsidies Action. The California Department of Water Resources (DWR) monitors non-managed seasonal and local flow pulses and managed flow pulses from agricultural drainage or main stem Sacramento River water redirected through Yolo By-Pass. Augmented flow pulses are hypothesized to improve net positive flow during summer and fall in Yolo By-Pass and enhance plankton availability in delta smelt habitat in Cache Slough complex. However, flow pulses may also result in unintended negative effects of increased pesticides that are transported through Yolo By-Pass. Here, we evaluate pesticides in surface water and suspended sediment correlated with flow pulses in Yolo By-Pass during the 2019–21 calendar years. Surface-water and suspended-sediment samples were collected by DWR personnel. Water samples were analyzed at the U.S. Geological Survey Organic Chemistry Research Laboratory in Sacramento, California, for a suite of as many as 178 current-use pesticides and pesticide degradates using gas chromatography with mass spectrometry (GC/MS), gas chromatography with tandem mass spectrometry, and liquid chromatography with tandem mass spectrometry. Suspended sediments filtered from water samples were analyzed for a suite of as many as 173 current-use pesticides and pesticide degradates. There were 52 different current-use pesticides and pesticide degradates detected in water samples collected throughout the study. Concentrations ranged from below method detection limits to 4,070 nanograms per liter. Five different compounds in water samples were detected with concentrations above U.S. Environmental Protection Agency aquatic life benchmarks. In suspended-sediment samples collected throughout the study, eight different current-use pesticides and pesticide degradates were detected. Total pesticide concentrations were highest at surface-water sites in the northern end of Yolo By-Pass and decreased farther downstream during the same sampling events. Total pesticide concentrations generally were higher for most surface-water sites immediately before or during the managed flow pulse in 2019 versus after the flow pulse. Finally, mean total pesticide concentrations for each surface-water site generally were higher during all of 2019 than 2021, regardless of sampling period.

Pesticide contamination detected across five wildlife refuges in the Sacramento Valley of California

Science of the Total Environment (Elsevier) | March 1st, 2025

An important goal for the applied ecological sciences is to understand the extent to which the biodiversity on conserved or managed lands is exposed to anthropogenic stre

An important goal for the applied ecological sciences is to understand the extent to which the biodiversity on conserved or managed lands is exposed to anthropogenic stressors. Among the various categories of conserved lands in the United States, the National Wildlife Refuge System is focused on the protection and management of native wildlife and plant populations. Refuge lands can be associated with wetlands and, especially in California, tend to be near areas of intense human use, including agriculture. The proximity of refuges to cultivated lands results in potential exposure to pesticide drift, which increases the possibility of non-target effects on plants and wildlife. We used a passive sampler approach to quantify aerial pesticide deposition during 28 days in spring of 2023, across five refuges in the Sacramento Valley of California. Pesticides were detected across all refuges and plots within the study area, with 36 individual compounds identified, including insecticides, herbicides, and fungicides, from 176 silicone bands from 49 plots. Distance to agriculture was not an important predictor in our models for most indices of contamination. However, our models revealed that the nearest crop type was an important mediator of the importance of distance to agriculture, as fungicide contamination decreased with distance to agriculture only when orchards were the nearest crop type. The overall lack of distance effects suggests that the interior of refuges in the study area do not necessarily provide more protection from pesticides than refuge edges, although larger refuges could offer more protection. We currently lack information on how the level of contamination found herein is biologically relevant to wildlife, and ongoing monitoring efforts have found productive communities of insects in the study area. The results of this study provide a foundation for future investigations on refuges to analyze impacts of specific pesticide compounds on plants and wildlife.

Pesticide Mixtures in the Sacramento–San Joaquin Delta, 2016–17: Results from Year 2 of the Delta Regional Monitoring Program

U.S. Geological Survey (USGS) | December 6th, 2019

Pesticides in fog

Nature Portfolio (Springer Nature) | February 18th, 1987

The discovery of the very acidic nature of fog and clouds1,2 has created much interest in sampling, analysing, and elucidating the chemistry of fog, principally because a

The discovery of the very acidic nature of fog and clouds1,2 has created much interest in sampling, analysing, and elucidating the chemistry of fog, principally because an understanding of the chemical transformations leading to acid fog may provide important clues to the origin of acid rain. Recently, the knowledge of the chemistry of fog has expanded to include carbonyl compounds3, volatile organic acids4, and alkyl sulphonates5,6. We have discovered that a variety of pesticides and their toxic alteration products are present in fog, and that they occasionally reach high concentrations relative to reported rainwater concentrations. In our experiments, we were able to measure the air–water distribution coefficients of pesticides between the liquid fog and the interstitial gas phase. These measurements reveal that some chemicals are enriched several thousandfold in the suspended liquid fog droplets compared to equilibrium distributions expected from Henry's Law coefficients for pure aqueous solutions.

Petition for 2023 Drought Emergency Regulation or Other Emergency Action to Protect Nesting Birds, Water Quality, and other Public Trust Resources at Mono Lake

Mono Lake Committee | December 16th, 2022

Petition For Rulemaking to Set Minimum Flows on the Shasta River

Mount Shasta Bioregional Ecology Center | January 20th, 2024

Decades of scientific inquiry make clear that adequate quality and quantity of flows are needed to prevent remaining fish populations from further decline. Yet this scien

Decades of scientific inquiry make clear that adequate quality and quantity of flows are needed to prevent remaining fish populations from further decline. Yet this science is not self-executing; effective government intervention is necessary to prevent the extirpation of salmonids in the Shasta. This type of government action is at the core of the Public Trust Doctrine, which requires the government to act as a trustee over public trust resources, and to the extent feasible, step in to protect these resources from over-allocation and over-use.

Phenomenological vs. biophysical models of thermal stress in aquatic eggs

Ecology Letters (Wiley) | January 1st, 2017

Predicting species responses to climate change is a central challenge in ecology. These predictions are often based on lab-derived phenomenological relationships between

Predicting species responses to climate change is a central challenge in ecology. These predictions are often based on lab-derived phenomenological relationships between temperature and fitness metrics. We tested one of these relationships using the embryonic stage of a Chinook salmon population. We parameterised the model with laboratory data, applied it to predict survival in the field, and found that it significantly underestimated field-derived estimates of thermal mortality. We used a biophysical model based on mass transfer theory to show that the discrepancy was due to the differences in water flow velocities between the lab and the field. This mechanistic approach provides testable predictions for how the thermal tolerance of embryos depends on egg size and flow velocity of the surrounding water. We found support for these predictions across more than 180 fish species, suggesting that flow and temperature mediated oxygen limitation is a general mechanism underlying the thermal tolerance of embryos.

Physical Characteristics of the Lower San Joaquin River, California, in Relation to White Sturgeon Spawning Habitat, 2011–14

U.S. Geological Survey (USGS) | July 18th, 2017

The U.S. Fish and Wildlife Service confirmed that white sturgeon (Acipenser transmontanus) recently spawned in the lower San Joaquin River, California. Decreases in the S

The U.S. Fish and Wildlife Service confirmed that white sturgeon (Acipenser transmontanus) recently spawned in the lower San Joaquin River, California. Decreases in the San Francisco Bay estuary white sturgeon population have led to an increased effort to understand their migration behavior and habitat preferences. The preferred spawning habitat of other white sturgeon (for example, those in the Columbia and Klamath Rivers) is thought to be areas that have high water velocity, deep pools, and coarse bed material. Coarse bed material (pebbles and cobbles), in particular, is important for the survival of white sturgeon eggs and larvae. Knowledge of the physical characteristics of the lower San Joaquin River can be used to preserve sturgeon spawning habitat and lead to management decisions that could help increase the San Francisco Bay estuary white sturgeon population. Between 2011 and 2014, the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, assessed selected reaches and tributaries of the lower river in relation to sturgeon spawning habitat by (1) describing selected spawning reaches in terms of habitat-related physical characteristics (such as water depth and velocity, channel slope, and bed material) of the lower San Joaquin River between its confluences with the Stanislaus and Merced Rivers, (2) describing variations in these physical characteristics during wet and dry years, and (3) identifying potential reasons for these variations. The lower San Joaquin River was divided into five study reaches. Although data were collected from all study reaches, three subreaches where the USFWS collected viable eggs at multiple sites in 2011–12 from Orestimba Creek to Sturgeon Bend were of special interest. Water depth and velocity were measured using two different approaches—channel cross sections and longitudinal profiles—and data were collected using an acoustic Doppler current profiler. During the first year of data collection (water year 2011), runoff was greatest, and gaged streamflow, measured as discharge, peaked at 875 cubic meters per second in the lower San Joaquin River. Also during that year, water velocity was generally between 0.6 and 0.9 meters per second, and depth was typically between 2.5 and 4.5 meters, but water depth exceeded 6 meters in several pools. Water year 2011 was classified as a “wet” year. Later water years were classified as either “dry” (water year 2012) or “critical” (water years 2013 and 2014). During the drier years, water was shallower, and velocities were slower. The streambed aggraded in several areas during the study. At Sturgeon Bend, for example, which had the deepest pool measured in 2011 (maximum depth was 14 meters), about 8 meters of sediment was deposited by 2014. The bed of the lower San Joaquin River was predominately sand, except in areas downstream from the mouth of Del Puerto Creek. A large amount of sand, gravel, and cobble was deposited at the mouth of Del Puerto Creek, and in the 9.5 kilometers downstream from the mouth of Del Puerto Creek, we encountered several gravel bars and patches of gravel-size (8–64 millimeters) bed material. Del Puerto and Orestimba Creeks drain from the Coast Ranges on the west side of the river. Only small quantities of gravel-size bed material were observed in the reach downstream from Orestimba Creek, indicating Orestimba Creek does not deliver much coarse sediment to the lower San Joaquin River. Del Puerto Creek appeared to be the primary source of gravels suitable for white sturgeon spawning in the lower San Joaquin River, and thus, it is important for the long-term spawning success of sturgeon in the San Joaquin River.

Phytoplankton, and Related Water-Quality Constituents in the California Sacramento– San Joaquin Delta at the Landscape Scale: 2018 High Resolution Mapping Surveys

U.S. Geological Survey (USGS) | April 1st, 2024

This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suis

This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta.

Pilot Study Examining Spatial Differences in Water Quality Between Shoal and Channel Habitats

San Francisco Estuary Institute (SFEI) | August 1st, 2019

Under the umbrella of the Nutrient Management Strategy (NMS; www.sfbaynutrients.sfei.org), we are investigating relationships between the SFB’s elevated nutrient levels

Under the umbrella of the Nutrient Management Strategy (NMS; www.sfbaynutrients.sfei.org), we are investigating relationships between the SFB’s elevated nutrient levels and phytoplankton production, with the goal of identifying protective nutrient loads and effective nutrient management options. To address these goals, NMS work includes continued ship-based monitoring (in collaboration with USGS); augmenting that monitoring with high-frequency sensor data and intensive field studies; and developing coupled hydrodynamic-biogeochemical models -- calibrated using field observations -- to simulate water quality under a range of forcings.