Estimation of groundwater residence time with deeply-derived carbon mixture considered in California

Science of the Total Environment (Elsevier) | December 16th, 2022

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic co

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic contamination. As a useful indicator of groundwater renewal rate and its residence time, groundwater age has been conventionally investigated based on 14C content and 3H concentration. However, the influence of deeply-derived (endogenic) CO2 mixture is not fully and quantitatively considered, although endogenic carbon contributes a large part of the dissolved inorganic carbon in groundwater. Combined with 3H concentration, both conventional and modified 14C-dating methods with endogenic CO2 mixture considered are employed for groundwater age determination in California. On average, the conventional groundwater 14C apparent age is overestimated by ~4.9 kyr or ~26.2 %, causing groundwater recharge rate underestimation and aquifer recovery time overestimation by ~46.0 % and ~26.2 %, respectively. High 3H concentration indicates modern water mixture in more than one fifth of groundwater samples, including those with high modified 14C apparent age (> 12 kyr, i.e., fossil groundwater) in the Central Valley and southern California, which are generally considered not to be recharged by modern water. Modern water mixture in old groundwater can potentially bring anthropogenic contamination to these groundwater resources, which should be paid attentions by the government and the managers. The results have important implications in evaluation of groundwater replenishment and its susceptibility to modern contamination in California, and in groundwater resources estimation globally.

Estrogen Receptor In Vitro Assay Linkage Studies

San Francisco Estuary Institute (SFEI) | July 30th, 2018

Our Phase 1 study indicated that it would be possible to link in vitro ER assays to in vivo endpoints (Mehinto et al. 2018). These conclusions were based on several expe

Our Phase 1 study indicated that it would be possible to link in vitro ER assays to in vivo endpoints (Mehinto et al. 2018). These conclusions were based on several experiments that were performed at the University of Florida and SCCWRP. Our conclusion was that in order to see higher order effects in Menidia, the dose of estrogens in the in vivo assay needed to be above the EC50 point for the in vitro assays. However, the dose response curve for the in vivo endpoints was broad starting at 20 ng E2/L and progressing to 20, 200 and 500 ng/L. Our Phase 1 experiments did not include the resolution to reduce uncertainty in estimated quantitative in vitro to in vivo linkage factors. While the data allowed us to extrapolate those values, it was decided that the experiment should be repeated another time with more intervening estradiol concentrations, to get a better determination. A second goal of the study was to measure estrogen equivalencies at 6 locations in San Francisco Bay, testing both the water and sediments, to determine the usefulness of the approach. Results from this study will begin to enable managers to determine whether or not additional cleanup is necessary for treated effluents that are disposed into sensitive estuarine environments.

Estuary-wide Data Repository for Delta Environmental Data to Understand a California Estuary Poster (2017)

San Francisco Estuary Institute (SFEI) | July 1st, 2017

The Sacramento-San Joaquin Delta (Delta) has some of the most pressing water supply and natural resource management issues facing California. The Delta Environmental Da

The Sacramento-San Joaquin Delta (Delta) has some of the most pressing water supply and natural resource management issues facing California. The Delta Environmental Data for the Understanding a California Estuary (DEDUCE), a collaborative project building upon the 2014 Environmental Data Summit vision, initiated a forum to integrate disparate data from multiple sources along with legacy data not uploaded to any of the State’s data-sharing systems. DEDUCE collected legacy toxic contaminant data from the Delta according to rigorous business rules, uploaded the data to the expanded estuary-wide data repository, and established design standards to exchange datasets with the California Environmental Data Exchange Network (CEDEN), a contributor to the US Environmental Protection Agency’s Water Quality Exchange (WQX). This data integration effort liberated accurate, accessible, and synthesized data for scientists and decision-makers as a foundation to inform management actions with the best available science

Estuary-Wide Data Repository for the Delta Environmental Data to Understand a California Estuary

San Francisco Estuary Institute (SFEI) | July 1st, 2017

The Sacramento-San Joaquin Delta (Delta) is the backdrop for some of the most pressing water supply and natural resource management issues facing California. To navigate

The Sacramento-San Joaquin Delta (Delta) is the backdrop for some of the most pressing water supply and natural resource management issues facing California. To navigate such matters comprehensively with transparency, and rigor, it is important to ensure broad dissemination of data. An Environmental Data Summit held in 2014 created a new era in information management and knowledge discoveries, and shed light on challenges associated with the use of disparate datasets. The Delta Environmental Data for the Understanding a California Estuary (DEDUCE), a collaborative project, builds upon the Data Summit vision and initiated a forum to integrate disparate data from multiple sources and legacy data that are currently not in any of the State’s data sharing systems. DEDUCE expanded the existing infrastructure to house water quality data from the Delta to address management questions by identifying and collecting high priority data according to rigorous business rules and mapping these data to a central system. This important step of harmonizing the data improves its interoperability and increases the access to and exchange of high-quality environmental data. DEDUCE facilitates the upload, aggregation and display of data in tools such as those created under the auspices of the California Water Quality Monitoring Council, including EcoAtlas and My Water Quality Portals, and CD3: Contaminant Data Display and Download tool for accessing and visualizing data comparable to State standards. DEDUCE achieved collecting and uploading the legacy and toxic contaminant data, and established design standards to exchange future datasets from the initial data storage or database to California Environmental Data Exchange Network (CEDEN). This data integration effort created accurate, accessible, and synthesized data for scientists and decision-makers as a foundation to inform management actions with the best available science.

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Science of the Total Environment (Elsevier) | June 22nd, 2026

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

Evaluating the environmental impact of cleaning the North Pacific Garbage Patch

Nature Portfolio (Springer Nature) | May 27th, 2025

Evaluation and Refinement of Chlorophyll-a Algorithms for High-Biomass Blooms in San Francisco Bay

Remote Sensing (MDPI) | March 21st, 2024

Evaluation of a Ground-Water Flow and Transport Model of the Upper Coachella Valley, California

U.S. Geological Survey (USGS) | June 25th, 1992

A geohydrologic data base was compiled to evaluate the changes in ground-water conditions in the upper Coachella Valley, California, since 1978, when the results of a pre

A geohydrologic data base was compiled to evaluate the changes in ground-water conditions in the upper Coachella Valley, California, since 1978, when the results of a previous ground-water-model study were published. The compiled data were analyzed to improve understanding of the ground-water flow system and the effects on water quality of an existing artificial-recharge program. Analysis of well logs indicates that several zones of differing permeability can be correlated throughout the valley. Analysis of the water-quality data suggests that the artificial recharge of Colorado River water has caused increases in dissolved solids in some wells. Sparse data indicate that the recharged water moves much more rapidly through the uppermost part of the ground-water system than through deeper parts. An evaluation of the existing ground-water simulation model of the upper Coachella Valley that was developed in the 1978 study yielded several conclusions. First, the 300- to 400-foot rise in water levels in the artificialrecharge area in 1985-86 significantly affected the groundwater flow system. Transmissivities in the model had to be increased to reflect the increase in saturated thickness. Storage-coefficient values in the model had to be increased from 0.02 (used in the previous study) to 0.10-0.15 to simulate the unconfined water-level response during this period. Second, stream-recharge and underflow rates from San Gorgonio Pass during 1979-86 seem to have been higher than the values estimated for previous studies. Conditions generally were wetter in 1979-86 than during the period in which the earlier estimates were made. Third, the flow system could be simulated more accurately if the model were extended to its true southeastern boundary, the Salton Sea. Finally, there are important vertical differences in transport of the artificially recharged water that the two-dimensional areal transport model cannot simulate. The study results indicate several additional data collection and modeling needs. The drilling of several sets of monitor wells perforated at different depths could help better define the three-dimensional flow system and waterquality differences. Additional data also are needed on underflow and stream recharge, evaporation rates and infiltration rates at the artificial-recharge facilities, and net pumpage. Three-dimensional flow and transport models are needed to evaluate the effects of ground-water development on water levels and water quality.

Evaluation of Ground-Water Flow and Solute Transport in the Lompoc Area, Santa Barbara County, California

U.S. Geological Survey (USGS) | July 1st, 1997

Ground-water quality in the Lompoc area, especially in the Lompoc plain, is only marginally acceptable for most uses. Demand for ground water has increased for municipal

Ground-water quality in the Lompoc area, especially in the Lompoc plain, is only marginally acceptable for most uses. Demand for ground water has increased for municipal use since the late 1950's and has continued to be high for irrigation on the Lompoc plain, the principal agricultural area in the Santa Ynez River basin. As use has increased, the quality of ground water has deteriorated in some areas of the Lompoc plain. The dissolved-solids concentration in the main zone of the upper aquifer beneath most of the central and western plains has increased from less than 1,000 milligrams per liter in the 1940's to greater than 2,000 milligrams per liter in the 1960's. Dissolved-solids concentration have remained relatively constant since the 1960's. A three-dimensional finite-difference model was used to simulate ground-water flow in the Lompoc area and a two-dimensional finite-element model was used to simulate solute transport to gain a better understanding of the ground-water system and to evaluate the effects of proposed management plans for the ground-water basin. The aquifer system was simulated in the flow model as four horizontal layers. In the area of the Lompoc plain, the layers represent the shallow, middle, and main zones of the upper aquifer, and the lower aquifer. For the Lompoc upland and Lompoc terrace, the four layers represent the lower aquifer. The solute transport model was used to simulate dissolved-solids transport in the main zone of the upper aquifer beneath the Lompoc plain. The flow and solute-transport models were calibrated to transient conditions for 1941-88. A steady-state simulation was made to provide initial conditions for the transient-state simulation by using long-term average (1941-88) recharge rates. Model-simulated hydraulic heads generally were within 5 feet of measured heads in the main zone for transient conditions. Model-simulated dissolved-solids concentrations for the main zone generally differed less than 200 milligrams per liter from concentrations in 1988.

Evaluation of PCB Concentrations, Masses, and Movement from Dredged Areas in San Francisco Bay

San Francisco Estuary Institute (SFEI) | March 28th, 2019

This report is a product of a Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) project funded to analyze sediment PCB data in the Dredged Materia

This report is a product of a Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) project funded to analyze sediment PCB data in the Dredged Materials Management Office (DMMO) database to address priority management questions for PCBs.