Effects of imported recharge on fluoride trends in groundwater used for public supply in California

Science of the Total Environment (Elsevier) | March 31st, 2022

Fluoride is a naturally occurring element in groundwater that supports bone and dental health at low concentrations but can cause health problems at elevated concentrati

Fluoride is a naturally occurring element in groundwater that supports bone and dental health at low concentrations but can cause health problems at elevated concentrations in drinking water. This study investigates spatial and temporal trends for fluoride concentrations in untreated groundwater from over 20,000 public supply wells in California. The presence of a significant temporal trend in fluoride concentrations in a well was assessed using the Mann-Kendall test and a spatial-weighting approach was used to identify the areal extent of the groundwater resources with significant trends. Less than 2% of the groundwater resources used for public supply in the state have concentrations above the California maximum contaminant level of 2 mg/L. Approximately 14% of the groundwater resource used for public supply show a significant recent trend (2000–2019), with decreasing trends occurring in 10%of the resource. Potential drivers for trends were evaluated in two of the areas in southern California with the greatest prevalence of trends but distinct climate and hydrogeological characteristics. Aquifers in the Mojave and Whitewater River watersheds, located in the desert region, and the Los Angeles Basin, located on the coast, have been replenished with imported and treated water over the last half century to maintain sustainable groundwater levels. The recharge of imported water with different chemistries has altered the geochemical conditions in the aquifers, driving changes in fluoride concentrations.

Effects of salinity on olfactory toxicity and behavioral responses of juvenile salmonids from copper

Aquatic Toxicology (Elsevier) | April 4th, 2016

Dissolved copper is one of the more pervasive and toxic constituents of stormwater runoff and is commonly found in stream, estuary, and coastal marine habitats of juvenil

Dissolved copper is one of the more pervasive and toxic constituents of stormwater runoff and is commonly found in stream, estuary, and coastal marine habitats of juvenile salmon. While stormwater runoff does not usually carry copper concentrations high enough to result in acute lethality, they are of concern because sublethal concentrations of copper exposure have been shown to both impair olfactory function and alter behavior in various species in freshwater. To compare these results to other environments that salmon are likely to encounter, experiments were conducted to evaluate the effects of salinity on the impairment of olfactory function and avoidance of copper. Copper concentrations well within the range of those found in urban watersheds, have been shown to diminish or eliminate the olfactory response to the amino acid, l-serine in freshwater using electro-olfactogram (EOG) techniques. The olfactory responses of both freshwater-phase and seawater-phase coho and seawater-phase Chinook salmon, were tested in freshwater or seawater, depending on phase, and freshwater-phase coho at an intermediate salinity of 10‰. Both 10‰ salinity and full strength seawater protected against the effects of 50 μg copper/L. In addition to impairing olfactory response, copper has also been shown to alter salmon behavior by causing an avoidance response. To determine whether copper will cause avoidance behavior at different salinities, experiments were conducted using a multi-chambered experimental tank. The circular tank was divided into six segments by water currents so that copper could be contained within one segment yet fish could move freely between them. The presence of individual fish in each of the segments was counted before and after introduction of dissolved copper (<20 μg/L) to one of the segments in both freshwater and seawater. To address whether use of preferred habitat is altered by the presence of copper, experiments were also conducted with a submerged structural element. The presence of sub-lethal levels of dissolved copper altered the behavior of juvenile Chinook salmon by inducing an avoidance response in both freshwater and seawater. While increased salinity is protective against loss of olfactory function from dissolved copper, avoidance could potentially affect behaviors beneficial to growth, survival and reproductive success.

Effects of Sea‐Level Rise on Ground Water Flow in a Coastal Aquifer System

National Groundwater Association (NGWA) | January 29th, 2007

The effects of sea‐level rise on the depth to the fresh water/salt water interface were simulated by using a density‐dependent, three‐dimensional numerical ground w

The effects of sea‐level rise on the depth to the fresh water/salt water interface were simulated by using a density‐dependent, three‐dimensional numerical ground water flow model for a simplified hypothetical fresh water lens that is similar to shallow, coastal aquifers found along the Atlantic coast of the United States. Simulations of sea‐level rise of 2.65 mm/year from 1929 to 2050 resulted in an increase in water levels relative to a fixed datum, yet a net decrease in water levels relative to the increased sea‐level position. The net decrease in water levels was much greater near a gaining stream than farther from the stream. The difference in the change in water levels is attributed to the dampening effect of the stream on water level changes in response to sea‐level rise. In response to the decreased water level altitudes relative to local sea level, the depth to the fresh water/salt water interface decreased. This reduction in the thickness of the fresh water lens varied throughout the aquifer and was greatly affected by proximity to a ground water fed stream and whether the stream was tidally influenced. Away from the stream, the thickness of the fresh water lens decreased by about 2% from 1929 to 2050, whereas the fresh water lens thickness decreased by about 22% to 31% for the same period near the stream, depending on whether the stream was tidally influenced. The difference in the change in the fresh water/salt water interface position is controlled by the difference in the net decline in water levels relative to local sea level.

Effects of the South Delta Agricultural Barriers on Emigrating Juvenile Salmonids

California Department of Water Resources (DWR) | November 28th, 2018

The TBP is implemented in compliance with the terms and conditions of two NMFS Biological Opinions (BiOp) (NMFS 2008, 2009). To comply with the requirements of the NMFS

The TBP is implemented in compliance with the terms and conditions of two NMFS Biological Opinions (BiOp) (NMFS 2008, 2009). To comply with the requirements of the NMFS BiOps, a study of the effects of the three SDABs (i.e., ORTB, MRB, and GLCB) on emigrating (i.e., out-migrating) juvenile salmonids was conducted (2010–2011) and the results are reported in this document. There were four effects considered in this study: 1) survival of juvenile salmonids (Ŝ); 2) juvenile salmonid time-in-vicinity (TIV) of a barrier; 3) predation on juvenile salmonids; and 4) predatory fish density evaluations near the barriers before-, during-, and after- construction during each study year. For one barrier, the ORTB, two-dimensional (2D) acoustic fish tracks for juvenile salmonids were used to evaluate: 1) the rates of successful passage through the barrier; and 2) route selection through the barrier. In addition, utilizing the ORTB 2D fish tracks for both juvenile salmonids and predatory fish, a mixture model (Romine et al. 2014) approach was employed to determine the probability that a juvenile salmonid had been eaten by a predatory fish in the vicinity of the ORTB.

Effects of Urban Development on Stream Ecosystems in Nine Metropolitan Study Areas Across the United States

U.S. Geological Survey (USGS) | November 13th, 2012

Urban development is an important agent of environmental change in the United States. The urban footprint on the American landscape has expanded during a century and a ha

Urban development is an important agent of environmental change in the United States. The urban footprint on the American landscape has expanded during a century and a half of almost continuous development. Eighty percent of Americans now live in metropolitan areas, and the advantages and challenges of living in these developed areas—convenience, congestion, employment, pollution—are part of the day-to-day realities of most Americans. Nowhere are the environmental changes associated with urban development more evident than in urban streams. Contaminants, habitat destruction, and increasing streamflow flashiness resulting from urban development have been associated with the disruption of biological communities, particularly the loss of sensitive aquatic species. Every stream is connected downstream to larger water bodies, including rivers, reservoirs, and ultimately coastal waters. Inputs of chemical contaminants or sediments at any point along the stream can cause degradation downstream with adverse effects on biological communities and on economically valuable resources, such as fisheries and tourism. In response to general concerns about the degradation of urban streams, the U.S. Geological Survey (USGS) conducted a national-scale, scientific investigation of the effects of urban development on stream ecosystems. Nine metropolitan study areas of the United States were selected—Portland, Oregon; Salt Lake City, Utah; Birmingham, Alabama; Atlanta, Georgia; Raleigh, North Carolina; Boston, Massachusetts; Denver, Colorado; Dallas, Texas; and Milwaukee, Wisconsin. The studies were conducted in Salt Lake City, Birmingham, and Boston in 1999–2000; in Atlanta, Raleigh, and Denver in 2002–2003; and in Portland, Dallas, and Milwaukee in 2003–2004. The comprehensive investigation of all nine studies focused on three broad questions of interest to decision makers: 1. What are the primary effects of urban development on stream ecosystems? 2. How do the effects of urban development on stream ecosystems vary regionally across the country? 3. Which urban-related stressors are most closely linked to biological community degradation, and how can multiple stressors be managed to protect stream health as a watershed becomes increasingly urbanized? RELATED DOCUMENT: Strategies for Managing the Effects of Urban Development on Streams

Effects of vegetation on methylmercury concentrations and loads in a mercury contaminated floodplain

Science of The Total Environment (Elsevier) | August 3rd, 2023

The Yolo Bypass (YB) is a large flood conveyance system designed to protect the city of Sacramento, California, USA from flooding when the Sacramento River approaches flo

The Yolo Bypass (YB) is a large flood conveyance system designed to protect the city of Sacramento, California, USA from flooding when the Sacramento River approaches flood stage. The Sacramento River watershed and YB are a source of methylmercury (MeHg) to downstream habitat as a result of historic mercury (Hg) and gold mining practices. In the dry season, the YB is extensively farmed and grazed. However, depending on the water year, the floodplain may remain inundated for months. Our experiments focused on the role of pasture land and decomposing vegetation as a source of MeHg during extensive periods of floodplain flooding. Decomposing vegetation, rather than sediment, was identified as the principal source of filter passing MeHg (fMeHg) within the floodplain. The decomposing vegetation provided a substrate for microbial methylation of inorganic Hg contained within the plants. In replicated flooded mesocosm experiments, MeHg concentrations increased from 2.78 to 31.0 ng g− 1 dw and 3.41 to 56.8 ng g− 1 dw in decomposing vegetation. In field collections, the concentrations of MeHg in vegetation increased from preflood levels of 2.78 to 45.4 ng g− 1dw after 17 weeks of flooding. The importance of vegetation was shown in laboratory experiments where there was a positive correlation between the amount of fMeHg in water and the amount of vegetation added. These results also provide Hg concentration data for an important functional type of vegetation, grasses, and fill a data gap that contributed to uncertainties with regards to the role of vegetation in Hg cycling.

Electrical Resistivity Imaging of Seawater Intrusion into the Monterey Bay Aquifer System

National Groundwater Association (NGWA) | June 17th, 2015

We use electrical resistivity tomography to obtain a 6.8‐km electrical resistivity image to a depth of approximately 150 m.b.s.l. along the coast of Monterey Bay. The

We use electrical resistivity tomography to obtain a 6.8‐km electrical resistivity image to a depth of approximately 150 m.b.s.l. along the coast of Monterey Bay. The resulting image is used to determine the subsurface distribution of saltwater‐ and freshwater‐saturated sediments and the geologic controls on fluid distributions in the region. Data acquisition took place over two field seasons in 2011 and 2012. To maximize our ability to image both vertical and horizontal variations in the subsurface, a combination of dipole–dipole, Wenner, Wenner‐gamma, and gradient measurements were made, resulting in a large final dataset of approximately 139,000 data points. The resulting resistivity section extends to a depth of 150 m.b.s.l., and is used, in conjunction with the gamma logs from four coastal monitoring wells to identify four dominant lithologic units. From these data, we are able to infer the existence of a contiguous clay layer in the southern portion of our transect, which prevents downward migration of the saltwater observed in the upper 25 m of the subsurface to the underlying freshwater aquifer. The saltwater and brackish water in the northern portion of the transect introduce the potential for seawater intrusion into the hydraulically connected freshwater aquifer to the south, not just from the ocean, but also laterally from north to south.

Electron bifurcation and fluoride efflux systems implicated in defluorination of perfluorinated unsaturated carboxylic acids by Acetobacterium spp

American Association for the Advancement of Science (AAAS) | July 17th, 2024

Emerging PFAS Trends in Water and Sediment from San Francisco Bay

San Francisco Estuary Institute (SFEI) | August 14th, 2025

Per- and polyfluoroalkyl substances (PFAS) are a diverse class of persistent compounds, including several that are bioaccumulative and known or suspected to be toxic. The

Per- and polyfluoroalkyl substances (PFAS) are a diverse class of persistent compounds, including several that are bioaccumulative and known or suspected to be toxic. These unique compounds have widespread uses across consumer, commercial, and industrial products, resulting in widespread occurrence in humans, the environment, and wildlife across the globe. Within San Francisco Bay, the RMP has monitored PFAS across the Bay ecosystem, beginning in 2004 with various biota and since expanding to sediment, surface water, stormwater, and wastewater. These studies found PFAS throughout the Bay, especially in sport fish, where concentrations are of potential concern for human health and led to a classification of PFAS as High Concern for the Bay under the RMP tiered risk-based framework for emerging contaminants.  This study examined Bay sediment and surface water to continue to build our understanding of the occurrence, fate, and risks of PFAS to ecological and human health. Using a targeted method, 40 PFAS were analyzed in Bay sediment collected in three monitoring cruises from 2017 to 2023, and Bay water collected from 2021 to 2023 during both the dry and wet seasons. The Total Oxidizable Precursor (TOP) assay was also used to supplement these findings by indirectly measuring unknown perfluoroalkyl acid (PFAA) precursors of detectable PFAS. This additional information aids in elucidating the broader levels of PFAS present in samples to better evaluate the exposure and risk to the Bay. 

Emerging understanding of the potential role of seagrass and kelp as an ocean acidification management tool in California

California Ocean Science Trust (OST) | January 2nd, 2018

This report was produced by the OPC-SAT working group and Ocean Science Trust on behalf of the Ocean Protection Council (OPC) and the broader community of California man

This report was produced by the OPC-SAT working group and Ocean Science Trust on behalf of the Ocean Protection Council (OPC) and the broader community of California managers with the aim of: • communicating emerging scientific understanding of the ability of seagrass and macroalgae (kelps) to ameliorate ocean acidification (OA) in a California-specific context, • summarizing knowledge gaps and opportunities for filling them through research and monitoring, and • providing guidance on next steps for the State as it considers future nature-based actions to reduce the negative impacts of OA in California and beyond.