Comparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California

Environmental Pollution (Elsevier) | October 10th, 2022

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to pla

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to planting). In California, multiple crops, including lettuce, can be grown using neonicotinoid treated seeds or receive a direct neonicotinoid soil application (drenching) at planting. Using research plots, this study compared pesticide runoff in four treatments: (1) imidacloprid seed treatment; (2) clothianidin seed treatment; (3) imidacloprid drench and an azoxystrobin seed treatment; and (4) a control with no pesticidal treatment. Neonicotinoid and azoxystrobin concentrations were measured in surface water runoff during six irrigations events in the 2020 growing seasons. Results showed runoff concentrations up to 1308 (±1200) ng L−1 for imidacloprid drench treatment, 431 (±100) ng L−1 for clothianidin seed treatment, 135 (±60) ng L−1 for imidacloprid seed treatment, 13 (±10) ng L−1 for azoxystrobin seed treatment (treatments averaged). The percent of applied mass in runoff over the entire sampling period varied by compound; the imidacloprid seed treatment and drench were similar (0.015 and 0.019%, respectively) to the clothianidin seed treatment (0.036%) while the azoxystrobin seed treatment was much higher (15%). Although the proportion of imidacloprid in runoff was similar for imidacloprid treatments, the mass applied during soil drench was > 4x the amount applied from the imidacloprid seed treatment. Surface soils were collected before planting and at the end of the trial. The neonicotinoids were detected in soil throughout the study and average maximum concentrations were 9–13 ng g−1; azoxystrobin was detected in only two soils at concentrations up to 0.57 ng g−1. These results elucidate the comparative mass runoff resulting from planting treated seed and soil drench applications and highlight the value of additional work to characterize off-site transport from the many commodities that may be utilizing treated seeds.

Comparison of potential drinking water source contamination across one hundred U.S. cities

Nature Portfolio (Springer Nature) | December 13th, 2021

Drinking water supplies of cities are exposed to potential contamination arising from land use and other anthropogenic activities in local and distal source watersheds. B

Drinking water supplies of cities are exposed to potential contamination arising from land use and other anthropogenic activities in local and distal source watersheds. Because water quality sampling surveys are often piecemeal, regionally inconsistent, and incomplete with respect to unregulated contaminants, the United States lacks a detailed comparison of potential source water contamination across all of its large cities. Here we combine national scale geospatial datasets with hydrologic simulations to compute two metrics representing potential contamination of water supplies from point and nonpoint sources for over a hundred U.S. cities. We reveal enormous diversity in anthropogenic activities across watersheds with corresponding disparities in the potential contamination of drinking water supplies to cities. Approximately 5% of large cities rely on water that is composed primarily of runoff from non-pristine lands (e.g., agriculture, residential, industrial), while four-fifths of all large cities that withdraw surface water are exposed to treated wastewater in their supplies.

Comparison of the Performance of Different Bioassessment Methods: Similar Evaluations of Biotic Integrity from Separate Programs and Procedures

Journal of the North American Benthological Society (University of Chicago Press) | January 16th, 2006

Regional bioassessment programs of states, various federal agencies, and other governmental and private groups often use different methods to collect and analyz

Regional bioassessment programs of states, various federal agencies, and other governmental and private groups often use different methods to collect and analyze stream invertebrate samples. This lack of uniformity has created concern and confusion over the comparability of disparate sources of data, but few studies have attempted to evaluate differences in performance between methods or to reconcile the results produced from different methods. We conducted concurrent sampling at 40 sites in the eastern Sierra Nevada of California using 3 bioassessment methods to obtain directly comparable data sets. The riffle-based methods (University of California Sierra Nevada Aquatic Research Laboratory [UC-SNARL, Lahontan Water Board], California Stream Bioassessment Protocol, and US Forest Service Region 5) differed at each stage from field sample collection to laboratory processing and data analysis. We used a performance-based methods system to compare precision, uniformity, discrimination, accuracy, and correlations among multimetric Index of Biotic Integrity (IBI) scores and multivariate River Invertebrate Prediction and Classification System (RIVPACS)-type observed/expected (O/E) ratios. Reference and test sites were identified using local and upstream-watershed disturbance criteria, and invertebrate community measures and models were then developed to discriminate between reference and test sites. The more- intensive UC-SNARL method showed slightly, but consistently, greater sensitivity for discriminating impairment than the other 2 methods. The UC-SNARL method produced greater differences between reference- and test-site means relative to lower reference-site standard deviations than the other 2 methods. However, assessment scores were highly correlated among methods and distinguished reference from test sites with similar accuracy among methods despite the slight differences in performance. Our results show that differing bioassessment methods can yield very similar, effective discrimination of impaired biological condition even though they have multiple differences in field and laboratory protocols (mesh size, replication, area sampled, taxonomic resolution, total counts). Moreover, this conclusion did not depend on the approach taken to data analysis because both multimetric IBIs and multivariate RIVPACS-type O/Es were in close agreement. Methodological uniformity is important when coordinating monitoring programs, but our results suggest that data from multiple sources could potentially be used interchangeably and for cross-validation of assessments of stream biological integrity.

Comparisons of Targeted-riffle and Reach-wide Benthic Macroinvertebrate Samples: Implications for Data Sharing in Stream-condition Assessments

Journal of the North American Benthological Society (University of Chicago Press) | January 1st, 2007

Recent comparisons of benthic macroinvertebrate (BMI) sampling protocols have shown that samples collected from different habitat types generally produce consis

Recent comparisons of benthic macroinvertebrate (BMI) sampling protocols have shown that samples collected from different habitat types generally produce consistent stream classifications and assessments. However, these comparisons usually have not included biological endpoints used by monitoring agencies, such as multimetric indices (e.g., benthic index of biotic integrity [B-IBI]) or observed- to-expected (O/E) indices of taxonomic completeness, as target variables, and estimates of method precision are rarely provided. Targeted-riffle (TR) and reach-wide (RW) benthic samples have been collected at thousands of sites across the western USA, but little guidance is available for understanding 1) the extent to which raw data sets can be combined in regional or large-scale analyses, 2) the degree of precision afforded by each method, or 3) the efficacy of cross-application of biological indicators derived from one sample type to the other. To address these issues, we used data from 193 sites in California where the Environmental Monitoring and Assessment Program (EMAP) collected the 2 samples side by side. We also conducted a separate study wherein 3 replicates of each sample type were collected from 15 streams to estimate minimum detectable difference (MDD) as a measure of each method’s precision. Metrics calculated from TR and RW samples showed similar dose–response relationships to stressors gradients and similar raw scoring ranges. Biological indices (B-IBI, O/E0, and O/E50) derived from RW samples were more precise than those derived from TR samples, but precision differences were not substantial. On average, pairwise differences in any index between TR and RW sample types were much less than the MDD associated with either sampling method. We observed a weak but consistent bias toward higher O/E50 scores from TR samples than from RW samples at the highest elevations and in the largest watersheds. Broad-scale condition assessments were nearly identical when B-IBI and O/E0 were used as endpoints, and assessments based on O/E50 were only slightly less similar. Our analyses indicate that raw data sets and biological indicators derived from TR and RW samples may be generally interchangeable when used in ambient biomonitoring programs.

Comprehensive Groundwater Cleanup Strategy for Historical Chromium Discharges from PG&E's Hinkley Compressor Station, San Bernardino County, Final Environmental Impact Report Volume I: Comments on Draft EIR and Responses

California State Water Resources Control Board (SWRCB) | April 20th, 2013

Click here for Volume II

Click here for Volume II

Concentrations for total dissolved solids, arsenic, boron, fluoride, and nitrite-nitrate for wells sampled in the Mojave Water Agency Management Area

U.S. Geological Survey (USGS) | July 1st, 2001

Concentrations for total dissolved solids, arsenic, boron, fluoride, and nitrite-nitrate for wells sampled in the Mojave Water Agency Management Area, California, 1991-97

U.S. Geological Survey (USGS) | January 31st, 2001

Concentrations, Loads, and Associated Trends of Nutrients Entering the Sacramento–San Joaquin Delta, California

University of California, Davis (UC Davis) | December 15th, 2021

Statistical modeling of water-quality data collected at the Sacramento River at Freeport and San Joaquin River near Vernalis, California, USA, was used to examine trends

Statistical modeling of water-quality data collected at the Sacramento River at Freeport and San Joaquin River near Vernalis, California, USA, was used to examine trends in concentrations and loads of various forms of dissolved and particulate nitrogen and phosphorus that entered the Sacramento–San Joaquin River Delta (Delta) from upstream sources between 1970 and 2019. Ammonium concentrations and loads decreased at the Sacramento River site from the mid-1970s through 1990 because of the consolidation of wastewater treatment and continuously reduced from the mid-1970s to 2019 at the San Joaquin River site. Current ammonium concentrations are mostly below 4 µM (0.056 mg N L–1) at both sites, a concentration above which reductions in phytoplankton productivity or changes in algal species composition may occur. The Sacramento River at Freeport site is located upstream of the Sacramento Regional County Sanitation District’s treatment facility’s discharge point; nutrient water quality there is representative of upstream sources. Inorganic nitrogen (nitrate plus ammonium) concentrations and loading differed at both sites. At the Sacramento River location, concentrations decrease in the summer agricultural season, reducing the molar ratios of nitrogen to phosphorus. In contrast, inorganic nitrogen concentrations increase in the San Joaquin River during the agricultural season as a result of irrigation runoff, increasing the molar ratio of nitrogen to phosphorus. This increase suggests a possible nitrogen limitation in the northern Delta and a phosphorus limitation in the southern Delta, as indicated by the molar ratios of bioavailable nitrogen to bioavailable phosphorus. Planned upgrades to the Sacramento Regional Wastewater Treatment Plant (SRWTP) will reduce inorganic nitrogen inputs to the northern Delta. Consequently, the supply of bioavailable nitrogen throughout the upper estuary should diminish. Source modeling of nitrogen and phosphorus identifies agriculture, atmospheric deposition, and wastewater effluent as sources of total nitrogen in the Central Valley. In contrast, geologic sources, agriculture, and wastewater discharge are the primary sources of phosphorus.

Conceptual and Numerical Models of Dissolved Solids in the Colorado River, Hoover Dam to Imperial Dam, and Parker Dam to Imperial Dam, Arizona, California, and Nevada

U.S. Geological Survey (USGS) | August 28th, 2018

Conceptual and numerical models were developed to understand and simulate monthly flow-weighted dissolved-solids concentrations in the Colorado River at Imperial

Conceptual and numerical models were developed to understand and simulate monthly flow-weighted dissolved-solids concentrations in the Colorado River at Imperial Dam. The ability to simulate dissolved-solids concentrations at this location will help the Bureau of Reclamation satisfy the binational agreement on the volume and salinity of Colorado River water delivered to Mexico. A robust spatial- and temporal-resolution dataset that consists of river discharge and dissolved-solids concentration and load information between January 1990 and September 2016 for 10 sites on canals, drains, tributaries, and the main stem of the Colorado River between Hoover and Imperial Dams was generated. Daily mean dissolved-solids concentrations were estimated and monthly mean dissolved-solids loads were computed for each site. Spatial and temporal load patterns, and historical and current controls on loads and concentrations, were analyzed in order to develop a conceptual model of dissolved- solids transport between Hoover and Imperial Dams. Two numerical models describing the relations between dissolved- solids concentrations and components controlling dissolved-solidsconcentrations and loads were developed, calibrated, and verified. Between January 1990 and September 2016, there was a 98.8-million-acre-feet loss of water and a 57.0-million-ton loss of dissolved-solids load from the Colorado River between Hoover and Imperial Dams. Between Hoover and Parker Dams, about 69.0 million acre-feet of water was lost and 51.1 million tons of dissolved solids were lost; between Parker and Imperial Dams, about 29.8 million acre-feet of water was lost and 5.9 million tons of dissolved solids were lost. Water was removed from the river at a relatively consistent rate over the 25-year study period through water transfers to California and Arizona, evapotranspiration from crop irrigation, transpiration processes of riparian vegetation, and evaporation from the river main stem. Dissolved solids were removed from the river between Hoover and Parker Dams at a relatively constant rate through water transfers to California and Arizona, and water pumped from the river for irrigation within the Mohave Valley. A small amount of dissolved solids are gainedby the river from inflow from the Bill Williams River. Between Parker and Imperial Dams, however, dissolved solids were not removed from the river at a consistent rate over the study period. Dissolved solids were generally removed from the river from 1990 to 2012, then gained by the river from 2012 to 2015, and then removed from the river from 2015 through 2016. Dissolved solids are assumed to be removed from the river and accumulated within the floodplain sediments and aquifers during irrigation processes; some dissolved solids may also be removed from the river through uptake by crops and riparian vegetation. Dissolved solids accumulated on the landscape and in the floodplain aquifer during irrigation are transported to the river during periods when the hydraulic gradient between the floodplain aquifer and the river is increased, causing a gain in dissolved solids in the river. Dissolved-solids gains in the river occur during periods of relatively low river discharge, such as during the winter months and during drier climatic conditions. Two numerical models were developed and coefficientswere estimated by using data from a May 2008-September 2016 calibration period. One model simulates concentrations at Imperial Dam based on the Colorado River system downstream from Parker Dam, and the other model simulates concentrations at Imperial Dam based on the Colorado River system downstreamfrom Hoover Dam. Both models simulated monthly flow-weighted concentrations of dissolved solids for the Colorado River at Imperial Dam, which corresponded well with observed concentrations for the entire study period. The models are more sensitive to input variables of monthly discharge of the ColoradoRiver below Parker Dam and monthly flow-weighted dissolved-solids concentrations of the Colorado River below Hoover Dam and Parker Dam than to the rate of change in concentration with respect to time and the combined discharge of the Colorado River Indian Reservation Main Canal and the Palo Verde Canal. The calibrated models can be used to run scenarios of future monthlyflow-weighted dissolved-solids concentrations in the ColoradoRiver at Imperial Dam. Although the models are expected to provide concentration estimates within 18 milligrams per liter (Parker Dam to Imperial Dam model) to 22 milligrams per liter (Hoover Dam to Imperial Dam model), 95 percent of the time, the error of future scenarios increases as uncertainty in the estimated future input variables increases.

Conceptual model for salinity in the Central Valley and Sacramento-San Joaquin Delta

Central Valley Drinking Water Policy Workgroup | July 13th, 2007

This report examines the state of knowledge about the causes of salinity increase in the system and opportunities to improve the Delta as a source of municipal and agricu

This report examines the state of knowledge about the causes of salinity increase in the system and opportunities to improve the Delta as a source of municipal and agricultural water supply. It begins with background information about salinity, its measurement, and its impacts. Following that, we present observed salinity in the Bay-Delta system. The conceptual models section, the core of this report, then seeks to explain the forces and processes (drivers) that cause the salinity patterns we observe. The computational models section introduces some of the tools available to assist with salinity management and planning. The last chapter explores the implications of the conceptual model for monitoring and management of salinity.