Climatic regulation of the neurotoxin domoic acid

National Academy of Sciences (NAS) | January 9th, 2017

Domoic acid is a potent neurotoxin produced by certain marine microalgae that can accumulate in the foodweb, posing a health threat to human seafood consumers a

Domoic acid is a potent neurotoxin produced by certain marine microalgae that can accumulate in the foodweb, posing a health threat to human seafood consumers and wildlife in coastal regions worldwide. Evidence of climatic regulation of domoic acid in shellfish over the past 20 y in the Northern California Current regime is shown. The timing of elevated domoic acid is strongly related to warm phases of the Pacific Decadal Oscillation and the Oceanic Niño Index, an indicator of El Niño events. Ocean conditions in the northeast Pacific that are associated with warm phases of these indices, including changes in prevailing currents and advection of anomalously warm water masses onto the continental shelf, are hypothesized to contribute to increases in this toxin. We present an applied domoic acid risk assessment model for the US West Coast based on combined climatic and local variables. Evidence of regional- to basin-scale controls on domoic acid has not previously been presented. Our findings have implications in coastal zones worldwide that are affected by this toxin and are particularly relevant given the increased frequency of anomalously warm ocean conditions.

Coagulant and Sorbent Efficacy in Removing Mercury from Surface Waters in the Cache Creek Watershed, California

U.S. Geological Survey (USGS) | February 25th, 2019

Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is c

Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, the use of coagulants and sorbents to immobilize Hg in water samples from high- concentration sources in the Cache Creek watershed was investigated. Three sites were selected for the collection of surface-water samples containing high and low concentrations of particulate-associated Hg. The high-particulate Hg samples were collected from Cache Creek Settling Basin duringstormflow conditions. The low-particulate Hg samples werecollected from two geochemically contrasting sites duringbase-flow conditions (downstream from a geothermal springand at the emergence point of a connate-water spring). Three coagulants were chosen for laboratory testing with the high-particulate sample— (1) ChitoVanTM HV 1.5 percent (shell based), (2) FerralyteTM 8131 (ferric sulfate based), and (3) UltrionTM 8186 (aluminum based). Each coagulant was tested at various dose amounts to determine the optimum dose rate for the high-particulate sample. The low-particulate source samples were passed through three sorbents— (1) chitosan flakes, (2) coconut shell-based activated carbon,and (3) coal-based activated carbon. In-line columns were packed with each material, and the untreated sample waspassed through each column at three different flow rates (0.1,0.5, and 1.0 liter per minute, L/min). For dose rates used in this study, ChitoVanTM reduced turbidity of the particulate sample by 85–91 percent, FerralyteTM reduced turbidity by 54–93 percent, and UltrionTMreduced turbidity by greater than 90 percent. At the lowest dose rate, ChitoVanTM achieved a 59- to 61-percent reduction in whole-water methylmercury (MeHg) concentrations and a 71- to 75-percent decrease in whole-water total mercury  (THg) concentrations. FerralyteTM achieved a 37- to 48-percent decrease in whole-water MeHg concentrations and a 37- to 48-percent reduction in whole-water THg concentrations. UltrionTM achieved a greater than 90-percent decrease in whole-water MeHg and THg concentrations. Mercury removal from the low-particulate samples was less efficient for the sorbent materials compared to the coagulants; less than 30 percent of THg was removed from any 500-milliliter aliquot using sorbent materials. The coal-based sorbent was the most versatile of the sorbents, removing THg to a similar extent from both low-particulatesource waters. The chitosan sorbent was the most effective atremoving THg from the low-particulate stream sample, but less effective for the low-particulate connate-spring sample. The Hg removal efficiency of the coconut sorbent decreasedquickly compared to the other two sorbents, indicating that sorption may be limited by the short contact times evaluated in this study.

Comments of San Francisco Baykeeper et al re: Draft Staff Report on Sacramento/Delta Updates

San Francisco Baykeeper | January 19th, 2024

In the face of a growing and severe ecological crisis, the Board has spent the better part of two decades crafting updates to the Bay-Delta Plan to reasonably protect fi

In the face of a growing and severe ecological crisis, the Board has spent the better part of two decades crafting updates to the Bay-Delta Plan to reasonably protect fish and wildlife beneficial uses. These delayed and too often meager efforts have so far done nothing to reverse the catastrophic path we are on, despite the potential permanent loss of these beneficial uses. The Draft Staff Report’s proposed project and the Voluntary Agreement alternatives will not change our course.

Comments on and Protest of Temporary Urgency Change Petition Regarding Delta Water Quality

California State Water Resources Control Board (SWRCB) | February 17th, 2023

Comments on the Draft Pyrethroid Control Program and Research Plan

Delta Stewardship Council (Delta Council) | September 18th, 2023

Comments on the Scientific Basis for Implementation of Voluntary Agreements for the Sacramento River, Delta, and Tributaries

Delta Stewardship Council (Delta Council) | March 8th, 2023

Communities that rely on a contaminated groundwater source for drinking water

California State Water Resources Control Board (SWRCB) | January 1st, 2013

AB 2222 (Caballero, Chapter 670, Statutes of 2008) requires the State Water Resources Control Board to submit a report to the Legislature that identifies: 1) communities

AB 2222 (Caballero, Chapter 670, Statutes of 2008) requires the State Water Resources Control Board to submit a report to the Legislature that identifies: 1) communities in California that rely on contaminated groundwater as a primary source of drinking water; 2) the principal contaminants and other constituents of concern; and 3) potential solutions and funding sources to clean up or treat groundwater or provide alternative water supplies. A “community,” for the purposes of this report, is defined as a Community Public Water System (Health and Safety Code Section 116395). When this report refers to communities that rely on a contaminated groundwater source, it is referring to community public water systems that draw water from a contaminated groundwater source prior to any treatment. Over 95 percent of the 38 million Californians get their drinking water from a public water system. The findings in this report do not reflect private domestic wells or other unregulated water systems since the state does not require these groundwater users to sample their wells, and consequently a comprehensive database for these groundwater sources does not exist. This report identifies 680 community water systems that, prior to any treatment, relied on a contaminated groundwater source during the most recent California Department of Public Health (CDPH) compliance cycle (2002-2010). It is important to note that, according to CDPH, over 98% of Californians on public water supply are served safe drinking water. Although many water suppliers draw from contaminated groundwater sources, most suppliers are able to treat the water or blend it with cleaner supplies before serving it to the public. Consequently, when this report refers to communities that rely on contaminated groundwater, it is referring to community public water systems that draw water from one or more contaminated groundwater wells prior to any treatment or blending. Some community water systems, however, cannot afford treatment or lack alternative water sources, and have served water that exceeds a public drinking water standard. Of the 680 community water systems that rely on a contaminated groundwater source, 265 have served water that exceeded a public drinking water standard during the most recent CDPH compliance cycle (2002-2010).

Comparing domestic and public-supply groundwater quality in the northern San Joaquin Valley, 2019—California GAMA Priority Basin Project

U.S. Geological Survey (USGS) | June 5th, 2023

Groundwater quality in the Northern San Joaquin Valley region of California was studied as part of California State Water Resources Control Board (SWRCB) Groundwater Ambi

Groundwater quality in the Northern San Joaquin Valley region of California was studied as part of California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment Program-Priority Basin Project (GAMA-PBP). The GAMA-PBP made a spatially unbiased assessment of the aquifer system used for domestic drinking-water supply in the study region and compared the results to the aquifer system used for public drinking-water supply. These assessments characterized the quality of raw groundwater to evaluate ambient conditions in regional aquifers and not the quality of treated drinking water. The study included two components: (1) a status assessment presenting study results summarizing the status of groundwater quality used for domestic supply in the Northern San Joaquin Valley and (2) a comparative assessment of groundwater resources used for domestic and public drinking-water supply in the study region.

Comparing Domestic and Public-Supply Groundwater Quality in the Northern San Joaquin Valley, 2019: California GAMA Priority Basin Project

U.S. Geological Survey (USGS) | June 5th, 2023

Analysis of construction data for wells included in the comparative assessment indicated that, although depth to top of perforations are comparable for domestic and publi

Analysis of construction data for wells included in the comparative assessment indicated that, although depth to top of perforations are comparable for domestic and public-supply wells in the Northern San Joaquin Valley (median depth about 60 meters [m]), public-supply wells have longer perforation intervals and extend to deeper parts of the aquifer system (exceeding 120 m) than domestic wells that typically draw exclusively from the shallower aquifer system in the upper 80 m of unconsolidated sediments. Analysis of the vertical and lateral distribution of constituents of interest (nitrate, fumigants, and arsenic) across domestic- and public-supply aquifers indicated that nitrate is prevalent in shallow aquifers throughout the Northern San Joaquin Valley but is potentially diluted by mixing with deeper, older groundwater at long-screened public-supply wells. Fumigants were prevalent in areas of urban and agricultural land use in the western part of the Northern San Joaquin Valley, particularly in areas near Lodi, California, but 1,2,3-TCP was more widespread than DBCP and was detected in shallow and deeper parts of the aquifer system, potentially because of its recalcitrance in groundwater and ability to be detected at low concentrations. Arsenic was most prevalent in the western part of the Northern San Joaquin Valley with proximity to deltaic sediments and was detected at high RCs in wells tapping shallow and deep parts of the aquifer system.

Comparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California

Environmental Pollution (Elsevier) | October 10th, 2022

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to pla

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to planting). In California, multiple crops, including lettuce, can be grown using neonicotinoid treated seeds or receive a direct neonicotinoid soil application (drenching) at planting. Using research plots, this study compared pesticide runoff in four treatments: (1) imidacloprid seed treatment; (2) clothianidin seed treatment; (3) imidacloprid drench and an azoxystrobin seed treatment; and (4) a control with no pesticidal treatment. Neonicotinoid and azoxystrobin concentrations were measured in surface water runoff during six irrigations events in the 2020 growing seasons. Results showed runoff concentrations up to 1308 (±1200) ng L−1 for imidacloprid drench treatment, 431 (±100) ng L−1 for clothianidin seed treatment, 135 (±60) ng L−1 for imidacloprid seed treatment, 13 (±10) ng L−1 for azoxystrobin seed treatment (treatments averaged). The percent of applied mass in runoff over the entire sampling period varied by compound; the imidacloprid seed treatment and drench were similar (0.015 and 0.019%, respectively) to the clothianidin seed treatment (0.036%) while the azoxystrobin seed treatment was much higher (15%). Although the proportion of imidacloprid in runoff was similar for imidacloprid treatments, the mass applied during soil drench was > 4x the amount applied from the imidacloprid seed treatment. Surface soils were collected before planting and at the end of the trial. The neonicotinoids were detected in soil throughout the study and average maximum concentrations were 9–13 ng g−1; azoxystrobin was detected in only two soils at concentrations up to 0.57 ng g−1. These results elucidate the comparative mass runoff resulting from planting treated seed and soil drench applications and highlight the value of additional work to characterize off-site transport from the many commodities that may be utilizing treated seeds.