From Sediment to Top Predators: Broad Exposure of Polyhalogenated Carbazoles in San Francisco Bay

American Chemical Society (ACS) | January 23rd, 2017

The present study provides the first comprehensive investigation of polyhalogenated carbazoles (PHCZs) contamination in an aquatic ecosystem. PHCZs have been found in soi

The present study provides the first comprehensive investigation of polyhalogenated carbazoles (PHCZs) contamination in an aquatic ecosystem. PHCZs have been found in soil and aquatic sediment from several different regions, but knowledge of their bioaccumulation and trophodynamics is extremely scarce. This work investigated a suite of 11 PHCZ congeners in San Francisco Bay (United States) sediment and organisms, including bivalves (n = 6 composites), sport fish (n = 12 composites), harbor seal blubber (n = 18), and bird eggs (n = 8 composites). The most detectable congeners included 3,6-dichlorocarbazole (36-CCZ), 3,6-dibromocarbazole (36-BCZ), 1,3,6-tribromocarbazole (136-BCZ), 1,3,6,8-tetrabromocarbazole (1368-BCZ), and 1,8-dibromo-3,6-dichlorocarbazole (18-B-36-CCZ). The median concentrations of ΣPHCZs were 9.3 ng/g dry weight in sediment and ranged from 33.7 to 164 ng/g lipid weight in various species. Biomagnification was observed from fish to harbor seal and was mainly driven by chlorinated carbazoles, particularly 36-CCZ. Congener compositions of PHCZs differed among species, suggesting that individual congeners may be subject to different bioaccumulation or metabolism in species occupying various trophic levels in the studied aquatic system. Toxic equivalent (TEQ) values of PHCZs were determined on the basis of their relative effect potencies (REP) compared to 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). The median TEQ was 1.2 pg TEQ/g dry weight in sediment and 4.8–19.5 pg TEQ/g lipid weight in biological tissues. Our study demonstrated the broad exposure of PHCZs in San Francisco Bay and their characteristics of bioaccumulation and biomagnification along with dioxin-like effects. These findings raise the need for additional research to better elucidate their sources, environmental behavior, and fate in global environments.

From Storage to Retention: Expanding California's Options for Meeting Its Water Needs

California Roundtable on Water and Food Supply (CRWFS) | November 19th, 2012

Achieving a more effective and flexible water storage system requires a shift in the way that we, as a society, understand, define, and use storage as an element of integ

Achieving a more effective and flexible water storage system requires a shift in the way that we, as a society, understand, define, and use storage as an element of integrated water management. Broadening our view of what constitutes a storage reservoir must be accompanied by a shift in our policies and programs to support a “retention” approach to storage—one that holds as much water as possible in the landscape for later use, while maintaining healthy ecosystems. To be more resilient and better prepared for future variations in water supply, California must take advantage of all storage opportunities throughout the system that meet the goals of reliable water supply and ecosystem restoration. Several valuable aspects of water storage tend to be overlooked in terms of their ability to contribute to the availability and reliability of water supplies for uses that benefit society. In particular, California’s agricultural lands play an important role in the storage infrastructure. The value of working lands in helping to sequester water for later use while achieving many benefits, such as food security, flood management and habitat restoration, represents a critical missed opportunity for improving water security. Four key principles must guide efforts to ensure effective water retention in the future: 1. Storage integrates all hydrological components affecting water availability, movement, and retention to improve supply reliability statewide for evolving needs. 2. Comprehensive, timely, accurate, accessible, and transparent data and resulting information about our water resources is an essential foundation for effectively managing water storage in California. 3. An effective storage system requires the coordination of policies and regulations, activities, oversight, and accountability of all government agencies to meet local, regional, and statewide needs simultaneously. 4. Water storage and retention for improved water supply reliability and watershed health is facilitated by the availability of new sources of financial support that allow investment in quantified outcomes. Improving the flow of information through coordinated data management and institutional coordination can lead to powerful water retention outcomes. Several new and innovative funding mechanisms can complement traditional funding streams for water retention and are particularly well suited to agricultural applications.

From the extreme to the mean: Acceleration and tipping points of coastal inundation from sea level rise

American Geophysical Union (AGU) | December 18th, 2014

Relative sea level rise (RSLR) has driven large increases in annual water level exceedances (duration and frequency) above minor (nuisance level) coastal flooding elevat

Relative sea level rise (RSLR) has driven large increases in annual water level exceedances (duration and frequency) above minor (nuisance level) coastal flooding elevation thresholds established by the National Weather Service (NWS) at U.S. tide gauges over the last half-century. For threshold levels below 0.5 m above high tide, the rates of annual exceedances are accelerating along the U.S. East and Gulf Coasts, primarily from evolution of tidal water level distributions to higher elevations impinging on the flood threshold. These accelerations are quantified in terms of the local RSLR rate and tidal range through multiple regression analysis. Along the U.S. West Coast, annual exceedance rates are linearly increasing, complicated by sharp punctuations in RSLR anomalies during El Niño Southern Oscillation (ENSO) phases, and we account for annual exceedance variability along the U.S. West and East Coasts from ENSO forcing. Projections of annual exceedances above local NWS nuisance levels at U.S. tide gauges are estimated by shifting probability estimates of daily maximum water levels over a contemporary 5-year period following probabilistic RSLR projections of Koppet al.(2014) for representative concentration pathways(RCP) 2.6, 4.5, and 8.5. We suggest a tipping point for coastal inundation (30 days/per year with a threshold exceedance) based on the evolution of exceedance probabilities. Under forcing associated with the local-median projections of RSLR, the majority of locations surpass the tipping point over the next several decades regardless of specific RCP.

From the sanitary city to the sustainable city: challenges to institutionalising biogenic (nature’s services) infrastructure

Local Environment (Routledge) | January 4th, 2010

Much has been made of the need for cities to becomemore sustainable, particularly since for the first time in human history over half of the world’s population are urb

Much has been made of the need for cities to becomemore sustainable, particularly since for the first time in human history over half of the world’s population are urban dwellers. Cities concentrate human activities in an exceptionally powerful manner, and this includes resource use and the generation of pollution. Attention has turned towards cities for their capacity to enhance and use nature’s services – ecological sustainability – to remediate some of their own environmental impacts. Insufficient attention has been paid to the challenges of implementation of this new approach to infrastructure in an era of devolution and skepticism about government. This paper discusses these twin and interwoven questions through the lens of an on-going natural experiment, the implementation of a million tree-planting campaign in Los Angeles, CA.

From the Sierra to the Sea: The Ecological History of the San Francisco Bay-Delta Watershed

Bay Institute | July 15th, 2003

A vast watershed connects the mountain streams surrounding California’s Central Valley with San Francisco Bay and the ocean beyond. Over the course of the last two cent

A vast watershed connects the mountain streams surrounding California’s Central Valley with San Francisco Bay and the ocean beyond. Over the course of the last two centuries, much of the natural productivity, biodiversity and ecological integrity of the watershed has been destroyed by modifying the environment without fully understanding the long-term environmental consequences. Long the site of some of the nation’s most intensive conflicts over the use of land and water resources, this system is now emerging as the focus of one of the most ambitious ecological restoration efforts ever undertaken in the United States. This report was designed to provide a coherent and defensible ecological framework and information base for restoration. The need for such an historical, broad-scale perspective on system ecology stems from two fundamental principles of ecological restoration - the need to manage toward a natural template and to manage at ecosystem and landscape levels.

From the Sierra to the Sea: The Ecological History of the San Francisco Bay-Delta Watershed

Bay Institute | January 1st, 1998

A vast watershed connects the mountain streams surrounding California’s Central Valley with San Francisco Bay and the ocean beyond. Over the course of the last two cent

A vast watershed connects the mountain streams surrounding California’s Central Valley with San Francisco Bay and the ocean beyond. Over the course of the last two centuries, much of the natural productivity, biodiversity and ecological integrity of the watershed has been destroyed by modifying the environment without fully understanding the long-term environmental consequences. Long the site of some of the nation’s most intensive conflicts over the use of land and water resources, this system is now emerging as the focus of one of the most ambitious ecological restoration efforts ever undertaken in the United States. This report was designed to provide a coherent and defensible ecological framework and information base for restoration. The need for such an historical, broad-scale perspective on system ecology stems from two fundamental principles of ecological restoration - the need to manage toward a natural template and to manage at ecosystem and landscape levels.

From wastewater treatment plants to decentralized resource factories

Nature Portfolio (Springer Nature) | June 10th, 2024

Frontiers in Ecology and the Environment: Alteration of streamflow magnitudes and potential ecological consequences: a multiregional assessment

Ecological Society of America (Wiley) | October 19th, 2010

Human impacts on watershed hydrology are widespread in the US, but the prevalence and severity of streamflow alteration and its potential ecological consequences have not

Human impacts on watershed hydrology are widespread in the US, but the prevalence and severity of streamflow alteration and its potential ecological consequences have not been quantified on a national scale. We assessed streamflow alteration at 2888 streamflow monitoring sites throughout the conterminous US. The magnitudes of mean annual (1980–2007) minimum and maximum streamflows were found to have been altered in 86% of assessed streams. The occurrence, type, and severity of streamflow alteration differed markedly between arid and wet climates. Biological assessments conducted on a subset of these streams showed that, relative to eight chemical and physical covariates, diminished flow magnitudes were the primary predictors of biological integrity for fish and macroinvertebrate communities. In addition, the likelihood of biological impairment doubled with increasing severity of diminished streamflows. Among streams with diminished flow magnitudes, increasingly common fish and macroinvertebrate taxa possessed traits characteristic of lake or pond habitats, including a preference for fine-grained substrates and slow-moving currents, as well as the ability to temporarily leave the aquatic environment.

Functional Flows in Modified Riverscapes: Hydrographs, Habitats and Opportunities

Oxford University Press (OUP) | August 5th, 2015

Building on previous environmental flow discussions and a growing recognition that hydrogeomorphic processes are inherent in the ecological functionality and biodiversity

Building on previous environmental flow discussions and a growing recognition that hydrogeomorphic processes are inherent in the ecological functionality and biodiversity of riverscapes, we propose a functional-flows approach to managing heavily modified rivers. The approach focuses on retaining specific process-based components of the hydrograph, or functional flows, rather than attempting to mimic the full natural flow regime. Key functional components include wet-season initiation flows, peak magnitude flows, recession flows, dry-season low flows, and interannual variability. We illustrate the importance of each key functional flow using examples from western US rivers with seasonably predictable flow regimes. To maximize the functionality of these flows, connectivity to morphologically diverse overbank areas must be enhanced in both space and time, and consideration must be given to the sediment-transport regime. Finally, we provide guiding principles for developing functional flows or incorporating functional flows into existing environmental flow frameworks.

Fundamentals of estimating the net benefits of ecosystem preservation: The case of the Salton Sea

Hydrobiologia (Springer) | July 15th, 2008

This article, both theoretical and methodological in nature, argues the potential merits of using a net benefits’ framework as a tool to aid policy-makers in their eff

This article, both theoretical and methodological in nature, argues the potential merits of using a net benefits’ framework as a tool to aid policy-makers in their efforts to compare Salton Sea restoration alternatives and inform the public as to the potential magnitude and distribution of trade-offs associated with each alternative. A net benefits approach can provide a more accurate comparison and evaluation of the potential net returns from public spending on Salton Sea restoration than what wouldbe provided under the suggested criteria of current legislative mandates. Furthermore, a net benefits framework provides a more lucid and systematic accounting framework by which to enumerate the full array of benefits and costs of each alternative for policy analysis. Finally, net benefits’ analysis serves to add transparency to the decision-making process sothat the public gains an understanding of how its scarce resources, including both financial and natural capital, are being appropriated. Additionally, we illustrate and emphasize the importance of estimating the non-market values associated with many of the ecosystem services provided by the Salton Sea and describe the major techniques that do so.