San Francisco Bay California Toxics Rule Priority Pollutant Ambient Water Monitoring Report

San Francisco Estuary Institute (SFEI) | March 2nd, 2017

In 2000, the USEPA published Water Quality Standards; Establishment of Numeric Objectives for Priority Toxic Pollutants for the State of California, commonly known as the

In 2000, the USEPA published Water Quality Standards; Establishment of Numeric Objectives for Priority Toxic Pollutants for the State of California, commonly known as the California Toxics Rule (CTR), which established numeric water quality standards for 126 priority pollutants. Under the Policy for Implementation of Toxics Standards for Inland Surface Waters, Enclosed Bays, and Estuaries of California (also known as the State Implementation Policy, SIP) the San Francisco Bay Regional Water Quality Control Board (SFBRWQCB) is required to establish water quality-based effluent limitations in order to achieve priority pollutant standards. For the purposes of this document “water quality criteria” (WQCs) will be used to refer both to the CTR established numeric criteria for 126 priority pollutants as well as to numeric objectives for 12 of these priority pollutants and tributyltin previously established in the San Francisco Bay Water Quality Control Plan (Basin Plan) and/or the National Toxics Rule. A number of these pollutants previously were or continue to be regularly monitored as part of the Regional Monitoring Program Status and Trends (RMP S&T). The priority pollutants not routinely included in RMP S&T were previously monitored in wet and dry season ambient water sampling in 2002 and 2003. Results of that effort are detailed in a previously issued report: http://www.sfei.org/documents/san-francisco-bay-ambient-monitoring-interim-report Most of the priority pollutants were not detected in that study, or detected at concentrations below their WQC. Among the pollutants that were detected, a number of them were also found at similar concentrations in lab blanks, suggesting they might not have been present (or at least were at lower concentrations) in the ambient environment. Since over a decade had passed since that previous monitoring effort, the RMP embarked on an effort to repeat measurement of these seldom analyzed (non- S&T) contaminants, to ensure conditions have not changed appreciably to present greater risk for any of them.

San Francisco Bay Nutrient Management Strategy Observation Program

San Francisco Estuary Institute (SFEI) | July 1st, 2020

This document presents a planning-level description of the draft Nutrient Management Strategy Observation Program (NMSOP), including estimated budget and approach for ph

This document presents a planning-level description of the draft Nutrient Management Strategy Observation Program (NMSOP), including estimated budget and approach for phased growth. The NMSOP represents the design that is needed to address NMS†data needs¨ not an existing program. The proposed design represents a balance between two key goals: ● Target high priority NMS data collection needs ● Where feasible, align field work and data collection efforts with other programs’ established infrastructure, to enhance cost-effectiveness and sustainability. While an inter-program collaborative approach is important for securing NMSOP’s long-term sustainability, building a reliable consortium will require up-front effort to establish inter-program science, management, and financial agreements. This document focuses on the NMSOP scientific program design and growth, with institutional program development described in a companion work plan (SFEI 2016b).

San Francisco Bay Triennial Bird Egg Monitoring Program for Contaminants, California—2018

U.S. Geological Survey (USGS) | May 23rd, 2019

The Regional Monitoring Program for Water Quality in San Francisco Bay (RMP), administered by the San Francisco Estuary Institute, is a large-scale effort to monitor cont

The Regional Monitoring Program for Water Quality in San Francisco Bay (RMP), administered by the San Francisco Estuary Institute, is a large-scale effort to monitor contaminant trends in water, sediment, fish, and birds throughout San Francisco Bay (San Francisco Estuary Institute, 2016). As part of the RMP and the U.S. Geological Survey (USGS) long-term Wildlife Contaminants Program, the USGS samples double-crested cormorant (Phalacrocorax auritus) and Forster’s tern (Sterna forsteri) eggs throughout the San Francisco Bay approximately every 3 years to assess temporal trends in contaminant concentrations. This sampling has previously been carried out by USGS in 2009, 2012, and 2016. This document summarizes egg collections for 2018, as well as mercury concentrations in Forster’s tern eggs on an individual egg basis. These data are available in a USGS data release (Ackerman and others, 2019).

San Gabriel Valley Groundwater Basin Salt And Nutrient Management Plan

Publisher not available | May 31st, 2016

San Leandro Bay PCB Study Data Report

San Francisco Estuary Institute (SFEI) | December 1st, 2017

The goal of RMP PCB special studies over the next few years is to inform the review and possible revision of the PCB TMDL and the reissuance of the Municipal Regional P

The goal of RMP PCB special studies over the next few years is to inform the review and possible revision of the PCB TMDL and the reissuance of the Municipal Regional Permit for Stormwater, both of which are tentatively scheduled to occur in 2020. Conceptual model development for a set of four representative priority margin units will provide a foundation for establishing an effective and efficient monitoring plan to track responses to load reductions, and will also help guide planning of management actions. The Emeryville Crescent was the first PMU to be studied in 2015-2016. The San Leandro Bay PMU is second (2016-2017), Steinberger Slough in San Carlos is third (2017), and Richmond Harbor will be fourth (2018). The conceptual model reports for these four PMUs will be developed and presented using a consistent framework, and will build on each other to form an integrated assessment of these four areas. The lessons learned from these analyses will also be more generally applicable to similar contaminated sites on the margins of the Bay. This document is a data report on field studies to support development of a conceptual model for San Leandro Bay.

Science, society, and the coastal groundwater squeeze

American Geophysical Union (AGU) | April 28th, 2017

Coastal zones encompass the complex interface between land and sea. Understanding how water and solutes move within and across this interface is essential for managing r

Coastal zones encompass the complex interface between land and sea. Understanding how water and solutes move within and across this interface is essential for managing resources for society. The increasingly dense human occupation of coastal zones disrupts natural groundwater flow patterns and degrades freshwater resources by both overuse and pollution. This pressure results in a ‘‘coastal groundwater squeeze,’’ where the thin veneers of potable freshwater are threatened by contaminant sources at the land surface and saline groundwater at depth. Scientific advances in the field of coastal hydrogeology have enabled responsible management of water resources and protection of important ecosystems. To address the problems of the future, we must continue to make scientific advances, and groundwater hydrology needs to be firmly embedded in integrated coastal zone management. This will require interdisciplinary scientific collaboration, open communication between scientists and the public, and strong partnerships with policymakers.

Screening of Pharmaceuticals in San Francisco Bay Wastewater

San Francisco Estuary Institute (SFEI) | October 1st, 2018

Previous studies have shown that pharmaceuticals are widely detected in San Francisco Bay, and some compounds occasionally approach levels of concern for wildlife. In 20

Previous studies have shown that pharmaceuticals are widely detected in San Francisco Bay, and some compounds occasionally approach levels of concern for wildlife. In 2016 and 2017, seven wastewater treatment facilities located throughout the Bay Area voluntarily collected wastewater samples and funded analyses for 104 pharmaceutical compounds. This dataset represents the most comprehensive analysis of pharmaceuticals in wastewater to date in this region. On behalf of the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP), the complete dataset was reviewed utilizing RMP quality assurance methods. An analysis of influent and effluent information is summarized in this report, and is intended to inform future monitoring recommendations for the Bay.

Selected trace-elements in alluvium and rocks, western Mojave Desert, southern California

Journal of Geochemical Exploration (Elsevier) | September 3rd, 2018

Concentrations of twenty-seven elements, including naturally-occurring water-quality contaminants arsenic, chromium, and uranium, were measured in 217 samples of alluviu

Concentrations of twenty-seven elements, including naturally-occurring water-quality contaminants arsenic, chromium, and uranium, were measured in 217 samples of alluvium and rock from the western Mojave Desert, southern California, using portable (pXRF) and laboratory (LXRF) X-ray fluorescence. Comparison of measurements with NIST-traceable standards was good, although pXRF overestimated iron compared to LXRF. Results suggest pXRF survey data are sufficiently accurate to assess regional geochemical differences in geologic-source terrains. Principal component analysis showed rubidium and potassium were associated with alluvium eroded from felsic terrain, while iron, copper, chromium, and to a lesser extent titanium, manganese, and nickel were associated with alluvium eroded from mafic terrain. Zinc, vanadium, and arsenic were associated with alluvium eroded from hydrothermal terrain. Elemental assemblages associated with different source terrains were traced spatially to identify the source and composition of alluvium composing aquifers pumped for water supply. Changes in geologic source terrain to the Mojave River, associated with movement along the San Andreas Fault over the past one to five million years, reduced the mafic fraction and increased the felsic fraction of alluvium deposited to the regionally important floodplain aquifer along the Mojave River—lowering chromium concentrations in alluvium through geologic time. Comparison of pXRF and sequential extraction data from 40samples showed arsenic and uranium were more abundant on the surfaces of mineral grains, while chromium and vanadium remained mostly within unweathered mineral grains—suggesting arsenic and uranium may be more readily mobilized into groundwater with changes in pH, redox, or ionic strength than chromium or vanadium.

Selenium Hazards in the Salton Sea Environment— Summary of Current Knowledge to Inform Future Wetland Management

U.S. Geological Survey (USGS) | July 20th, 2023

Quaternary marine and continental shales in the western United States are sources of selenium that can be loaded into the aquatic environment through mining, agricultural

Quaternary marine and continental shales in the western United States are sources of selenium that can be loaded into the aquatic environment through mining, agricultural, and energy production processes. The mobilization of selenium from shales through agricultural irrigation has been recognized since the 1930s; however, discovery of deformities in birds and other wildlife using agricultural habitats during the 1980s spurred studies to determine the extent and effects of the contamination. Through these early studies, researchers determined that biota in the Salton Sea drainage basin was at risk from legacy selenium contamination in the Colorado River watershed.

Selenium in Muscle Plugs of White Sturgeon from North San Francisco Bay, 2015-2017

San Francisco Estuary Institute (SFEI) | February 1st, 2019

This report presents the findings from a study evaluating selenium concentrations in white sturgeon (Acipenser transmontanus) muscle tissues collected from live sturgeon

This report presents the findings from a study evaluating selenium concentrations in white sturgeon (Acipenser transmontanus) muscle tissues collected from live sturgeon during the California Department of Fish and Wildlife’s fall sturgeon tagging studies in North San Francisco Bay. The goal of this study was to non-lethally collect a large number of sturgeon muscle plugs and analyze them for selenium to (1) establish an understanding of current status, trends, and causes of variability in sturgeon muscle selenium concentrations; and (2) evaluate the potential for long-term sturgeon selenium monitoring with muscle plugs, through development of field and laboratory methods and informing the monitoring design. Monitoring of selenium in white sturgeon is needed to evaluate the effectiveness of the North Bay Selenium Total Maximum Daily Load (TMDL) in protecting sturgeon from selenium toxicity. This technical report provides documentation of the study and presents its major findings in the context of all historically available data on sturgeon muscle selenium concentrations in San Francisco Bay.