Exploring scientific and management implications of upper trophic level food webs in the Delta

Delta Stewardship Council (Delta Council) | April 17th, 2024

The Sacramento-San Joaquin Delta (the Delta) has complex and evolving ecosystems characterized by multiple food webs that vary in time and space. Here, food webs are defi

The Sacramento-San Joaquin Delta (the Delta) has complex and evolving ecosystems characterized by multiple food webs that vary in time and space. Here, food webs are defined as the network of species interactions (competition, predation) and interactions with their environment that are related through the flow of energy through the ecosystem (e.g., Paine 1980). Physical modifications, in addition to the introduction of non-native species and the changing climate, have significantly altered the structure and energetic pathways of the food webs for decades. The science clearly suggests that predicting the impacts of habitat restoration, fisheries, changes in environmental drivers (e.g., climate, changes in nutrient loading, invasive species) on the ecological carrying capacity and productivity of the Delta, as well as the bioaccumulation of contaminants on species or the ecosystem, requires an understanding of food web processes.

Extremophile hotspots linked to containerized industrial waste dumping in a deep-sea basin

Oxford University Press (OUP) | September 9th, 2025

Decaying barrels on the seafloor linked to DDT contamination have raised concerns about the public health implications of decades old industrial waste dumped off the coas

Decaying barrels on the seafloor linked to DDT contamination have raised concerns about the public health implications of decades old industrial waste dumped off the coast of Los Angeles. To explore their contents, we collected sediment cores perpendicular to five deepsea barrels. The concentration of DDT and its breakdown products were highly elevated relative to control sites yet did not vary with distance from the barrels, suggesting that they were not associated with the contamination. Sediment cores collected through white halos surrounding three barrels were enriched in calcite and had elevated pH. The associated microbial communities were low diversity and dominated by alkalophilic bacteria with metagenome-assembled genomes adapted to high pH. A solid concretion sampled between a white halo and barrel was composed of brucite, a magnesium hydroxide mineral that forms at high pH. Based on these findings, we postulate that leakage of containerized alkaline waste triggered the formation of mineral concretions that are slowly dissolving and raising the pH of the surrounding sediment pore water. This selects for taxa adapted to extreme alkalinity and drives the precipitation of “anthropogenic” carbonates forming white halos, which serve as a visual identifier of barrels that contained alkaline waste. Remarkably, containerized alkaline waste discarded >50 years ago represents a persistent pollutant creating localized mineral formations and microbial communities that resemble those observed at some hydrothermal systems. These formations were observed at one-third of the visually identified barrels in the San Pedro Basin and have unforeseen, long-term consequences for benthic communities in the region.

Factors Affecting Marsh Vegetation at the Liberty Island Conservation Bank in the Cache Slough Region of the Sacramento–San Joaquin Delta, California

U.S. Geological Survey (USGS) | July 5th, 2017

The Liberty Island Conservation Bank (LICB) is a tidal freshwater marsh restored for the purpose of mitigating adverse effects on sensitive fish populations elsewhere in

The Liberty Island Conservation Bank (LICB) is a tidal freshwater marsh restored for the purpose of mitigating adverse effects on sensitive fish populations elsewhere in the region. The LICB was completed in 2012 and is in the northern Cache Slough region of the Sacramento–San Joaquin Delta. The wetland vegetation at the LICB is stunted and yellow-green in color (chlorotic) compared to nearby wetlands. A study was done to investigate three potential causes of the stunted and chlorotic vegetation: (1) improper grading of the marsh plain, (2) pesticide contamination from agricultural and urban inputs upstream from the site, (3) nitrogen-deficient soil, or some combination of these. Water samples were collected from channels at five sites, and soil samples were collected from four wetlands, including the LICB, during the summer of 2015. Real-time kinematic global positioning system (RTK-GPS) elevation surveys were completed at the LICB and north Little Holland Tract, a closely situated natural marsh that has similar hydrodynamics as the LICB, but contains healthy marsh vegetation. The results showed no significant differences in carbon or nitrogen content in the surface soils or in pesticides in water among the sites. The elevation survey indicated that the mean elevation of the LICB was about 26 centimeters higher than that of the north Little Holland Tract marsh. Because marsh plain elevation largely determines the hydroperiod of a marsh, these results indicated that the LICB has a hydroperiod that differs from that of neighboring north Little Holland Tract marsh. This difference in hydroperiod contributed to the lower stature and decreased vigor of wetland vegetation at the LICB. Although the LICB cannot be regraded without great expense, it could be possible to reduce the sharp angle of the marsh edge to facilitate deeper and more frequent tidal flooding along the marsh periphery. Establishing optimal elevations for restored wetlands is necessary for obtaining the full suite of ecosystem services provided by tidal wetlands. A better system of tidal benchmarks throughout the delta is needed to help restoration practitioners correctly grade the elevation of newly restored wetlands.

Final Environmental Impact Report for Adoption of a Regulation for the Hexavalent Chromium Maximum Contaminant Level

California State Water Resources Control Board (SWRCB) | April 17th, 2024

As the lead agency in accordance with sections 15089 and 15132 of the California Environmental Quality Act (CEQA) Guidelines (Cal. Code Regs., tit. 14, § 15000 et seq.),

As the lead agency in accordance with sections 15089 and 15132 of the California Environmental Quality Act (CEQA) Guidelines (Cal. Code Regs., tit. 14, § 15000 et seq.), this document is the Final Environmental Impact Report (Final EIR) for the adoption of statewide regulations setting the maximum contaminant level (MCL) for hexavalent chromium (Proposed Regulations). The Proposed Regulations include a maximum contaminant level (MCL) of 10 μg/L for hexavalent chromium. (Cal. Code Regs. tit. 22, § 64431 Table 64431-A.) The Proposed Regulations also include a compliance schedule based on public water system size, by adding subdivision (p) and Table 64432-B to section 64432 of title 22 of the California Code of Regulations, identifies a detection limit for purposes of reporting, sets monitoring and reporting requirements and public notice requirements for violations of the MCL, and establishes the Best Available Technologies (BAT) for treating hexavalent chromium in drinking water. California State Water Resources Control Board (SWRCB) Chrom VI MCL rulemaking chronology.

Final Report on the recovery of the Upper Sacramento River - subsequent to the 1991 Cantara spill

Cantara Trustee Council | June 18th, 2007

The Cantara Trustee Council (CTC), and the Cantara Program, operated for a period of 12 years, from 1995-2007. During that time, the CTC funded numerous projects which in

The Cantara Trustee Council (CTC), and the Cantara Program, operated for a period of 12 years, from 1995-2007. During that time, the CTC funded numerous projects which included restoration activities, land acquisition and protection, research, and public education. The purpose of this document is to leave a summary record of events that occurred due to the 1991 Cantara spill. It is our intent to provide a condensed presentation of the spill event, the legal processes following the spill, including the formation of the CTC, the formation of the Cantara Program, and the development of guiding plans and documents used by the CTC in the disbursement of settlement funds.

Fire and Water: Assessing Drinking Water Contamination After a Major Wildfire

American Chemical Society (ACS) | August 2nd, 2021

We investigated patterns of volatile organic compound (VOC) contamination in drinking water systems affected by the California 2018 Camp Fire. We performed spatial analys

We investigated patterns of volatile organic compound (VOC) contamination in drinking water systems affected by the California 2018 Camp Fire. We performed spatial analysis of over 5000 water samples collected over a 17 month period by a local water utility, sampled tap water for VOCs in approximately 10% (N = 136) of standing homes, and conducted additional nontargeted chemical analysis of 10 samples. Benzene contamination was present in 29% of service connections to destroyed structures and 2% of service connections to standing homes. A spatial pattern was apparent. Tap water in standing homes 11 months after the fire contained low concentrations of benzene in 1% of samples, but methylene chloride was present in 19% of samples, including several above regulatory limits. Elevated methylene chloride was associated with greater distance from the water meter to the tap, longer stagnation time, and the presence of a destroyed structure on the service connection; it was inversely associated with certain trihalomethanes. Nontargeted analysis identified multiple combustion byproducts in the water at 2/10 homes. Our findings support the hypothesis that pyrolysis and smoke intrusion from depressurization contributed to the benzene contamination. Further research is needed to test the hypothesis that methylene chloride may be generated from the dehalogenation of disinfection byproducts stagnating in galvanized iron pipes.

First flush analysis of urban storm runoff

Science of the Total Environment (Elsevier) | July 3rd, 2003

Stormwater runoff was monitored on 13 separate urban watersheds, which were chosen to represent distinct types of residential and industrial development, along with vario

Stormwater runoff was monitored on 13 separate urban watersheds, which were chosen to represent distinct types of residential and industrial development, along with various watershed characteristics. A total of 38 storm events were monitored to investigate the first flush phenomenon. The first flush phenomenon may be defined as the initial period of stormwater runoff during which the concentration of pollutants is substantially higher than during later stages. The magnitude of the first flush phenomenon, and if it actually occurs, was calculated using a method of data analysis which results in determining the ‘event mean concentration’ (EMC). The magnitude of the first flush phenomenon was found to be greater for some pollutants (e.g. suspended solids from residential areas) and less for others (e.g. chemical oxygen demand from industrial areas). No correlation was observed between the first flush phenomenon and the antecedent dry weather period, however, the first flush phenomenon was greater for smaller watershed areas.

Flame retardants and plastic additives in San Francisco Bay: Targeted monitoring of organophosphate esters and bisphenols

San Francisco Estuary Institute (SFEI) | January 31st, 2020

Fourth National Climate Assessment Chapter 3: Water

U.S. Global Change Research Program | November 23rd, 2018

Significant changes in water quantity and quality are evident across the country. These changes, which are expected to persist, present an ongoing risk to coupled human

Significant changes in water quantity and quality are evident across the country. These changes, which are expected to persist, present an ongoing risk to coupled human and natural systems and related ecosystem services. Variable precipitation and rising temperature are intensifying droughts, increasing heavy downpours, and reducing snowpack. Reduced snow-to-rain ratios are leading to significant differences between the timing of water supply and demand. Groundwater depletion is exacerbating drought risk. Surface water quality is declining as water temperature increases and more frequent high-intensity rainfall events mobilize pollutants such as sediments and nutrients. Click here for the text of the full report.

From Sediment to Top Predators: Broad Exposure of Polyhalogenated Carbazoles in San Francisco Bay

American Chemical Society (ACS) | January 23rd, 2017

The present study provides the first comprehensive investigation of polyhalogenated carbazoles (PHCZs) contamination in an aquatic ecosystem. PHCZs have been found in soi

The present study provides the first comprehensive investigation of polyhalogenated carbazoles (PHCZs) contamination in an aquatic ecosystem. PHCZs have been found in soil and aquatic sediment from several different regions, but knowledge of their bioaccumulation and trophodynamics is extremely scarce. This work investigated a suite of 11 PHCZ congeners in San Francisco Bay (United States) sediment and organisms, including bivalves (n = 6 composites), sport fish (n = 12 composites), harbor seal blubber (n = 18), and bird eggs (n = 8 composites). The most detectable congeners included 3,6-dichlorocarbazole (36-CCZ), 3,6-dibromocarbazole (36-BCZ), 1,3,6-tribromocarbazole (136-BCZ), 1,3,6,8-tetrabromocarbazole (1368-BCZ), and 1,8-dibromo-3,6-dichlorocarbazole (18-B-36-CCZ). The median concentrations of ΣPHCZs were 9.3 ng/g dry weight in sediment and ranged from 33.7 to 164 ng/g lipid weight in various species. Biomagnification was observed from fish to harbor seal and was mainly driven by chlorinated carbazoles, particularly 36-CCZ. Congener compositions of PHCZs differed among species, suggesting that individual congeners may be subject to different bioaccumulation or metabolism in species occupying various trophic levels in the studied aquatic system. Toxic equivalent (TEQ) values of PHCZs were determined on the basis of their relative effect potencies (REP) compared to 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). The median TEQ was 1.2 pg TEQ/g dry weight in sediment and 4.8–19.5 pg TEQ/g lipid weight in biological tissues. Our study demonstrated the broad exposure of PHCZs in San Francisco Bay and their characteristics of bioaccumulation and biomagnification along with dioxin-like effects. These findings raise the need for additional research to better elucidate their sources, environmental behavior, and fate in global environments.