wastewater – California Water Library

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Passage of fiproles and imidacloprid from urban pest control uses through wastewater treatment plants in northern California, USA

Society of Environmental Toxicology and Chemistry (SETAC) | November 3rd, 2017

Summary

Urban pest control insecticides—specifically fipronil and its 4 major degradates (fipronil sulfone, sulfide, desulfinyl, and amide), as well as imidacloprid—were moni

Urban pest control insecticides—specifically fipronil and its 4 major degradates (fipronil sulfone, sulfide, desulfinyl, and amide), as well as imidacloprid—were monitored during drought conditions in 8 San Francisco Bay (San Francisco, CA, USA) wastewater treatment plants (WWTPs). In influent and effluent, ubiquitous detections were obtained in units of ng/L for fipronil (13–88 ng/L), fipronil sulfone (1–28 ng/L), fipronil sulfide (1–5 ng/L), and imidacloprid (58–306 ng/L). Partitioning was also investigated; in influent, 100% of imidacloprid and 62 ± 9% of total fiproles (fipronil and degradates) were present in the dissolved state, with the balance being bound to filter‐removable particulates. Targeted insecticides persisted during wastewater treatment, regardless of treatment technology utilized (imidacloprid: 93 ± 17%; total fiproles: 65 ± 11% remaining), with partitioning into sludge (3.7–151.1 μg/kg dry wt as fipronil) accounting for minor losses of total fiproles entering WWTPs. The load of total fiproles was fairly consistent across the facilities but fiprole speciation varied. This first regional study on fiprole and imidacloprid occurrences in raw and treated California sewage revealed ubiquity and marked persistence to conventional treatment of both phenylpyrazole and neonicotinoid compounds. Flea and tick control agents for pets are identified as potential sources of pesticides in sewage meriting further investigation and inclusion in chemical‐specific risk assessments. Environ Toxicol Chem 2017;36:1473–1482. © 2016 SETAC

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Per- and polyfluoroalkyl substances (PFASs) in San Francisco Bay wildlife: Temporal trends, exposure pathways, and notable presence of precursor compounds

Chemosphere (Elsevier) | April 21st, 2017

Summary

Concentrations of perfluorooctane sulfonate (PFOS) in San Francisco Bay (SF Bay) wildlife have historically been among the highest reported globally. To track continuing

Concentrations of perfluorooctane sulfonate (PFOS) in San Francisco Bay (SF Bay) wildlife have historically been among the highest reported globally. To track continuing exposures to PFASs and assess the impact of the 2002 phase-out of production of PFOS and related chemicals in the US, nine perfluoroalkyl carboxylic acids (PFCAs; C4-C12), three perfluoroalkyl sulfonic acids (PFSAs; C4, C6, C8) and perfluorooctane sulfonamide (PFOSA, a PFOS precursor) were measured in SF Bay cormorant eggs in 2012 and harbor seal serum sampled between 2009 and 2014. PFOS remained the dominant perfluoroalkyl acid (PFAA) in both cormorant eggs (36.1–466 ng/g) and seals (12.6–796 ng/g) from 2012 and 2014, respectively. Concentrations in seal and bird eggs from the South Bay have declined approximately 70% in both matrices. To elucidate potential pathways of exposure, prey fish, sediments and wastewater effluent were analyzed for PFASs, and in the case of sediment and effluent, a suite of PFAA precursors. PFOS was the dominant PFAA in prey fish and sediment. In effluent, different mixtures of PFAAs were measured, with PFOS, PFHxA, and PFOA detected in the highest concentrations. Polyfluoroalkyl phosphate diesters (PFCA-precursors) were observed at concentrations over an order of magnitude higher than PFCAs in sediment, highlighting their importance as a potential, on-going source of PFCAs to SF Bay wildlife. These findings suggest that the PFOS phase-out has resulted in reduced burdens to wildlife in SF Bay, but that exposure to diverse and incompletely characterized PFASs continues.

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Plumbing the Depths: Californians Without Toilets and Running Water

Pacific Institute | July 15th, 2019

Summary

California’s Human Right to Water law states that “every human being has the right to safe, clean, affordable, and accessible water adequate for human consumption

California’s Human Right to Water law states that “every human being has the right to safe, clean, affordable, and accessible water adequate for human consumption, cooking, and sanitary purposes.” To date, the policy discussion on meeting California’s Human Right to Water has focused largely on expanding and improving drinking water utility services in the state, and improving the quality and reliability of drinking water for rural households using domestic wells. Sanitation and wastewater have received less attention. There also has been less attention paid to individuals and households in communities served by functional water and wastewater utilities but lacking the plumbing necessary to access those services. To partially remedy these gaps, we set out to better understand the number of Californians with inadequate access to toilets and hot and cold running water.

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Policy for Water Quality Control for Recycled Water (Recycled Water Policy)

California State Water Resources Control Board (SWRCB) | June 21st, 2013

Summary

The purpose of this Policy is to increase the use of recycled water from municipal wastewater sources that meets the definition in Water Code section 13050(n), in a manne

The purpose of this Policy is to increase the use of recycled water from municipal wastewater sources that meets the definition in Water Code section 13050(n), in a manner that implements state and federal water quality laws. The State Water Board expects to develop additional policies to encourage the use of stormwater, encourage water conservation, encourage the conjunctive use of surface and groundwater, and improve the use of local water supplies. When used in compliance with this Policy, Title 22 and all applicable state and federal water quality laws, the State Water Board finds that recycled water is safe for approved uses, and strongly supports recycled water as a safe alternative to potable water for such approved uses.

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Poly- and perfluoroalkyl substances in wastewater: Significance of unknown precursors, manufacturing shifts, and likely AFFF impacts

Water Research, Elsevier | May 15th, 2016

Summary

In late 2014, wastewater effluent samples were collected from eight treatment plants that discharge to San Francisco (SF) Bay in order to assess poly- and perfluoroalkyl

In late 2014, wastewater effluent samples were collected from eight treatment plants that discharge to San Francisco (SF) Bay in order to assess poly- and perfluoroalkyl substances (PFASs) currently released from municipal and industrial sources. In addition to direct measurement of twenty specific PFAS analytes, the total concentration of perfluoroalkyl acid (PFAA) precursors was also indirectly measured by adapting a previously developed oxidation assay. Effluent from six municipal treatment plants contained similar amounts of total PFASs, with highest median concentrations of PFHxA (24 ng/L), followed by PFOA (23 ng/L), PFBA (19 ng/L), and PFOS (15 ng/L). Compared to SF Bay municipal wastewater samples collected in 2009, the short chain perfluorinated carboxylates PFBA and PFHxA rose significantly in concentration. Effluent samples from two treatment plants contained much higher levels of PFASs: over two samplings, wastewater from one municipal plant contained an average of 420 ng/L PFOS and wastewater from an airport industrial treatment plant contained 560 ng/L PFOS, 390 ng/L 6:2 FtS, 570 ng/L PFPeA, and 500 ng/L PFHxA. The elevated levels observed in effluent samples from these two plants are likely related to aqueous film forming foam (AFFF) sources impacting their influent; PFASs attributable to both current use and discontinued AFFF formulations were observed. Indirectly measured PFAA precursor compounds accounted for 33%–63% of the total molar concentration of PFASs across all effluent samples and the PFAA precursors indicated by the oxidation assay were predominately short-chained. PFAS levels in SF Bay effluent samples reflect the manufacturing shifts towards shorter chained PFASs while also demonstrating significant impacts from localized usage of AFFF.

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San Francisco Bay California Toxics Rule Priority Pollutant Ambient Water Monitoring Report

San Francisco Estuary Institute (SFEI) | February 1st, 2017

Summary

In 2000, the USEPA published Water Quality Standards; Establishment of Numeric Objectives for Priority Toxic Pollutants for the State of California, commonly known as t

In 2000, the USEPA published Water Quality Standards; Establishment of Numeric Objectives for Priority Toxic Pollutants for the State of California, commonly known as the California Toxics Rule (CTR), which established numeric water quality standards for 126 priority pollutants. Under the Policy for Implementation of Toxics Standards for Inland Surface Waters, Enclosed Bays, and Estuaries of California (also known as the State Implementation Policy, SIP) the San Francisco Bay Regional Water Quality Control Board (SFBRWQCB) is required to establish water quality-based effluent limitations in order to achieve priority pollutant standards. For the purposes of this document “water quality criteria” (WQCs) will be used to refer both to the CTR established numeric criteria for 126 priority pollutants as well as to numeric objectives for 12 of these priority pollutants and tributyltin previously established in the San Francisco Bay Water Quality Control Plan (Basin Plan) and/or the National Toxics Rule. A number of these pollutants previously were or continue to be regularly monitored as part of the Regional Monitoring Program Status and Trends (RMP S&T). The priority pollutants not routinely included in RMP S&T were previously monitored in wet and dry season ambient water sampling in 2002 and 2003. Results of that effort are detailed in a previously issued : Most of the priority pollutants were not detected in that study, or detected at concentrations below their WQC. Among the pollutants that were detected, a number of them were also found at similar concentrations in lab blanks, suggesting they might not have been present (or at least were at lower concentrations) in the ambient environment. Since over a decade had passed since that previous monitoring effort, the RMP embarked on an effort to repeat measurement of these seldom analyzed (non- S&T) contaminants, to ensure conditions have not changed appreciably to present greater risk for any of them.

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Screening of Pharmaceuticals in San Francisco Bay Wastewater

San Francisco Estuary Institute (SFEI) | October 1st, 2018

Summary

Previous studies have shown that pharmaceuticals are widely detected in San Francisco Bay, and some compounds occasionally approach levels of concern for wildlife. In 20

Previous studies have shown that pharmaceuticals are widely detected in San Francisco Bay, and some compounds occasionally approach levels of concern for wildlife. In 2016 and 2017, seven wastewater treatment facilities located throughout the Bay Area voluntarily collected wastewater samples and funded analyses for 104 pharmaceutical compounds. This dataset represents the most comprehensive analysis of pharmaceuticals in wastewater to date in this region. On behalf of the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP), the complete dataset was reviewed utilizing RMP quality assurance methods. An analysis of influent and effluent information is summarized in this report, and is intended to inform future monitoring recommendations for the Bay.

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Sea Level Rise Impacts on Wastewater Treatment Systems Along the U.S. Coasts

American Geophysical Union (AGU) | April 13th, 2018

Summary

Wastewater treatment plants are susceptible to flooding resulting from sea level rise. Previous estimates of wastewater exposure have only considered the impacts of mar

Wastewater treatment plants are susceptible to flooding resulting from sea level rise. Previous estimates of wastewater exposure have only considered the impacts of marine flooding at the local or regional scale. In this analysis, we quantify the exposure to marine flooding across the coastal United States and then consider the relative impacts of marine and groundwater flooding at the regional scale in the San Francisco Bay Area. We also estimate the number of people who may lose access to wastewater services if no actions are taken to prevent flooding at wastewater treatment plants. We find that the number of people impacted by sea level rise due to loss of wastewater services could be five times as high as previous predictions of the number of people who experience direct flooding of their homes or property. We also find that groundwater flooding poses a significant threat to wastewater plants in the San Francisco Bay region.

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State and green crimes related to water pollution and ecological disorganization: water pollution from publicly owned treatment works (POTW) facilities across US states

Palgrave Communications | August 1st, 2017

Summary

Green criminologists often refer to water pollution as an example of a green crime, but have yet to produce much research on this subject. The current article addresses�

Green criminologists often refer to water pollution as an example of a green crime, but have yet to produce much research on this subject. The current article addresses the need for green criminological analyses of water pollution problems, and draws attention to an overlooked issue: water pollution emissions from state owned public water treatment facilities or POTWs. Legally, POTWs may emit certain quantities and kinds of pollutants to waterways following treatment. This does not mean, however, that those emissions have no adverse ecological or public health impacts, or that those emissions cannot also be employed as examples of green crimes or green-state crimes. Indeed, from the perspective of environmental sociology and ecological Marxism, those emissions generate ecological disorganization. Moreover, POTW emissions contain numerous pollutants that generate different forms of ecological disorganization. The current study uses POTW emissions data drawn from the US EPA’s Discharge Monitoring Report system for 2014 to illustrate the extent of pollution emitted by POTWs in and across US states as one dimension of ecological disorganization. To contextualize the meaning of those data, we review US water pollution regulations, review the health and ecological impacts of chemicals emitted by POTWs, and situate those emissions within green criminological discussions of green crime and greenstate crimes.

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Study to Evaluate Long-Term Trends and Variations in the Average Total Dissolved Solids Concentration in Wastewater and Recycled Water

Southern California Salinity Coalition | March 30th, 2018

Summary

This report was funded by the Southern California Salinity Coalition (SCSC). SCSC and its member agencies are dedicated to managing salinity in the water supplies, waste

This report was funded by the Southern California Salinity Coalition (SCSC). SCSC and its member agencies are dedicated to managing salinity in the water supplies, wastewater, and recycled water. Member agencies include Eastern Municipal Water District (EMWD), Inland Empire Utilities Agency (IEUA), Metropolitan Water District of Southern California (MWDSC), Orange County Sanitation District (OCSD), Orange County Water District (OCWD), San Diego County Water Authority (SDCWA), Sanitation Districts of Los Angeles County (LACSD), and Santa Ana Watershed Project Authority (SAWPA). Daniel B. Stephens & Associates, Inc. (DBS&A) performed the analysis and is submitting this technical memorandum to address the research questions posed by SCSC and its member agencies. The 2011 to 2016 drought in California, in conjunction with unprecedented statewide conservation legislation, caused several member agencies to face challenges meeting regulatory water quality standards for the salinity of discharge water from wastewater treatment plants (WWTPs). In particular, total dissolved solids (TDS) concentrations have increased, while the operation of WWTPs have remained consistent with prior years. Figure ES-1 is a typical example of TDS trends for WWTPs in Southern California.

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