pesticides – California Water Library

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2021 RMP Water Cruise Plan

San Francisco Estuary Institute (SFEI) | October 14th, 2021

Summary

This report details plans associated with the annual Regional Monitoring Program for Water Quality in the San Francisco Estuary (RMP) water cruise. The RMP water samplin

This report details plans associated with the annual Regional Monitoring Program for Water Quality in the San Francisco Estuary (RMP) water cruise. The RMP water sampling program was redesigned in 2002 to adopt a randomized sampling design at thirty-one sites in place of the twenty-six base program stations sampled previously. In 2007, the number of sites was decreased to twenty-two stations, and it remains as such for 2021. The analytes for 2021 have been modified based on the Status and Trends (S&T) Review process that started in 2020. The analytes that are being removed from the program include selenium and methylmercury (dissolved and particulate), while bisphenols and organophosphate esters (OPEs) have been added to S&T monitoring.

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A multi-scale approach for identification of potential pesticide use sites impacting vernal pool critical habitat in California

Science of the Total Environment (Elsevier) | October 17th, 2022

Summary

Spatially explicit ecological risk assessment (ERA) requires estimating the overlap between chemical and receptor distribution to evaluate the potential impacts of exposu

Spatially explicit ecological risk assessment (ERA) requires estimating the overlap between chemical and receptor distribution to evaluate the potential impacts of exposure on nontarget organisms. Pesticide use estimation at field level is prone to error due to inconsistencies between ground-reporting and geospatial data coverage; attempts to rectify these inconsistencies have been limited in approach and rarely scaled to multiple crop types. We built upon a previously developed Bayesian approach to combine multiple crop types for a probabilistic determination of field-crop assignments and to examine co-occurrence of critical vernal pool habitats and bifenthrin application within a 5-county area in California (Madera, Merced, Sacramento, San Joaquin, and Stanislaus counties). We incorporated a multi-scale repeated sampling approach with an area constraint to improve the delineation of field boundaries and better capture variability in crop assignments and rotation schemes. After comparing the accuracy of the spatial probabilistic approach to USDA Census of Agriculture crop acreage data, we found our approach allows more specificity in the combination of crop types represented by the potential application area and improves acreage estimates when compared to traditional deterministic approaches. In addition, our multi-scale sampling scheme improved estimates of bifenthrin acreage variability for co-occurrence analysis and allowed for estimates of crop rotations that were previously uncaptured. Our approach could be leveraged for more realistic, spatially resolved exposure and effects models both in and outside of California.

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A pesticide and iPSC dopaminergic neuron screen identifies and classifies Parkinson-relevant pesticides

Nature Communications | May 16th, 2023

Summary

Parkinson’s disease (PD) is a complex neurodegenerative disease with etiology rooted in genetic vulnerability and environmental factors. Here we combine quantitative ep

Parkinson’s disease (PD) is a complex neurodegenerative disease with etiology rooted in genetic vulnerability and environmental factors. Here we combine quantitative epidemiologic study of pesticide exposures and PD with toxicity screening in dopaminergic neurons derived from PD patient induced pluripotent stem cells (iPSCs) to identify Parkinson’s-relevant pesticides. Agricultural records enable investigation of 288 specific pesticides and PD risk in a comprehensive, pesticide-wide association study. We associate long-term exposure to 53 pesticides with PD and identify co-exposure profiles. We then employ a live-cell imaging screening paradigm exposing dopaminergic neurons to 39 PD-associated pesticides. We find that 10 pesticides are directly toxic to these neurons. Further, we analyze pesticides typically used in combinations in cotton farming, demonstrating that co-exposures result in greater toxicity than any single pesticide. We find trifluralin is a driver of toxicity to dopaminergic neurons and leads to mitochondrial dysfunction. Our paradigm may prove useful to mechanistically dissect pesticide exposures implicated in PD risk and guide agricultural policy.

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Agrichemicals in surface water and birth defects in the United States

Acta Paediatrica (Wiley) | March 6th, 2009

Summary

Objectives: To investigate if live births conceived in months when surface water agrichemicals are highest are at greater risk for birth defects. Methods: Monthly conc

Objectives: To investigate if live births conceived in months when surface water agrichemicals are highest are at greater risk for birth defects. Methods: Monthly concentrations during 1996–2002 of nitrates, atrazine and other pesticides were calculated using United States Geological Survey's National Water Quality Assessment data. Monthly United States birth defect rates were calculated for live births from 1996 to 2002 using United States Centers for Disease Control and Prevention natality data sets. Birth defect rates by month of last menstrual period (LMP) were then compared to pesticide/nitrate means using logistical regression models. Results: Mean concentrations of agrichemicals were highest in April–July. Total birth defects, and eleven of 22 birth defect subcategories, were more likely to occur in live births with LMPs between April and July. A significant association was found between the season of elevated agrichemicals and birth defects. Conclusion: Elevated concentrations of agrichemicals in surface water in April–July coincided with higher risk of birth defects in live births with LMPs April–July. While a causal link between agrichemicals and birth defects cannot be proven from this study an association might provide clues to common factors shared by both variables.

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Assessing the presence of current-use pesticides in mid-elevation Sierra Nevada streams using passive samplers, California, 2018–19

U.S. Geological Survey (USGS) | February 9th, 2023

Summary

Passive sampler devices were deployed in six northern California streams five times between November 2018 and December 2019 to measure the presence or absence of current-

Passive sampler devices were deployed in six northern California streams five times between November 2018 and December 2019 to measure the presence or absence of current-use pesticides in surface water. In the targeted areas, there are reported pesticide uses for agriculture, commercial forestry, and rights of way maintenance along with unreported pesticide use at private residences and cannabis grow sites. The sites sampled in this study were not previously monitored for current-use pesticides. Streams in the Sierra Nevada foothills of northern California are important habitats for many sensitive species including salmonids, but the logistics of sampling these areas can be difficult using traditional water-quality sampling techniques, especially when sampling watersheds where contaminant transport is episodic. Chemcatcher passive sampling devices and silicone bands were deployed in these areas to concentrate pesticides for days to weeks at a time. The U.S. Geological Survey, in cooperation with the Central Valley Regional Water Quality Control Board, was responsible for developing passive sampler field deployment and laboratory analytical methods for current-use pesticides, providing pesticide measurements from streams in the study region, and determining how well passive samplers detect pesticides in these environments. Six sites were monitored during the study, and passive sampler extracts were analyzed for a total 155 current-use pesticides in this study. A total of 19 out of the 155 pesticides including 9 insecticides, 5 fungicides, and 5 herbicides were detected in extracts from passive samplers. The most frequently detected pesticides were the herbicides hexazinone and dithiopyr, the insecticides bifenthrin and methoxyfenozide, and the fungicide azoxystrobin.

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Assessment of Interim Flow Water-Quality Data of the San Joaquin River Restoration Program and Implications for Fishes, California, 2009–11

U.S. Geological Survey (USGS), San Francisco Water Department | June 29th, 2015

Summary

After more than 50 years of extensive water diversion for urban and agriculture use, a major settlement was reached among the U.S. Departments of the Interior and Commerc

After more than 50 years of extensive water diversion for urban and agriculture use, a major settlement was reached among the U.S. Departments of the Interior and Commerce, the Natural Resources Defense Council, and the Friant Water Users Authority in an effort to restore the San Joaquin River. The settlement received Federal court approval in October 2006 and established the San Joaquin River Restoration Program, a multi-agency collaboration between State and Federal agencies to restore and maintain fish populations, including Chinook salmon, in the main stem of the river between Friant Dam and the confluence with the Merced River. This is to be done while avoiding or minimizing adverse water supply effects to all of the Friant Division contractors that could result from restoration flows required by the settlement. The settlement stipulates that water- and sediment-quality data be collected to help assess the restoration goals. This report summarizes and evaluates water-quality data collected in the main stem of the San Joaquin River between Friant Dam and the Merced River by the U.S. Bureau of Reclamation for the San Joaquin River Restoration Program during 2009–11. This summary and assessment consider sampling frequency for adequate characterization of variability, sampling locations for sufficient characterization of the San Joaquin River Restoration Program restoration reach, sampling methods for appropriate media (water and sediment), and constituent reporting limits. After reviewing the water- and sediment-quality results for the San Joaquin River Restoration Program, several suggestions were made to the Fisheries Management Work Group, a division of the San Joaquin River Restoration Program that focuses solely on the reintroduction strategies and health of salmon and other native fishes in the river. Water-quality results for lead and total organic carbon exceeded the Surface Water Ambient Monitoring Program Basin Plan Objectives for the San Joaquin Basin, and results for copper exceeded the U.S. Environmental Protection Agency Office of Pesticide Programs’ aquatic-life chronic and acute benchmarks for invertebrates. One sediment sample contained detections of pyrethroid pesticides bifenthrin, lambda-cyhalothrin, and total permethrin at concentrations above published chronic toxicity thresholds.

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California regulation of agricultural runoff

American Bar Association (ABA) | November 1st, 2017

Summary

Agriculture in California is a multibillion dollar industry that produces more than half of the nation’s fruits, nuts, and vegetables. But this comes at a cost. Agricul

Agriculture in California is a multibillion dollar industry that produces more than half of the nation’s fruits, nuts, and vegetables. But this comes at a cost. Agriculture is the primary source of water pollution, with irrigation and rainfall sweeping excess fertilizers and pesticides off the fields into adjoining waters and, over time, leaching into groundwater. As a result, waterbodies—spanning roughly 8,000 miles of rivers and streams and 300,000 acres of lakes, bays, and wetlands—are impaired.

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Chlorinated Byproducts of Neonicotinoids and Their Metabolites: An Unrecognized Human Exposure Potential?

American Chemical Society (ACS) | January 14th, 2019

Summary

We recently reported the initial discovery of neonicotinoid pesticides in drinking water and their potential for transformation through chlorination and alkaline hydrolys

We recently reported the initial discovery of neonicotinoid pesticides in drinking water and their potential for transformation through chlorination and alkaline hydrolysis during water treatment. The objectives of this research were: (1) to determine if neonicotinoid metabolites are relevant to drinking water exposure and (2) to identify the products formed from chlorination of neonicotinoids and their metabolites. Desnitroimidacloprid and imidacloprid-urea, two known metabolites of imidacloprid, are documented for the first time in drinking water. Desnitro-imidacloprid was present above the lower level of detection (0.03 ng/L) in 67% of samples (six of nine) from drinking water systems but detectable in all samples (up to 0.6 ng/L). Although concentrations of desnitro-imidacloprid were lower than concentrations of the parent neonicotinoids, desnitro-imidacloprid exhibits significantly greater mammalian toxicity than imidacloprid. Using LC-HR-ToF-MS/MS analysis of results from laboratory experiments, we propose structures for novel transformation products resulting from the chlorination of clothianidin, imidacloprid, desnitro-imidacloprid, imidacloprid-urea, and hydrolysis products of thiamethoxam. Formation of chlorinated neonicotinoid byproducts occurs at time scales relevant to water treatment and/or distribution for the imidacloprid metabolites (t1/2 values from 2.4 min to 1.0 h) and thiamethoxam hydrolysis products (4.8 h). Neonicotinoid metabolites in finished drinking water and potential formation of novel disinfection byproducts during treatment and/or distribution are relevant to evaluating the exposure and potential impacts of neonicotinoids on human health.

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Comparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California

Environmental Pollution (Elsevier) | October 10th, 2022

Summary

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to pla

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to planting). In California, multiple crops, including lettuce, can be grown using neonicotinoid treated seeds or receive a direct neonicotinoid soil application (drenching) at planting. Using research plots, this study compared pesticide runoff in four treatments: (1) imidacloprid seed treatment; (2) clothianidin seed treatment; (3) imidacloprid drench and an azoxystrobin seed treatment; and (4) a control with no pesticidal treatment. Neonicotinoid and azoxystrobin concentrations were measured in surface water runoff during six irrigations events in the 2020 growing seasons. Results showed runoff concentrations up to 1308 (±1200) ng L−1 for imidacloprid drench treatment, 431 (±100) ng L−1 for clothianidin seed treatment, 135 (±60) ng L−1 for imidacloprid seed treatment, 13 (±10) ng L−1 for azoxystrobin seed treatment (treatments averaged). The percent of applied mass in runoff over the entire sampling period varied by compound; the imidacloprid seed treatment and drench were similar (0.015 and 0.019%, respectively) to the clothianidin seed treatment (0.036%) while the azoxystrobin seed treatment was much higher (15%). Although the proportion of imidacloprid in runoff was similar for imidacloprid treatments, the mass applied during soil drench was > 4x the amount applied from the imidacloprid seed treatment. Surface soils were collected before planting and at the end of the trial. The neonicotinoids were detected in soil throughout the study and average maximum concentrations were 9–13 ng g−1; azoxystrobin was detected in only two soils at concentrations up to 0.57 ng g−1. These results elucidate the comparative mass runoff resulting from planting treated seed and soil drench applications and highlight the value of additional work to characterize off-site transport from the many commodities that may be utilizing treated seeds.

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Contaminant Concentrations in Sport Fish from San Francisco Bay: 2014

San Francisco Estuary Institute | January 1st, 2014

Summary

This summary report presents results from a 2014 survey of contaminants in San Francisco Bay sport fish, as well as an additional 2015 sampling of sport fish in Artesian

This summary report presents results from a 2014 survey of contaminants in San Francisco Bay sport fish, as well as an additional 2015 sampling of sport fish in Artesian Slough in Lower South Bay. This monitoring effort represents the seventh round of sport fish contaminant monitoring conducted by the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP). This technical report is intended for agency staff charged with managing water quality issues related to bioaccumulation of contaminants in San Francisco Bay. The RMP began sport fish monitoring in 1997, following a pilot study conducted by the Bay Protection and Toxic Cleanup Program in 1994. Data collected through this monitoring program provides updates on the status and long-term trends of contaminants in Bay sport fish, and are used to update human health consumption advisories and evaluate the effectiveness of regulatory and management efforts to reduce the impacts of contaminants of concern in the Bay. Key analyses in this report include comparisons of concentrations to human health and regulatory thresholds, spatial trend evaluation, and temporal trend evaluation. Mercury, polychlorinated biphenyls (PCBs), dioxins, selenium, polybrominated diphenyl ethers (PBDEs), and perfluoroalkylated substances (PFASs) were analyzed across sixteen fish species collected at eight locations in San Francisco Bay and Artesian Slough. Fish species were selected based on a number of criteria, including species that are popular for consumption, are sensitive indicators of problems (accumulating relatively high concentrations of contaminants), are widely distributed, represent different exposure pathways (benthic vs. pelagic), and have been monitored in the past. Concentrations were compared to numeric human health thresholds established by the California Office of Environmental Health Hazard Assessment (OEHHA) for mercury, PCBs, selenium, and PBDEs. Results were also compared to regulatory thresholds for mercury, PCBs, and selenium, as well as non-regulatory screening value for dioxins, which have been established in Total Maximum Daily Load (TMDL) regulations by the San Francisco Bay Regional Water Quality Control Board (Water Board). The OEHHA fish consumption advisory is primarily driven by human exposure risks to mercury and PCBs. The 2014 data show that mercury and PCB concentrations remain high and widespread, indicating that these contaminants continue to pose the greatest human and wildlife health risks. Mercury concentrations exceeded OEHHA’s no consumption threshold for the sensitive population (women 18-45 and children 1-17) in several white sturgeon and striped bass samples, while PCB concentrations exceeded the no consumption threshold in Pacific sardine and white sturgeon samples. The spatial distribution of contamination has remained consistent over time, reflecting current knowledge of contaminated source areas targeted for management activities. Recent data showed no clear evidence of Bay-wide declines in either mercury or PCBs, although progressively lower PCB concentrations have been observed in recent years near Berkeley and in San Pablo Bay.

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