Emerging PFAS Trends in Water and Sediment from San Francisco Bay

Per- and polyfluoroalkyl substances (PFAS) are a diverse class of persistent compounds, including several that are bioaccumulative and known or suspected to be toxic. These unique compounds have widespread uses across consumer, commercial, and industrial products, resulting in widespread occurrence in humans, the environment, and wildlife across the globe. Within San Francisco Bay, the RMP has monitored PFAS across the Bay ecosystem, beginning in 2004 with various biota and since expanding to sediment, surface water, stormwater, and wastewater. These studies found PFAS throughout the Bay, especially in sport fish, where concentrations are of potential concern for human health and led to a classification of PFAS as High Concern for the Bay under the RMP tiered risk-based framework for emerging contaminants. 

This study examined Bay sediment and surface water to continue to build our understanding of the occurrence, fate, and risks of PFAS to ecological and human health. Using a targeted method, 40 PFAS were analyzed in Bay sediment collected in three monitoring cruises from 2017 to 2023, and Bay water collected from 2021 to 2023 during both the dry and wet seasons. The Total Oxidizable Precursor (TOP) assay was also used to supplement these findings by indirectly measuring unknown perfluoroalkyl acid (PFAA) precursors of detectable PFAS. This additional information aids in elucidating the broader levels of PFAS present in samples to better evaluate the exposure and risk to the Bay.